Exam 21: Electrochemistry: Chemical Change and Electrical Work

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A voltaic cell prepared using zinc and iodine has the following cell notation. Zn(s) | Zn2+(aq) || I-(aq) | I2(s) | C(graphite) Which of the following equations correctly represents the balanced, spontaneous, cell reaction?

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A galvanic cell is constructed using the two hypothetical half-reactions A galvanic cell is constructed using the two hypothetical half-reactions   a. Write down the balanced equation representing the cell reaction. b. Calculate the standard potential of this cell, E°<sub>cell</sub>. c. Calculate <font face=symbol></font>G° for the cell reaction. a. Write down the balanced equation representing the cell reaction. b. Calculate the standard potential of this cell, E°cell. c. Calculate G° for the cell reaction.

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Which of the following conditions is most likely to apply to a fully-charged secondary cell?

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A voltaic cell is prepared using copper and silver. Its cell notation is shown below. Cu(s) | Cu2+(aq) || Ag+(aq) | Ag(s) Which of the following processes occurs at the cathode?

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Electrons are produced at the cathode of a voltaic cell.

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A voltaic cell consists of a Hg/Hg22+ electrode (E° = 0.85 V) and a Sn/Sn2+ electrode (E° = -0.14 V). Calculate [Sn2+] if [Hg22+] = 0.24 M and Ecell = 1.04 V at 25°C.

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Calculate E°cell and indicate whether the overall reaction shown is spontaneous or nonspontaneous. Calculate E°<sub>cell</sub><sub> </sub> and indicate whether the overall reaction shown is spontaneous or nonspontaneous.     Overall reaction: 4Al(s) + 3O<sub>2</sub>(g) + 12H<sup>+</sup>(aq) <font face=symbol></font> 4Al<sup>3+</sup>(aq) + 6H<sub>2</sub>O(l) Overall reaction: 4Al(s) + 3O2(g) + 12H+(aq) 4Al3+(aq) + 6H2O(l)

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What is the E°cell for the cell represented by the combination of the following half-reactions? ClO4-(aq) + 8H+(aq) + 8e- What is the E°<sub>cell</sub> for the cell represented by the combination of the following half-reactions? ClO<sub>4</sub><sup>-</sup>(aq) + 8H<sup>+</sup>(aq) + 8e<sup>-</sup>   Cl<sup>-</sup>(aq) + 4H<sub>2</sub>O(l) E°<sup> </sup>= 1.389 V VO<sub>2</sub><sup>+</sup>(aq) + 2H<sup>+</sup>(aq) + e<sup>-</sup>   VO<sup>+</sup>(aq) + H<sub>2</sub>O(l) E°<sup> </sup>= 0.991 V Cl-(aq) + 4H2O(l) E° = 1.389 V VO2+(aq) + 2H+(aq) + e- What is the E°<sub>cell</sub> for the cell represented by the combination of the following half-reactions? ClO<sub>4</sub><sup>-</sup>(aq) + 8H<sup>+</sup>(aq) + 8e<sup>-</sup>   Cl<sup>-</sup>(aq) + 4H<sub>2</sub>O(l) E°<sup> </sup>= 1.389 V VO<sub>2</sub><sup>+</sup>(aq) + 2H<sup>+</sup>(aq) + e<sup>-</sup>   VO<sup>+</sup>(aq) + H<sub>2</sub>O(l) E°<sup> </sup>= 0.991 V VO+(aq) + H2O(l) E° = 0.991 V

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A current of 1000. A flows for exactly 1 hour, through a cell in which the following reaction occurs at one of the electrodes. Mg2+ + 2e- Mg a. Calculate the charge, in coulombs, which passes through the circuit in this time. b. Calculate the theoretical mass of Mg (magnesium metal) which is produced in this time.

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A voltaic cell consists of a Ag/Ag+ electrode (E° = 0.80 V) and a Fe2+/Fe3+ electrode (E° = 0.77 V) with the following initial molar concentrations: [Fe2+] = 0.30 M; [Fe3+] = 0.10 M; [Ag+] = 0.30 M. What is the equilibrium concentration of Fe3+? (Assume the anode and cathode solutions are of equal volume, and a temperature of 25°C.)

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What product forms at the anode during the electrolysis of molten NaBr?

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Calculate the potential of a voltaic cell (E°cell) if it is required to do 5.43 × 10-3 kJ of work when a charge of 2.50 C is transferred.

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Examine the following half-reactions and select the strongest oxidizing agent among the substances. Examine the following half-reactions and select the strongest oxidizing agent among the substances.

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Consider the reaction of iodine with manganese dioxide Consider the reaction of iodine with manganese dioxide   The equilibrium constant for the overall reaction is 8.30 × 10<sup>-7</sup>. Calculate E°<sub>cell</sub> for the reaction at 25°C. The equilibrium constant for the overall reaction is 8.30 × 10-7. Calculate E°cell for the reaction at 25°C.

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What mass of copper will be deposited when 18.2 A are passed through a CuSO4 solution for 45.0 minutes?

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The line notation, Al(s) | Al3+(aq) || Co2+(aq) | Co(s), indicates that

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Manganese dioxide (MnO2) for use in dry cells is made by electrolyzing solutions of Mn2+, where the following reaction occurs at the anode: Mn2+(aq) + 2H2O(l) MnO2(s) + 4H+(aq) + 2e- Using a current of 100. amperes (A), how many hours will it take to produce 5.00 kg of MnO2, according to the above reaction?

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A salt bridge provides a path for electrons to move between the anode and cathode compartments of a voltaic cell.

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How many grams of oxygen gas will be produced in the electrolysis of water, for every gram of hydrogen gas formed? Reaction: 2H2O(l) 2H2(g) + O2(g)

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What is the value of the equilibrium constant for the cell reaction below at 25°C? E°cell = 0.30 V Sn2+(aq) + Fe(s) What is the value of the equilibrium constant for the cell reaction below at 25°C? E°<sub>cell</sub> = 0.30 V Sn<sup>2+</sup>(aq) + Fe(s)   Sn(s) + Fe<sup>2+</sup>(aq) Sn(s) + Fe2+(aq)

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