Exam 21: Electrochemistry: Chemical Change and Electrical Work

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A voltaic cell prepared using aluminum and nickel has the following cell notation. Al(s)| Al3+(aq)|| Ni2+(aq)| Ni(s) Which of the following reactions occurs at the anode?

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In the shorthand notation for cells,a single vertical line represents a salt bridge.

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A voltaic cell prepared using aluminum and nickel has the following cell notation. Al(s)| Al3+(aq)|| Ni2+(aq)| Ni(s) Which of the following represents the correctly balanced spontaneous reaction equation for the cell?

(Multiple Choice)
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When the following redox equation is balanced with smallest whole number coefficients,the coefficient for Sn(OH)3- will be _____. Bi(OH)3(s)+ Sn(OH)3-(aq) →\to Sn(OH)62-(aq)+ Bi(s)(basic solution)

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A current of 250.A flows for 24.0 hours at an anode where the reaction occurring is Mn2+(aq)+ 2H2O(l) →\to MnO2(s)+ 4H+(aq)+ 2e- What mass of MnO2 is deposited at this anode?

(Multiple Choice)
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What is the E°cell for the cell represented by the combination of the following half-reactions? 2Hg2+(aq)+ 2e- What is the E°<sub>cell</sub> for the cell represented by the combination of the following half-reactions? 2Hg<sup>2+</sup>(aq)+ 2e<sup>-</sup>   Hg<sub>2</sub><sup>2+</sup>(aq);E°= 0.92 V Cr<sup>3+</sup> (aq)+ 3e<sup>-</sup>   Cr(s);E°= -0.74 V Hg22+(aq);E°= 0.92 V Cr3+ (aq)+ 3e- What is the E°<sub>cell</sub> for the cell represented by the combination of the following half-reactions? 2Hg<sup>2+</sup>(aq)+ 2e<sup>-</sup>   Hg<sub>2</sub><sup>2+</sup>(aq);E°= 0.92 V Cr<sup>3+</sup> (aq)+ 3e<sup>-</sup>   Cr(s);E°= -0.74 V Cr(s);E°= -0.74 V

(Multiple Choice)
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When the following redox equation is balanced with smallest whole number coefficients,the coefficient for zinc will be _____. Zn(s)+ ReO4-(aq) →\to Re(s)+ Zn2+(aq)(acidic solution)

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Which,if any,of the following metals would be capable of acting as a sacrificial anode when used with iron pipe? E°Fe = -0.44 V;all E° values refer to the M2+/M half-cell reactions.

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A salt bridge provides a path for electrons to move between the anode and cathode compartments of a voltaic cell.

(True/False)
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When the following redox equation is balanced with smallest whole number coefficients,the coefficient for the iodide ion will be _____. I-(aq)+ NO3-(aq) →\to NO(g)+ I2(s)(acidic solution)

(Multiple Choice)
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A much-studied cell in electrochemistry has the following cell notation: Ag(s)| AgCl(s)| HCl(aq)| H2(g)| Pt(s) Bearing in mind that HCl(aq)consists of H+(aq)and Cl-(aq),and that this solution is in contact with both electrodes (there is no salt bridge),write down balanced equations for a.the anode half-reaction. b.the cathode half-reaction. c.the cell reaction.

(Essay)
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What is the value of the equilibrium constant for the cell reaction below at 25°C? E°cell = 0.61 V 2Cr(s)+ 3Pb2+(aq) What is the value of the equilibrium constant for the cell reaction below at 25°C? E°<sub>cell</sub> = 0.61 V 2Cr(s)+ 3Pb<sup>2+</sup>(aq)   3Pb(s)+ 2Cr<sup>3+</sup>(aq) 3Pb(s)+ 2Cr3+(aq)

(Multiple Choice)
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Calculate E°cell and indicate whether the overall reaction shown is spontaneous or nonspontaneous. O2(g)+ 4H+(aq)+ 4e-  Calculate E°<sub>cell </sub>and indicate whether the overall reaction shown is spontaneous or nonspontaneous. O<sub>2</sub>(g)+ 4H<sup>+</sup>(aq)+ 4e<sup>-</sup>   2H<sub>2</sub>O(l);E° = 1.229 V Al<sup>3+</sup>(aq)+ 3e<sup>-</sup>   Al(s);E° = -1.662 V Overall reaction: 4Al(s)+ 3O<sub>2</sub>(g)+ 12H<sup>+</sup>(aq)  \to  4Al<sup>3+</sup>(aq)+ 6H<sub>2</sub>O(l) 2H2O(l);E° = 1.229 V Al3+(aq)+ 3e-  Calculate E°<sub>cell </sub>and indicate whether the overall reaction shown is spontaneous or nonspontaneous. O<sub>2</sub>(g)+ 4H<sup>+</sup>(aq)+ 4e<sup>-</sup>   2H<sub>2</sub>O(l);E° = 1.229 V Al<sup>3+</sup>(aq)+ 3e<sup>-</sup>   Al(s);E° = -1.662 V Overall reaction: 4Al(s)+ 3O<sub>2</sub>(g)+ 12H<sup>+</sup>(aq)  \to  4Al<sup>3+</sup>(aq)+ 6H<sub>2</sub>O(l) Al(s);E° = -1.662 V Overall reaction: 4Al(s)+ 3O2(g)+ 12H+(aq) →\to 4Al3+(aq)+ 6H2O(l)

(Multiple Choice)
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Explain what is meant by a fuel cell.Provide a balanced equation to represent the reaction in any fuel cell of your choice.

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a.Write a balanced equation to represent the overall reaction you would expect to occur in the electrolysis of molten KCl. b.Write a balanced equation to represent the overall reaction you would expect to occur in the electrolysis of aqueous KCl. c.Clearly explain why the products of the two processes are not the same.

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Which of the following conditions is most likely to apply to a fully-charged secondary cell?

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Consider the following balanced redox reaction Mn2+(aq)+ S2O82-(aq)+ 2H2O(l) →\to MnO2(s)+ 4H+(aq)+ 2SO42-(aq) Which of the following statements is true?

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What mass of silver will be formed when 15.0 A are passed through molten AgCl for 25.0 minutes?

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Which one of the following statements about electrochemical cells is correct?

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Electrons are produced at the cathode of a voltaic cell.

(True/False)
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