Exam 21: Electrochemistry: Chemical Change and Electrical Work
Exam 1: Keys to the Study of Chemistry66 Questions
Exam 2: The Components of Matter91 Questions
Exam 3: Stoichiometry of Formulas and Equations90 Questions
Exam 4: Three Major Classes of Chemical Reactions84 Questions
Exam 5: Gases and the Kinetic-Molecular Theory93 Questions
Exam 6: Thermochemistry: Energy Flow and Chemical Change71 Questions
Exam 7: Quantum Theory and Atomic Structure72 Questions
Exam 8: Electron Configuration and Chemical Periodicity70 Questions
Exam 9: Models of Chemical Bonding60 Questions
Exam 10: The Shapes of Molecules94 Questions
Exam 11: Theories of Covalent Bonding49 Questions
Exam 12: Intermolecular Forces: Liquids,solids,and Phase Changes89 Questions
Exam 13: The Properties of Solutions73 Questions
Exam 14: The Main-Group Elements: Applying Principles of Bonding and Structure58 Questions
Exam 15: Organic Compounds and the Atomic Properties of Carbon95 Questions
Exam 16: Kinetics: Rates and Mechanisms of Chemical Reactions76 Questions
Exam 17: Equilibrium: the Extent of Chemical Reactions85 Questions
Exam 18: Acid-Base Equilibria90 Questions
Exam 19: Ionic Equilibria in Aqueous Systems96 Questions
Exam 20: Thermodynamics: Entropy, free Energy, and the Direction of Chemical Reactions84 Questions
Exam 21: Electrochemistry: Chemical Change and Electrical Work97 Questions
Exam 22: The Transition Elements and Their Coordination Compounds72 Questions
Exam 23: Nuclear Reactions and Their Applications75 Questions
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A voltaic cell prepared using aluminum and nickel has the following cell notation.
Al(s)| Al3+(aq)|| Ni2+(aq)| Ni(s)
Which of the following reactions occurs at the anode?
(Multiple Choice)
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In the shorthand notation for cells,a single vertical line represents a salt bridge.
(True/False)
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A voltaic cell prepared using aluminum and nickel has the following cell notation.
Al(s)| Al3+(aq)|| Ni2+(aq)| Ni(s)
Which of the following represents the correctly balanced spontaneous reaction equation for the cell?
(Multiple Choice)
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When the following redox equation is balanced with smallest whole number coefficients,the coefficient for Sn(OH)3- will be _____.
Bi(OH)3(s)+ Sn(OH)3-(aq) Sn(OH)62-(aq)+ Bi(s)(basic solution)
(Multiple Choice)
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A current of 250.A flows for 24.0 hours at an anode where the reaction occurring is
Mn2+(aq)+ 2H2O(l) MnO2(s)+ 4H+(aq)+ 2e-
What mass of MnO2 is deposited at this anode?
(Multiple Choice)
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What is the E°cell for the cell represented by the combination of the following half-reactions?
2Hg2+(aq)+ 2e-
Hg22+(aq);E°= 0.92 V
Cr3+ (aq)+ 3e-
Cr(s);E°= -0.74 V
(Multiple Choice)
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When the following redox equation is balanced with smallest whole number coefficients,the coefficient for zinc will be _____.
Zn(s)+ ReO4-(aq) Re(s)+ Zn2+(aq)(acidic solution)
(Multiple Choice)
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Which,if any,of the following metals would be capable of acting as a sacrificial anode when used with iron pipe? E°Fe = -0.44 V;all E° values refer to the M2+/M half-cell reactions.
(Multiple Choice)
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A salt bridge provides a path for electrons to move between the anode and cathode compartments of a voltaic cell.
(True/False)
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When the following redox equation is balanced with smallest whole number coefficients,the coefficient for the iodide ion will be _____.
I-(aq)+ NO3-(aq) NO(g)+ I2(s)(acidic solution)
(Multiple Choice)
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A much-studied cell in electrochemistry has the following cell notation:
Ag(s)| AgCl(s)| HCl(aq)| H2(g)| Pt(s)
Bearing in mind that HCl(aq)consists of H+(aq)and Cl-(aq),and that this solution is in contact with both electrodes (there is no salt bridge),write down balanced equations for
a.the anode half-reaction.
b.the cathode half-reaction.
c.the cell reaction.
(Essay)
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What is the value of the equilibrium constant for the cell reaction below at 25°C? E°cell = 0.61 V
2Cr(s)+ 3Pb2+(aq)
3Pb(s)+ 2Cr3+(aq)
(Multiple Choice)
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Calculate E°cell and indicate whether the overall reaction shown is spontaneous or nonspontaneous.
O2(g)+ 4H+(aq)+ 4e-
2H2O(l);E° = 1.229 V
Al3+(aq)+ 3e-
Al(s);E° = -1.662 V
Overall reaction:
4Al(s)+ 3O2(g)+ 12H+(aq) 4Al3+(aq)+ 6H2O(l)
(Multiple Choice)
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Explain what is meant by a fuel cell.Provide a balanced equation to represent the reaction in any fuel cell of your choice.
(Essay)
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a.Write a balanced equation to represent the overall reaction you would expect to occur in the electrolysis of molten KCl.
b.Write a balanced equation to represent the overall reaction you would expect to occur in the electrolysis of aqueous KCl.
c.Clearly explain why the products of the two processes are not the same.
(Essay)
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Which of the following conditions is most likely to apply to a fully-charged secondary cell?
(Multiple Choice)
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Consider the following balanced redox reaction
Mn2+(aq)+ S2O82-(aq)+ 2H2O(l) MnO2(s)+ 4H+(aq)+ 2SO42-(aq)
Which of the following statements is true?
(Multiple Choice)
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What mass of silver will be formed when 15.0 A are passed through molten AgCl for 25.0 minutes?
(Multiple Choice)
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Which one of the following statements about electrochemical cells is correct?
(Multiple Choice)
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