Exam 6: Thermochemistry

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Hydrogen peroxide decomposes to water and oxygen at constant pressure by the following reaction: 2 H2O2(l)→ 2 H2O(l)+ O2(g)ΔH = -196 kJ Calculate the value of q (kJ)in this exothermic reaction when 4.60 g of hydrogen peroxide decomposes at constant pressure.

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Define heat capacity.

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When 5.50 g of Ba(s)is added to 100.00 g of water in a container open to the atmosphere,the reaction shown below occurs and the temperature of the resulting solution rises from 22.00°C to 61.16°C.If the specific heat of the solution is 4.18 J/(g ∙ °C),calculate When 5.50 g of Ba(s)is added to 100.00 g of water in a container open to the atmosphere,the reaction shown below occurs and the temperature of the resulting solution rises from 22.00°C to 61.16°C.If the specific heat of the solution is 4.18 J/(g ∙ °C),calculate   for the reaction,as written. Ba(s)+ 2 H<sub>2</sub>O(l)→ Ba(OH)<sub>2</sub>(aq)+ H<sub>2</sub>(g)   = ? for the reaction,as written. Ba(s)+ 2 H2O(l)→ Ba(OH)2(aq)+ H2(g) When 5.50 g of Ba(s)is added to 100.00 g of water in a container open to the atmosphere,the reaction shown below occurs and the temperature of the resulting solution rises from 22.00°C to 61.16°C.If the specific heat of the solution is 4.18 J/(g ∙ °C),calculate   for the reaction,as written. Ba(s)+ 2 H<sub>2</sub>O(l)→ Ba(OH)<sub>2</sub>(aq)+ H<sub>2</sub>(g)   = ? = ?

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Choose the reaction that illustrates ΔH°f for KHCO3.

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Define specific heat capacity.

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The specific heat of copper is 0.385 J/(g ∙ °C).If 34.2 g of copper,initially at 25.0°C,absorbs 4.689 kJ,what will be the final temperature of the copper?

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According to the following thermochemical equation,what mass of H2O (in g)must form in order to produce 975 kJ of energy? SiO2(s)+ 4 HF(g)→ SiF4(g)+ 2 H2O(l)ΔH°rxn = -184 kJ

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Calculate the change in internal energy (ΔE)for a system that is absorbing 35.8 kJ of heat and is expanding from 8.00 to 16.0 L in volume at 2.00 atm.(Remember that 101.3 J = 1 L∙atm)

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Energy that is associated with the position or composition of an object is called

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A balloon is inflated from 0.0100 L to 0.600 L against an external pressure of 10.00 atm.How much work is done in joules? 101.3 J = 1 L × atm

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What is the enthalpy change (in kJ)of a chemical reaction that raises the temperature of 250.0 mL of solution having a density of 1.25 g/ml by 9.20°C? (The specific heat of the solution is 3.74 J/g ∙ K.)

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Two solutions,initially at 24.60°C,are mixed in a coffee cup calorimeter.When a 100.0 mL volume of 0.100 M AgNO3 solution is mixed with a 100.0 mL sample of 0.200 M NaCl solution,the temperature in the calorimeter rises to 25.30°C.Determine the DH°rxn for the reaction as written below.Assume that the density and heat capacity of the solutions is the same as that of water. NaCl(aq)+ AgNO3(aq)→ AgCl(s)+ NaNO3(aq)DH°rxn = ?

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Use the standard reaction enthalpies given below to determine ΔH°rxn for the following reaction: 2 S(s)+ 3 O2(g)→ 2 SO3(g)ΔH°rxn = ? Given: SO2(g)→ S(s)+ O2(g)ΔH°rxn = +296.8 kJ 2 SO2(g)+ O2(g)→ 2 SO3(g)ΔH°rxn = -197.8 kJ

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Choose the thermochemical equation that illustrates ΔH°f for Li2SO4.

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Which of the following statements is TRUE?

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Calculate the change internal energy (ΔE)for a system that is giving off 65.0 kJ of heat and is performing 855 J of work on the surroundings.

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A 6.55 g sample of aniline (C6H5NH2,molar mass = 93.13 g/mol)was combusted in a bomb calorimeter.If the temperature rose by 32.9°C,use the information below to determine the heat capacity of the calorimeter. 4 C6H5NH2(l)+ 35 O2(g)→ 24 CO2(g)+ 14 H2O(g)+ 4 NO2(g) ΔH°rxn = -1.28 × 104 kJ

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The law of ________ states that energy that can be neither created nor destroyed.

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According to the following reaction,how much energy is required to decompose 56.0 kg of Fe3O4? The molar mass of Fe3O4 is 231.55 g/mol. Fe3O4(s)→ 3 Fe(s)+ 2 O2(g)ΔH°rxn = +1118 kJ

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When 50.0 mL of 0.400 M Ca(NO3)2 is added to 50.0 mL of 0.800 M NaF,CaF2 precipitates,as shown in the net ionic equation below.The initial temperature of both solutions is 22.0°C.Assuming that the reaction goes to completion,and that the resulting solution has a mass of 100.00 g and a specific heat of 4.18 J/(g ∙ °C),calculate the final temperature of the solution. Ca2+(aq)+ 2 F-(aq)→ CaF2(s)ΔH° = -11.5 kJ

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