Exam 21: Electrochemistry: Chemical Change and Electrical Work

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Consider the non-aqueous cell reaction 2Na(l) + FeCl2(s) Consider the non-aqueous cell reaction 2Na(l) + FeCl<sub>2</sub>(s)   2NaCl(s) + Fe(s) For which E°<sub>cell</sub> = 2.35 V at 200°C. <font face=symbol></font>G° at this temperature is 2NaCl(s) + Fe(s) For which E°cell = 2.35 V at 200°C. G° at this temperature is

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The following half-reactions occur in the mercury battery used in calculators. If E°cell = 1.357 V, calculate the equilibrium constant for the cell reaction at 25°C. (Assume the stoichiometric coefficients in the cell reaction are all equal to 1.) HgO(s) + H2O(l) + 2e- The following half-reactions occur in the mercury battery used in calculators. If E°<sub>cel</sub><sub>l</sub> = 1.357 V, calculate the equilibrium constant for the cell reaction at 25°C. (Assume the stoichiometric coefficients in the cell reaction are all equal to 1.) HgO(s) + H<sub>2</sub>O(l) + 2e<sup>-</sup>   Hg(l) + 2OH<sup>-</sup>(aq) ZnO(s) + H<sub>2</sub>O(l) + 2e<sup>-</sup>   Zn(s) + 2OH<sup>-</sup>(aq) Hg(l) + 2OH-(aq) ZnO(s) + H2O(l) + 2e- The following half-reactions occur in the mercury battery used in calculators. If E°<sub>cel</sub><sub>l</sub> = 1.357 V, calculate the equilibrium constant for the cell reaction at 25°C. (Assume the stoichiometric coefficients in the cell reaction are all equal to 1.) HgO(s) + H<sub>2</sub>O(l) + 2e<sup>-</sup>   Hg(l) + 2OH<sup>-</sup>(aq) ZnO(s) + H<sub>2</sub>O(l) + 2e<sup>-</sup>   Zn(s) + 2OH<sup>-</sup>(aq) Zn(s) + 2OH-(aq)

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