Exam 21: Electrochemistry: Chemical Change and Electrical Work
Exam 1: Keys to the Study of Chemistry79 Questions
Exam 2: The Components of Matter105 Questions
Exam 3: Stoichiometry of Formulas and Equations87 Questions
Exam 4: The Major Classes of Chemical Reactions124 Questions
Exam 5: Gases and the Kinetic-Molecular Theory115 Questions
Exam 6: Thermochemistry: Energy Flow and Chemical Change85 Questions
Exam 7: Quantum Theory and Atomic Structure83 Questions
Exam 8: Electron Configuration and Chemical Periodicity85 Questions
Exam 9: Models of Chemical Bonding74 Questions
Exam 10: The Shapes of Molecules109 Questions
Exam 11: Theories of Covalent Bonding58 Questions
Exam 12: Intermolecular Forces: Liquids, Solids, and Phase Changes111 Questions
Exam 13: The Properties of Mixtures: Solutions and Colloids105 Questions
Exam 14: Periodic Patterns in the Main Group Elements: Bonding, Structure, and Reactivity118 Questions
Exam 15: Organic Compounds and the Atomic Properties of Carbon118 Questions
Exam 16: Kinetics: Rates and Mechanisms of Chemical Reactions88 Questions
Exam 17: Equilibrium: the Extent of Chemical Reactions104 Questions
Exam 18: Acid-Base Equilibria103 Questions
Exam 19: Ionic Equilibria in Aqueous Systems119 Questions
Exam 20: Thermodynamics: Entropy, Free Energy, and the Direction of Chemical Reactions94 Questions
Exam 21: Electrochemistry: Chemical Change and Electrical Work102 Questions
Exam 22: The Elements in Nature and Industry57 Questions
Exam 23: The Transition Elements and Their Coordination Compounds92 Questions
Exam 24: Nuclear Reactions and Their Applications94 Questions
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A voltaic cell prepared using zinc and iodine has the following cell notation.
Zn(s) | Zn2+(aq) || I-(aq) | I2(s) | C(graphite)
Which of the following equations correctly represents the balanced, spontaneous, cell reaction?
(Multiple Choice)
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A galvanic cell is constructed using the two hypothetical half-reactions
a. Write down the balanced equation representing the cell reaction.
b. Calculate the standard potential of this cell, E°cell.
c. Calculate G° for the cell reaction.
(Essay)
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Which of the following conditions is most likely to apply to a fully-charged secondary cell?
(Multiple Choice)
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A voltaic cell is prepared using copper and silver. Its cell notation is shown below.
Cu(s) | Cu2+(aq) || Ag+(aq) | Ag(s)
Which of the following processes occurs at the cathode?
(Multiple Choice)
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A voltaic cell consists of a Hg/Hg22+ electrode (E° = 0.85 V) and a Sn/Sn2+ electrode (E° = -0.14 V). Calculate [Sn2+] if [Hg22+] = 0.24 M and Ecell = 1.04 V at 25°C.
(Multiple Choice)
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Calculate E°cell and indicate whether the overall reaction shown is spontaneous or nonspontaneous.
Overall reaction: 4Al(s) + 3O2(g) + 12H+(aq) 4Al3+(aq) + 6H2O(l)
(Multiple Choice)
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What is the E°cell for the cell represented by the combination of the following half-reactions? ClO4-(aq) + 8H+(aq) + 8e-
Cl-(aq) + 4H2O(l) E° = 1.389 V
VO2+(aq) + 2H+(aq) + e-
VO+(aq) + H2O(l) E° = 0.991 V
(Multiple Choice)
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A current of 1000. A flows for exactly 1 hour, through a cell in which the following reaction occurs at one of the electrodes.
Mg2+ + 2e- Mg
a. Calculate the charge, in coulombs, which passes through the circuit in this time.
b. Calculate the theoretical mass of Mg (magnesium metal) which is produced in this time.
(Essay)
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A voltaic cell consists of a Ag/Ag+ electrode (E° = 0.80 V) and a Fe2+/Fe3+ electrode (E° = 0.77 V) with the following initial molar concentrations: [Fe2+] = 0.30 M;
[Fe3+] = 0.10 M; [Ag+] = 0.30 M. What is the equilibrium concentration of Fe3+? (Assume the anode and cathode solutions are of equal volume, and a temperature of 25°C.)
(Multiple Choice)
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What product forms at the anode during the electrolysis of molten NaBr?
(Multiple Choice)
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Calculate the potential of a voltaic cell (E°cell) if it is required to do 5.43 × 10-3 kJ of work when a charge of 2.50 C is transferred.
(Multiple Choice)
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Examine the following half-reactions and select the strongest oxidizing agent among the substances. 
(Multiple Choice)
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Consider the reaction of iodine with manganese dioxide
The equilibrium constant for the overall reaction is 8.30 × 10-7. Calculate E°cell for the reaction at 25°C.
(Multiple Choice)
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What mass of copper will be deposited when 18.2 A are passed through a CuSO4 solution for 45.0 minutes?
(Multiple Choice)
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The line notation, Al(s) | Al3+(aq) || Co2+(aq) | Co(s), indicates that
(Multiple Choice)
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Manganese dioxide (MnO2) for use in dry cells is made by electrolyzing solutions of Mn2+, where the following reaction occurs at the anode:
Mn2+(aq) + 2H2O(l) MnO2(s) + 4H+(aq) + 2e-
Using a current of 100. amperes (A), how many hours will it take to produce 5.00 kg of MnO2, according to the above reaction?
(Short Answer)
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A salt bridge provides a path for electrons to move between the anode and cathode compartments of a voltaic cell.
(True/False)
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How many grams of oxygen gas will be produced in the electrolysis of water, for every gram of hydrogen gas formed? Reaction: 2H2O(l) 2H2(g) + O2(g)
(Multiple Choice)
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What is the value of the equilibrium constant for the cell reaction below at 25°C? E°cell = 0.30 V Sn2+(aq) + Fe(s)
Sn(s) + Fe2+(aq)
(Multiple Choice)
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