Exam 14: Chemical Equilibrium

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Increasing the pressure will ________. 2SO₂ (g) + O₂ (g) Increasing the pressure will ________. 2SO₂ (g) + O₂ (g)   2SO₃ (g) 2SO₃ (g)

(Multiple Choice)
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Oxygen (O₂) and ozone (O₃) coexist in the stratosphere and are in equilibrium with one another: Oxygen (O₂) and ozone (O₃) coexist in the stratosphere and are in equilibrium with one another:       a) Assuming that no other factors affect this equilibrium, if ozone (   ) is being depleted (somehow removed from the reaction system entirely), what is the direction of the equilibrium shift? b) What must be happening to the concentration of oxygen (   ) as a result of the equilibrium shift predicted in part a? Oxygen (O₂) and ozone (O₃) coexist in the stratosphere and are in equilibrium with one another:       a) Assuming that no other factors affect this equilibrium, if ozone (   ) is being depleted (somehow removed from the reaction system entirely), what is the direction of the equilibrium shift? b) What must be happening to the concentration of oxygen (   ) as a result of the equilibrium shift predicted in part a? Oxygen (O₂) and ozone (O₃) coexist in the stratosphere and are in equilibrium with one another:       a) Assuming that no other factors affect this equilibrium, if ozone (   ) is being depleted (somehow removed from the reaction system entirely), what is the direction of the equilibrium shift? b) What must be happening to the concentration of oxygen (   ) as a result of the equilibrium shift predicted in part a? a) Assuming that no other factors affect this equilibrium, if ozone ( Oxygen (O₂) and ozone (O₃) coexist in the stratosphere and are in equilibrium with one another:       a) Assuming that no other factors affect this equilibrium, if ozone (   ) is being depleted (somehow removed from the reaction system entirely), what is the direction of the equilibrium shift? b) What must be happening to the concentration of oxygen (   ) as a result of the equilibrium shift predicted in part a? ) is being "depleted" (somehow removed from the reaction system entirely), what is the direction of the equilibrium shift? b) What must be happening to the concentration of oxygen ( Oxygen (O₂) and ozone (O₃) coexist in the stratosphere and are in equilibrium with one another:       a) Assuming that no other factors affect this equilibrium, if ozone (   ) is being depleted (somehow removed from the reaction system entirely), what is the direction of the equilibrium shift? b) What must be happening to the concentration of oxygen (   ) as a result of the equilibrium shift predicted in part a? ) as a result of the equilibrium shift predicted in part a?

(Essay)
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Predict the effect of increasing pressure in each of the reactions by choosing the appropriate direction shift. -2 NH? (g) Predict the effect of increasing pressure in each of the reactions by choosing the appropriate direction shift. -2 NH? (g)   N? (g) + 3 H? (g) N? (g) + 3 H? (g)

(Multiple Choice)
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Consider the reaction: C (s) + CO? (g) Consider the reaction: C (s) + CO? (g)   2 CO (g) (endothermic).  Match each equilibrium change with its corresponding consequence. -cooling the mixture 2 CO (g) (endothermic). Match each equilibrium change with its corresponding consequence. -cooling the mixture

(Multiple Choice)
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Adding iron(III) chloride will ________. FeCL₃ (aq) + KSCN (aq) Adding iron(III) chloride will ________. FeCL₃ (aq) + KSCN (aq)   3[Fe(SCN)6] (aq) + 3KCl (aq) Yellow colorless red colorless 3[Fe(SCN)6] (aq) + 3KCl (aq) Yellow colorless red colorless

(Multiple Choice)
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The following chemical reaction has reached equilibrium. The following chemical reaction has reached equilibrium.     (g)     (g) Calculate the equilibrium constant, Keq, if the concentrations of     and   are 0.0238 M and 0.196 M, respectively. The following chemical reaction has reached equilibrium.     (g)     (g) Calculate the equilibrium constant, Keq, if the concentrations of     and   are 0.0238 M and 0.196 M, respectively. (g) The following chemical reaction has reached equilibrium.     (g)     (g) Calculate the equilibrium constant, Keq, if the concentrations of     and   are 0.0238 M and 0.196 M, respectively. The following chemical reaction has reached equilibrium.     (g)     (g) Calculate the equilibrium constant, Keq, if the concentrations of     and   are 0.0238 M and 0.196 M, respectively. (g) Calculate the equilibrium constant, Keq, if the concentrations of The following chemical reaction has reached equilibrium.     (g)     (g) Calculate the equilibrium constant, Keq, if the concentrations of     and   are 0.0238 M and 0.196 M, respectively. The following chemical reaction has reached equilibrium.     (g)     (g) Calculate the equilibrium constant, Keq, if the concentrations of     and   are 0.0238 M and 0.196 M, respectively. and The following chemical reaction has reached equilibrium.     (g)     (g) Calculate the equilibrium constant, Keq, if the concentrations of     and   are 0.0238 M and 0.196 M, respectively. are 0.0238 M and 0.196 M, respectively.

