Exam 17: Aqueous Ionic Equilibrium

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A sample contains Ba3(PO4)2, HgS,AgCl,NH4Br,and CoS.Identify the precipitate after the addition of 6 M HCl; then H2S and 0.2 M HCl; and then OH- to a pH of 8.

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A solution contains 2.2 × 10-3 M in Cu2+ and 0.33 M in LiCN.If the Kf for Cu(CN)42- is 1.0 × 1025,how much copper ion remains at equilibrium?

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Formic acid (HCO2H,Ka = 1.8 × 10-4)is the principal component in the venom of stinging ants.What is the molarity of a formic acid solution if 25.00 mL of the formic acid solution requires 44.80 mL of 0.0567 M NaOH to reach the equivalence point?

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A 400.0 mL sample of 0.10 M Ba(OH)2 is titrated with 0.10 M HBr.Determine the pH of the solution before the addition of any HBr.

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Give the expression for the solubility product constant for PbI2.

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Which of the following compounds will be more soluble in acidic solution than in pure water?

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What is the approximate pH at the equivalence point of a weak acid-strong base titration if 25 mL of aqueous formic acid requires 29.80 mL of 0.3567 M NaOH to reach the equivalence point? Ka =1.8 × 10-4 What is the approximate pH at the equivalence point of a weak acid-strong base titration if 25 mL of aqueous formic acid requires 29.80 mL of 0.3567 M NaOH to reach the equivalence point? K<sub>a</sub> =1.8 × 10<sup>-4</sup>   for formic acid. for formic acid.

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Determine the molar solubility for Zn(OH)2 in pure water.Ksp for Zn(OH)2 is 3.00 × 10-17.

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Which of the following compounds will have the highest molar solubility in pure water?

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What is the pH at the equivalence point of a weak base-strong acid titration if 20.00 mL of NaOCl requires 28.30 mL of 0.50 M HCl to reach the equivalence point? Ka = 3.0 × 10-8 for HOCl.

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Match the following.
pH = 7
equivalence point of a weak base/strong acid titration
pH = pKa2
equivalence point of a weak acid/strong base titration
pH = pKa
half-way to equivalence point of a weak acid/strong base titration
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pH = 7
equivalence point of a weak base/strong acid titration
pH = pKa2
equivalence point of a weak acid/strong base titration
pH = pKa
half-way to equivalence point of a weak acid/strong base titration
pH < 7
3/4 of the way to second equivalence point of a diprotic acid/strong base titration
pH > 7
equivalence point of a strong acid/strong base titration
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Which of the following compounds will have the highest molar solubility in pure water?

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Define a buffer.

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A sample contains Ca3(PO4)2, HgS,AgCl,NH4Cl,and NiS.Identify the soluble compound after the addition of 6 M HCl; then H2S and 0.2 M HCl; then OH- to a pH of 8; and then (NH4)2HPO4 with NH3.

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Identify the pH of normal blood.

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A 1.0 L buffer solution is 0.060 M HC2H3O2 and 0.250 M LiC2H3O2.Which of the following actions will destroy the buffer?

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Calculate the pH of a solution that is 0.210 M in nitrous acid (HNO2)and 0.290 M in potassium nitrite (KNO2).The acid dissociation constant of nitrous acid is 4.50 × 10-4.

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Determine the molar solubility of AgBr in a solution containing 0.200 M NaBr. Ksp (AgBr)= 7.7 × 10-13.

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Determine the molar solubility of Fe(OH)2 in pure water.Ksp for Fe(OH)2= 4.87 × 10-17.

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A sample contains Ca3(PO4)2, HgS,AgCl,NH4Br,and CoS.Identify the precipitate after the addition of 6 M HCl,then H2S and 0.2 M HCl.

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