Exam 14: Chemical Equilibrium

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Consider the reaction: C (s) + CO? (g) Consider the reaction: C (s) + CO? (g)   2 CO (g) (endothermic).  Match each equilibrium change with its corresponding consequence. -adding extra carbon dioxide 2 CO (g) (endothermic). Match each equilibrium change with its corresponding consequence. -adding extra carbon dioxide

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A

The equilibrium constant is equal to which of the following?

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Expanding the reaction vessel will shift the equilibrium to the right. 3O₂ (g) ⇔ 2O₃ (g)

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Identify each of the equilibrium constant values as "Equilibrium lies to the right/products favored" or "Equilibrium lies to the left/reactants favored." -4.5 × 10-2

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At equilibrium, the concentrations of reactants and products are always exactly the same.

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Write an expression for the equilibrium constant (Keq) for the following reaction. Write an expression for the equilibrium constant (Keq) for the following reaction.   (g) +   (g)     (g) + NO (g) (g) + Write an expression for the equilibrium constant (Keq) for the following reaction.   (g) +   (g)     (g) + NO (g) (g) Write an expression for the equilibrium constant (Keq) for the following reaction.   (g) +   (g)     (g) + NO (g) Write an expression for the equilibrium constant (Keq) for the following reaction.   (g) +   (g)     (g) + NO (g) (g) + NO (g)

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Adding helium to the reaction vessel will ________. 2H₂S (g) + 3O₂ (g) Adding helium to the reaction vessel will ________. 2H₂S (g) + 3O₂ (g)   2SO₂ (g) + 2H₂O (g) 2SO₂ (g) + 2H₂O (g)

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Increasing the volume of the system will ________. 2H₂S (g) + 3O₂ (g) Increasing the volume of the system will ________. 2H₂S (g) + 3O₂ (g)   2SO₂ (g) + 2H₂O (g) 2SO₂ (g) + 2H₂O (g)

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Identify each of the equilibrium constant values as "Equilibrium lies to the right/products favored" or "Equilibrium lies to the left/reactants favored." -3.7 × 103

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Consider the reaction: C (s) + CO? (g) Consider the reaction: C (s) + CO? (g)   2 CO (g) (endothermic).  Match each equilibrium change with its corresponding consequence. -adding extra carbon 2 CO (g) (endothermic). Match each equilibrium change with its corresponding consequence. -adding extra carbon

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Predict the effect of increasing the concentration of the bolded species in each of the balanced equations by choosing the appropriate direction shift. -2 NH? (g) Predict the effect of increasing the concentration of the bolded species in each of the balanced equations by choosing the appropriate direction shift. -2 NH? (g)   N? (g) + 3 H? (g) N? (g) + 3 H? (g)

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For which of the following values of an equilibrium constant, Keq, would you expect the equilibrium to lie farthest to the left?

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If more If more     is added to the following reaction already at equilibrium:         what would be expected to happen to the rate of the forward reaction? If more     is added to the following reaction already at equilibrium:         what would be expected to happen to the rate of the forward reaction? is added to the following reaction already at equilibrium: If more     is added to the following reaction already at equilibrium:         what would be expected to happen to the rate of the forward reaction? If more     is added to the following reaction already at equilibrium:         what would be expected to happen to the rate of the forward reaction? If more     is added to the following reaction already at equilibrium:         what would be expected to happen to the rate of the forward reaction? If more     is added to the following reaction already at equilibrium:         what would be expected to happen to the rate of the forward reaction? what would be expected to happen to the rate of the forward reaction?

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Reducing the pressure will shift the equilibrium to the right. N₂ (g) + O₂ (g) ⇔ 2NO (g)

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Decreasing the concentration of nitrogen will shift the equilibrium to the left. N₂ (g) + 2O₂ (g) ⇔ 2NO₂ (g)

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Predict the shift in the direction of the reaction for the following chemical reaction: Predict the shift in the direction of the reaction for the following chemical reaction:   (g) +   (g)     (g)+   O (g) a) if methane (   ) is added b) if carbon dioxide (   ) is added c) if water (   O) is removed (g) + Predict the shift in the direction of the reaction for the following chemical reaction:   (g) +   (g)     (g)+   O (g) a) if methane (   ) is added b) if carbon dioxide (   ) is added c) if water (   O) is removed (g) Predict the shift in the direction of the reaction for the following chemical reaction:   (g) +   (g)     (g)+   O (g) a) if methane (   ) is added b) if carbon dioxide (   ) is added c) if water (   O) is removed Predict the shift in the direction of the reaction for the following chemical reaction:   (g) +   (g)     (g)+   O (g) a) if methane (   ) is added b) if carbon dioxide (   ) is added c) if water (   O) is removed (g)+ Predict the shift in the direction of the reaction for the following chemical reaction:   (g) +   (g)     (g)+   O (g) a) if methane (   ) is added b) if carbon dioxide (   ) is added c) if water (   O) is removed O (g) a) if methane ( Predict the shift in the direction of the reaction for the following chemical reaction:   (g) +   (g)     (g)+   O (g) a) if methane (   ) is added b) if carbon dioxide (   ) is added c) if water (   O) is removed ) is added b) if carbon dioxide ( Predict the shift in the direction of the reaction for the following chemical reaction:   (g) +   (g)     (g)+   O (g) a) if methane (   ) is added b) if carbon dioxide (   ) is added c) if water (   O) is removed ) is added c) if water ( Predict the shift in the direction of the reaction for the following chemical reaction:   (g) +   (g)     (g)+   O (g) a) if methane (   ) is added b) if carbon dioxide (   ) is added c) if water (   O) is removed O) is removed

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Which of the following statements is true for a chemical reaction that has not reached an equilibrium?

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If a chemical reaction at an equilibrium state is disturbed, the reaction will compensate for the disturbance in some way so that equilibrium can be restored.

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Adding excess oxygen will ________. CH₄ (g) + 2O₂ (g) Adding excess oxygen will ________. CH₄ (g) + 2O₂ (g)   CO₂ (g) + 2H₂O (g) CO₂ (g) + 2H₂O (g)

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Which of the following will shift the reaction to the right? CH₄ (g) + 2O₂ (g) Which of the following will shift the reaction to the right? CH₄ (g) + 2O₂ (g)   CO₂ (g) + 2H₂O (g) CO₂ (g) + 2H₂O (g)

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