Exam 17: Aqueous Ionic Equilibrium

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What is the pH of a solution made by mixing 10.00 mL of 0.10 M acetic acid with 10.00 mL of 0.10 M KOH? Assume that the volumes of the solutions are additive.Ka = 1.8 × 10-5 for CH3CO2H.

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Identify the indicator that has two endpoints.

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Identify the indicator that can be used at the lowest pH.

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What is the molar solubility of zinc oxalate ( ZnC2O4 )in water? The solubility-product constant for ZnC2O4 is 2.7 × 10-8 at 25°C.

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Determine the solubility of the ions that is calculated from the Ksp for Na3PO4.

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A 25.0 mL sample of 0.150 M hydrofluoric acid is titrated with a 0.150 M NaOH solution.What is the pH at the equivalence point? The Ka of hydrofluoric acid is 3.5 × 10-4.

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Describe the solubility of Al(OH)3 with respect to pH.

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The molar solubility of Ag2S is 1.26 × 10-16 M in pure water.Calculate the Ksp for Ag2S.

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Which of the following is TRUE?

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Give the expression for the solubility product constant for Cr2(CO3)3.

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Identify the compound that is acid-insoluble.

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You wish to prepare an HC2H3O2 buffer with a pH of 4.14.If the pKa of is 4.74,what ratio of C2H3O2-/HC2H3O2 must you use?

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Calculate the pH of a solution that is 0.295 M in sodium formate (NaHCO2)and 0.205 M in formic acid (HCO2H).The Ka of formic acid is 1.77 × 10-4.

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What is the [CH3CO2-] / [CH3CO2H] ratio necessary to make a buffer solution with a pH of 4.34? Ka = 1.8 × 10-5 for CH3CO2H.

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A sample contains Ca3(PO4)2, HgS,AgCl,NH4Cl,and MnS.Identify the precipitate after the addition of 6 M HCl; then H2S and 0.2 M HCl; then OH- to a pH of 8; and then (NH4)2HPO4 with NH3.

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Calculate the pH of a buffer that is 0.145 M HC2H3O2 and 0.202 M KC2H3O2.The Ka for HC2H3O2 is 1.8 × 10-5.

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Which of the following acids (listed with Ka values)and their conjugate base would form a buffer with a pH of 2.34?

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Calculate K. AgI(s)⇌ Ag+(aq)+ I-(aq)Ksp = 8.5 × 10-17 Ag+(aq)+ 2 NH3(aq)⇌ Ag(NH3)22+(aq)Kf = 1.7 × 107 AgI(s)+ 2 NH3(aq)⇌ Ag(NH3)22+(aq)+ I-(aq)K = ?

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Calculate the pH of a buffer that is 0.060 M HF and 0.030 M KF.The Ka for HF is 3.5 × 10-4.

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A 1.00 L buffer solution is 0.150 M in HC7H5O2 and 0.250 M in LiC7H5O2.Calculate the pH of the solution after the addition of 100.0 mL of 1.00 M HCl.The Ka for HC7H5O2 is 6.5 × 10-5.

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