Exam 20: Introduction to Carbonyl Chemistry; Organometallic Reagents; Oxidation and Reduction

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Rank the carbon-metal bond in the following organometallic reagents in order of decreasing polarity, starting with the most polar. I II III

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What is the name of the general reaction type that aldehydes and ketones undergo?

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What is the major organic product of the following reaction? What is the major organic product of the following reaction?

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What is the starting material in the following reaction? What is the starting material in the following reaction?

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What is the major organic product of the following reaction? What is the major organic product of the following reaction?

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What is the product of the following reaction? What is the product of the following reaction?

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What is the missing reagent in the reaction below? What is the missing reagent in the reaction below?

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What is the missing reagent in the reaction below? What is the missing reagent in the reaction below?

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What is the product of the following reaction? What is the product of the following reaction?

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What carbonyl compound and Grignard reagent could be used to prepare 2-butanol? CH3CHO/CH3CH2MgBrCH3CH2CHO/CH3MgBrCH3COCH3/CH3MgBr\mathrm { CH } _ { 3 } \mathrm { CHO } / \mathrm { CH } _ { 3 } \mathrm { CH } _ { 2 } \mathrm { MgBr } \quad \mathrm { CH } _ { 3 } \mathrm { CH } _ { 2 } \mathrm { CHO } / \mathrm { CH } _ { 3 } \mathrm { MgBr } \quad \mathrm { CH } _ { 3 } \mathrm { COCH } _ { 3 } / \mathrm { CH } _ { 3 } \mathrm { MgBr } I II III

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What is the major organic product of the following reaction? What is the major organic product of the following reaction?

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Rank the following compounds in order of increasing reactivity (least to most reactive) with respect to acyl substitution. I. methyl benzoate II) benzoylchloride III) benzamide

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What is the product of the following reaction? What is the product of the following reaction?

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What is the starting material in the reaction below? What is the starting material in the reaction below?

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Both LiAlH4 and NaBH4 are reducing agents. Which statement about these reagents is true?

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What is the purpose of a silyl ether?

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What is the major organic product of the following reaction? What is the major organic product of the following reaction?

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What reagent would be used to reduce an amide to an amine?

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What are the two steps in a nucleophilic addition mechanism?

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What is the major organic product of the following reaction? What is the major organic product of the following reaction?

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