(Multiple Choice)
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In an endothermic reaction, adding heat will ________.

(Multiple Choice)
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The following chemical reaction has reached equilibrium. 2NO (g) + O₂ (g) The following chemical reaction has reached equilibrium. 2NO (g) + O₂ (g)   2NO₂ (g) Calculate the equilibrium constant, Keq, if the concentrations of reactants and products are 1.26 × 10<sup>-10</sup> M for NO, 2.28 × 10<sup>-3</sup> M for O₂, and 9.32 × 10<sup>-6</sup> M for NO₂. 2NO₂ (g) Calculate the equilibrium constant, Keq, if the concentrations of reactants and products are 1.26 × 10-10 M for NO, 2.28 × 10-3 M for O₂, and 9.32 × 10-6 M for NO₂.

(Multiple Choice)
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Predict the effect of increasing pressure in each of the reactions by choosing the appropriate direction shift. -O₂ (g) + 2F₂ (g) Predict the effect of increasing pressure in each of the reactions by choosing the appropriate direction shift. -O₂ (g) + 2F₂ (g)   2 OF₂ (g) 2 OF₂ (g)

(Multiple Choice)
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Predict the direction in which the reaction will shift for the following reactions if the temperature is increased: a) CO + Predict the direction in which the reaction will shift for the following reactions if the temperature is increased: a) CO +       +   O (exothermic) b)   +     2HI (endothermic) c) CO +   O     +   (exothermic) Predict the direction in which the reaction will shift for the following reactions if the temperature is increased: a) CO +       +   O (exothermic) b)   +     2HI (endothermic) c) CO +   O     +   (exothermic) Predict the direction in which the reaction will shift for the following reactions if the temperature is increased: a) CO +       +   O (exothermic) b)   +     2HI (endothermic) c) CO +   O     +   (exothermic) + Predict the direction in which the reaction will shift for the following reactions if the temperature is increased: a) CO +       +   O (exothermic) b)   +     2HI (endothermic) c) CO +   O     +   (exothermic) O (exothermic) b) Predict the direction in which the reaction will shift for the following reactions if the temperature is increased: a) CO +       +   O (exothermic) b)   +     2HI (endothermic) c) CO +   O     +   (exothermic) + Predict the direction in which the reaction will shift for the following reactions if the temperature is increased: a) CO +       +   O (exothermic) b)   +     2HI (endothermic) c) CO +   O     +   (exothermic) Predict the direction in which the reaction will shift for the following reactions if the temperature is increased: a) CO +       +   O (exothermic) b)   +     2HI (endothermic) c) CO +   O     +   (exothermic) 2HI (endothermic) c) CO + Predict the direction in which the reaction will shift for the following reactions if the temperature is increased: a) CO +       +   O (exothermic) b)   +     2HI (endothermic) c) CO +   O     +   (exothermic) O Predict the direction in which the reaction will shift for the following reactions if the temperature is increased: a) CO +       +   O (exothermic) b)   +     2HI (endothermic) c) CO +   O     +   (exothermic) Predict the direction in which the reaction will shift for the following reactions if the temperature is increased: a) CO +       +   O (exothermic) b)   +     2HI (endothermic) c) CO +   O     +   (exothermic) + Predict the direction in which the reaction will shift for the following reactions if the temperature is increased: a) CO +       +   O (exothermic) b)   +     2HI (endothermic) c) CO +   O     +   (exothermic) (exothermic)

(Essay)
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Predict the effect of increasing pressure in each of the reactions by choosing the appropriate direction shift. -L₂ (g) + H₂ (g) Predict the effect of increasing pressure in each of the reactions by choosing the appropriate direction shift. -L₂ (g) + H₂ (g)   2 HI (g) 2 HI (g)

(Multiple Choice)
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Consider the reaction: C (s) + CO? (g) Consider the reaction: C (s) + CO? (g)   2 CO (g) (endothermic).  Match each equilibrium change with its corresponding consequence. -increasing the pressure 2 CO (g) (endothermic). Match each equilibrium change with its corresponding consequence. -increasing the pressure

