Exam 21: Electrochemistry: Chemical Change and Electrical Work

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Examine the following half-reactions and select the weakest oxidizing agent among the species listed. AuBr4-(aq)+ 3e- Examine the following half-reactions and select the weakest oxidizing agent among the species listed. AuBr<sub>4</sub><sup>-</sup>(aq)+ 3e<sup>-</sup>   Au(s)+ 4Br<sup>-</sup>(aq);E° = 0.854 V Mn<sup>2+</sup>(aq)+ 2e<sup>-</sup>   Mn(s);E° = -1.185 V K<sup>+</sup>(aq)+ e<sup>-</sup>   K(s);E° = -2.931 V F<sub>2</sub>O(aq)+ 2H<sup>+</sup>(aq)+ 4e<sup>-</sup>   2F<sup>-</sup>(aq)+ H<sub>2</sub>O(l);E° = 2.153 V Au(s)+ 4Br-(aq);E° = 0.854 V Mn2+(aq)+ 2e- Examine the following half-reactions and select the weakest oxidizing agent among the species listed. AuBr<sub>4</sub><sup>-</sup>(aq)+ 3e<sup>-</sup>   Au(s)+ 4Br<sup>-</sup>(aq);E° = 0.854 V Mn<sup>2+</sup>(aq)+ 2e<sup>-</sup>   Mn(s);E° = -1.185 V K<sup>+</sup>(aq)+ e<sup>-</sup>   K(s);E° = -2.931 V F<sub>2</sub>O(aq)+ 2H<sup>+</sup>(aq)+ 4e<sup>-</sup>   2F<sup>-</sup>(aq)+ H<sub>2</sub>O(l);E° = 2.153 V Mn(s);E° = -1.185 V K+(aq)+ e- Examine the following half-reactions and select the weakest oxidizing agent among the species listed. AuBr<sub>4</sub><sup>-</sup>(aq)+ 3e<sup>-</sup>   Au(s)+ 4Br<sup>-</sup>(aq);E° = 0.854 V Mn<sup>2+</sup>(aq)+ 2e<sup>-</sup>   Mn(s);E° = -1.185 V K<sup>+</sup>(aq)+ e<sup>-</sup>   K(s);E° = -2.931 V F<sub>2</sub>O(aq)+ 2H<sup>+</sup>(aq)+ 4e<sup>-</sup>   2F<sup>-</sup>(aq)+ H<sub>2</sub>O(l);E° = 2.153 V K(s);E° = -2.931 V F2O(aq)+ 2H+(aq)+ 4e- Examine the following half-reactions and select the weakest oxidizing agent among the species listed. AuBr<sub>4</sub><sup>-</sup>(aq)+ 3e<sup>-</sup>   Au(s)+ 4Br<sup>-</sup>(aq);E° = 0.854 V Mn<sup>2+</sup>(aq)+ 2e<sup>-</sup>   Mn(s);E° = -1.185 V K<sup>+</sup>(aq)+ e<sup>-</sup>   K(s);E° = -2.931 V F<sub>2</sub>O(aq)+ 2H<sup>+</sup>(aq)+ 4e<sup>-</sup>   2F<sup>-</sup>(aq)+ H<sub>2</sub>O(l);E° = 2.153 V 2F-(aq)+ H2O(l);E° = 2.153 V

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When the following redox equation is balanced with smallest whole number coefficients,the coefficient for nitrogen dioxide will be _____. I2(s)+ HNO3(aq) →\to HIO3(aq)+ NO2(g)+ H2O(l)

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The Downs cell is used in the electrolysis of

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A battery that cannot be recharged is a

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A primary battery is one which can be recharged.

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Consider the reaction of iodine with manganese dioxide 3I2(s)+ 2MnO2(s)+ 8OH-(aq)  Consider the reaction of iodine with manganese dioxide 3I<sub>2</sub>(s)+ 2MnO<sub>2</sub>(s)+ 8OH<sup>-</sup>(aq)   6I<sup>-</sup>(aq)+ 2MnO<sub>4</sub><sup>-</sup>(aq)+ 4H<sub>2</sub>O(l) The equilibrium constant for the overall reaction is 8.30  \times  10<sup>-7</sup>.Calculate E°<sub>cell</sub> for the reaction at 25°C. 6I-(aq)+ 2MnO4-(aq)+ 4H2O(l) The equilibrium constant for the overall reaction is 8.30 ×\times 10-7.Calculate E°cell for the reaction at 25°C.

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Which one of the following statements relating to the glass electrode is correct?

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Given that E° for X + e- →\to Y is greater than E° for A + 2e- →\to B,it is correct to say that,under standard conditions

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A current of 1000.A flows for exactly 1 hour,through a cell in which the following reaction occurs at one of the electrodes. Mg2+ + 2e- →\to Mg a.Calculate the charge,in coulombs,which passes through the circuit in this time. b.Calculate the theoretical mass of Mg (magnesium metal)which is produced in this time.

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When metal A is placed in a solution of metal ions B2+,a reaction occurs between A and B2+,and metal ions A2+ appear in the solution.When metal B is placed in acid solution,gas bubbles form on its surface.When metal A is placed in a solution of metal ions C2+,no reaction occurs.Which of the following reactions would not occur spontaneously?

