Exam 21: Electrochemistry: Chemical Change and Electrical Work

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Consider the reaction CuO(s) + H2(g) Cu(s) + H2O(l) In this reaction, which substances are the oxidant and reductant, respectively?

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A current of 250. A flows for 24.0 hours at an anode where the reaction occurring is Mn2+(aq) + 2H2O(l) MnO2(s) + 4H+(aq) + 2e- What mass of MnO2 is deposited at this anode?

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A cell can be prepared from copper and tin. What is the E°cell for the cell that forms from the following half-reactions? Cu2+(aq) + 2e- A cell can be prepared from copper and tin. What is the E°<sub>cell</sub> for the cell that forms from the following half-reactions?  Cu<sup>2+</sup>(aq) + 2e<sup>-</sup>   Cu(s) E°<sup> </sup>= 0.34 V Sn<sup>4+</sup>(aq) + 2e<sup>- </sup>   Sn<sup>2+</sup>(aq) E°<sup> </sup>= 0.13 V Cu(s) E° = 0.34 V Sn4+(aq) + 2e- A cell can be prepared from copper and tin. What is the E°<sub>cell</sub> for the cell that forms from the following half-reactions?  Cu<sup>2+</sup>(aq) + 2e<sup>-</sup>   Cu(s) E°<sup> </sup>= 0.34 V Sn<sup>4+</sup>(aq) + 2e<sup>- </sup>   Sn<sup>2+</sup>(aq) E°<sup> </sup>= 0.13 V Sn2+(aq) E° = 0.13 V

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The redox reaction of peroxydisulfate with iodide has been used for many years as part of the iodine clock reaction which introduces students to kinetics. If E°cell = 1.587 V and E° of the cathode half-cell is 0.536 V, what is E° of the anode half-cell? S2O82-(aq) + 2H+ + 2I-(aq) 2HSO4-(aq) + I2(aq)

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Examine the following half-reactions and select the strongest oxidizing agent among the species listed. Examine the following half-reactions and select the strongest oxidizing agent among the species listed.

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Consider the reaction of iodine with manganese dioxide Consider the reaction of iodine with manganese dioxide    The equilibrium constant for the overall reaction is 8.30 × 10<sup>-7</sup>. Calculate <font face=symbol></font>G°<sup> </sup>for the reaction at 25°C. The equilibrium constant for the overall reaction is 8.30 × 10-7. Calculate G° for the reaction at 25°C.

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Examine the following half-reactions and select the weakest oxidizing agent among the species listed. Examine the following half-reactions and select the weakest oxidizing agent among the species listed.

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In the shorthand notation for cells, a double vertical line is used to separate the reduced and oxidized forms of a redox couple.

(True/False)
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When the following redox equation is balanced with smallest whole number coefficients, the coefficient for Sn(OH)3- will be _____. Bi(OH)3(s) + Sn(OH)3-(aq) Sn(OH)62-(aq) + Bi(s) (basic solution)

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If the electrodes of a voltaic cell are connected with an external wire, electrons will flow in this wire from the cathode to the anode.

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Which of the following solids is commonly used as an inactive electrode in electrochemical cells?

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Consider the following balanced redox reaction 3CuO(s) + 2NH3(aq) N2(g) + 3H2O(l) + 3Cu(s) Which of the following statements is true?

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What is the E°cell for the cell represented by the combination of the following half-reactions? What is the E°<sub>cell</sub> for the cell represented by the combination of the following half-reactions?

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Consider the following balanced redox reaction Mn2+(aq) + S2O82-(aq) + 2H2O(l) MnO2(s) + 4H+(aq) + 2SO42-(aq) Which of the following statements is true?

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A voltaic cell consists of a Cd/Cd2+ electrode (E° = -0.40 V) and a Fe/Fe2+ electrode (E° = -0.44 V). If Ecell = 0 and the temperature is 25°C, what is the ratio [Fe2+]/[Cd2+]?

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A buried iron pipe can be protected against corrosion by connecting it to a rod of magnesium.

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A voltaic cell consists of an Au/Au3+ electrode (E° = 1.50 V) and a Cu/Cu2+ electrode (E° = 0.34 V). Calculate [Au3+] if [Cu2+] = 1.20 M and Ecell = 1.13 V at 25°C.

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The value of E°cell for the reaction 2Cr3+(aq) + 6Hg(l) 2Cr(s) + 3Hg22+(aq) Is 1.59 V. Calculate G° for the reaction.

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Which one of the following statements relating to the glass electrode is correct?

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In the shorthand notation for cells, a single vertical line represents a salt bridge.

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