(Multiple Choice)
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The equilibrium constant expression for the reaction is ________. N₂ (g) + 3H₂ (g) The equilibrium constant expression for the reaction is ________. N₂ (g) + 3H₂ (g)   2NH₃ (g) 2NH₃ (g)

(Multiple Choice)
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Consider the reaction: C (s) + CO? (g) Consider the reaction: C (s) + CO? (g)   2 CO (g) (endothermic).  Match each equilibrium change with its corresponding consequence. -adding carbon monoxide 2 CO (g) (endothermic). Match each equilibrium change with its corresponding consequence. -adding carbon monoxide

(Multiple Choice)
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The term "molar solubility of a salt" refers to the molar concentration of one anion (or cation) formed in an aqueous, saturated solution of that salt.

(True/False)
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Which of the following will shift the equilibrium to the left? 2H₂S (g) + 3O₂ (g) Which of the following will shift the equilibrium to the left? 2H₂S (g) + 3O₂ (g)   2SO₂ (g) + 2H₂O (g) 2SO₂ (g) + 2H₂O (g)

(Multiple Choice)
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Adding a couple of drops of an aqueous KCl solution will ________. FeCL₃ (aq) + KSCN (aq) Adding a couple of drops of an aqueous KCl solution will ________. FeCL₃ (aq) + KSCN (aq)   K3[Fe(SCN)6] (aq) + 3KCl (aq) Yellow colorless red colorless K3[Fe(SCN)6] (aq) + 3KCl (aq) Yellow colorless red colorless

(Multiple Choice)
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Predict the effect of increasing the concentration of the bolded species in each of the balanced equations by choosing the appropriate direction shift. -2 C?H?? (g) + 25 O? Predict the effect of increasing the concentration of the bolded species in each of the balanced equations by choosing the appropriate direction shift. -2 C?H?? (g) + 25 O?    Predict the effect of increasing the concentration of the bolded species in each of the balanced equations by choosing the appropriate direction shift. -2 C?H?? (g) + 25 O?

(Multiple Choice)
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Predict the direction in which the reaction will shift for the following reactions if the temperature is decreased: a) Predict the direction in which the reaction will shift for the following reactions if the temperature is decreased: a)   + NO     +   (endothermic) b)   +   O   CO +   (endothermic) c)   +       (exothermic) + NO Predict the direction in which the reaction will shift for the following reactions if the temperature is decreased: a)   + NO     +   (endothermic) b)   +   O   CO +   (endothermic) c)   +       (exothermic) Predict the direction in which the reaction will shift for the following reactions if the temperature is decreased: a)   + NO     +   (endothermic) b)   +   O   CO +   (endothermic) c)   +       (exothermic) + Predict the direction in which the reaction will shift for the following reactions if the temperature is decreased: a)   + NO     +   (endothermic) b)   +   O   CO +   (endothermic) c)   +       (exothermic) (endothermic) b) Predict the direction in which the reaction will shift for the following reactions if the temperature is decreased: a)   + NO     +   (endothermic) b)   +   O   CO +   (endothermic) c)   +       (exothermic) + Predict the direction in which the reaction will shift for the following reactions if the temperature is decreased: a)   + NO     +   (endothermic) b)   +   O   CO +   (endothermic) c)   +       (exothermic) O Predict the direction in which the reaction will shift for the following reactions if the temperature is decreased: a)   + NO     +   (endothermic) b)   +   O   CO +   (endothermic) c)   +       (exothermic) CO + Predict the direction in which the reaction will shift for the following reactions if the temperature is decreased: a)   + NO     +   (endothermic) b)   +   O   CO +   (endothermic) c)   +       (exothermic) (endothermic) c) Predict the direction in which the reaction will shift for the following reactions if the temperature is decreased: a)   + NO     +   (endothermic) b)   +   O   CO +   (endothermic) c)   +       (exothermic) + Predict the direction in which the reaction will shift for the following reactions if the temperature is decreased: a)   + NO     +   (endothermic) b)   +   O   CO +   (endothermic) c)   +       (exothermic) Predict the direction in which the reaction will shift for the following reactions if the temperature is decreased: a)   + NO     +   (endothermic) b)   +   O   CO +   (endothermic) c)   +       (exothermic) Predict the direction in which the reaction will shift for the following reactions if the temperature is decreased: a)   + NO     +   (endothermic) b)   +   O   CO +   (endothermic) c)   +       (exothermic) (exothermic)

(Short Answer)
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Identify each of the equilibrium constant values as "Equilibrium lies to the right/products favored" or "Equilibrium lies to the left/reactants favored." -6.2 × 1010

(Multiple Choice)
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