(Multiple Choice)
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What is the E°cell for the cell represented by the combination of the following half-reactions? ClO4-(aq)+ 8H+(aq)+ 8e- What is the E°<sub>cell</sub> for the cell represented by the combination of the following half-reactions? ClO<sub>4</sub><sup>-</sup>(aq)+ 8H<sup>+</sup>(aq)+ 8e<sup>-</sup>   Cl<sup>-</sup>(aq)+ 4H<sub>2</sub>O(l);E° = 1.389 V VO<sub>2</sub><sup>+</sup>(aq)+ 2H<sup>+</sup>(aq)+ e<sup>-</sup>   VO<sup>+</sup>(aq)+ H<sub>2</sub>O(l);E° = 0.991 V Cl-(aq)+ 4H2O(l);E° = 1.389 V VO2+(aq)+ 2H+(aq)+ e- What is the E°<sub>cell</sub> for the cell represented by the combination of the following half-reactions? ClO<sub>4</sub><sup>-</sup>(aq)+ 8H<sup>+</sup>(aq)+ 8e<sup>-</sup>   Cl<sup>-</sup>(aq)+ 4H<sub>2</sub>O(l);E° = 1.389 V VO<sub>2</sub><sup>+</sup>(aq)+ 2H<sup>+</sup>(aq)+ e<sup>-</sup>   VO<sup>+</sup>(aq)+ H<sub>2</sub>O(l);E° = 0.991 V VO+(aq)+ H2O(l);E° = 0.991 V

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Consider the reaction of iodine with manganese dioxide 3I2(s)+ 2MnO2(s)+ 8OH-(aq)  Consider the reaction of iodine with manganese dioxide 3I<sub>2</sub>(s)+ 2MnO<sub>2</sub>(s)+ 8OH<sup>-</sup>(aq)   6I<sup>-</sup>(aq)+ 2MnO<sub>4</sub><sup>-</sup>(aq)+ 4H<sub>2</sub>O(l) The equilibrium constant for the overall reaction is 8.30  \times  10<sup>-7</sup>.Calculate  \Delta G° for the reaction at 25°C. 6I-(aq)+ 2MnO4-(aq)+ 4H2O(l) The equilibrium constant for the overall reaction is 8.30 ×\times 10-7.Calculate Δ\Delta G° for the reaction at 25°C.

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How many grams of oxygen gas will be produced in the electrolysis of water,for every gram of hydrogen gas formed? Reaction: 2H2O(l) →\to 2H2(g)+ O2(g)

(Multiple Choice)
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When the following redox equation is balanced with smallest whole number coefficients,the coefficient for the hydrogen sulfate ion will be ______. Al(s)+ HSO4-(aq)+ OH-(aq) →\to Al2O3(s)+ S2-(aq)+ H2O(l)

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For the reaction occurring in a voltaic (galvanic)cell, Δ\Delta G > 0.

(True/False)
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Examine the following half-reactions and select the strongest oxidizing agent among the species listed. Cr2+(aq)+ 2e- Examine the following half-reactions and select the strongest oxidizing agent among the species listed. Cr<sup>2+</sup>(aq)+ 2e<sup>-</sup>   Cr(s);E° = -0.913 V Fe<sup>2+</sup>(aq)+ 2e<sup>-</sup>   Fe(s);E° = -0.447 V Sr<sup>2+</sup>(aq)+ 2e<sup>-</sup>   Sr(s);E° = -2.89 V Co<sup>2+</sup>(aq)+ 2e<sup>-</sup>   Co(s);E° = -0.28 V Cr(s);E° = -0.913 V Fe2+(aq)+ 2e- Examine the following half-reactions and select the strongest oxidizing agent among the species listed. Cr<sup>2+</sup>(aq)+ 2e<sup>-</sup>   Cr(s);E° = -0.913 V Fe<sup>2+</sup>(aq)+ 2e<sup>-</sup>   Fe(s);E° = -0.447 V Sr<sup>2+</sup>(aq)+ 2e<sup>-</sup>   Sr(s);E° = -2.89 V Co<sup>2+</sup>(aq)+ 2e<sup>-</sup>   Co(s);E° = -0.28 V Fe(s);E° = -0.447 V Sr2+(aq)+ 2e- Examine the following half-reactions and select the strongest oxidizing agent among the species listed. Cr<sup>2+</sup>(aq)+ 2e<sup>-</sup>   Cr(s);E° = -0.913 V Fe<sup>2+</sup>(aq)+ 2e<sup>-</sup>   Fe(s);E° = -0.447 V Sr<sup>2+</sup>(aq)+ 2e<sup>-</sup>   Sr(s);E° = -2.89 V Co<sup>2+</sup>(aq)+ 2e<sup>-</sup>   Co(s);E° = -0.28 V Sr(s);E° = -2.89 V Co2+(aq)+ 2e- Examine the following half-reactions and select the strongest oxidizing agent among the species listed. Cr<sup>2+</sup>(aq)+ 2e<sup>-</sup>   Cr(s);E° = -0.913 V Fe<sup>2+</sup>(aq)+ 2e<sup>-</sup>   Fe(s);E° = -0.447 V Sr<sup>2+</sup>(aq)+ 2e<sup>-</sup>   Sr(s);E° = -2.89 V Co<sup>2+</sup>(aq)+ 2e<sup>-</sup>   Co(s);E° = -0.28 V Co(s);E° = -0.28 V

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If the electrodes of a voltaic cell are connected with an external wire,electrons will flow in this wire from the cathode to the anode.

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