Exam 6: Thermochemistry

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Using the following thermochemical equation,determine the amount of heat produced per kg of CO2 formed during the combustion of benzene (C6H6). 2 C6H6(l)+ 15 O2(g)→ 12 CO2(g)+ 6 H2O(g)ΔH°rxn = -6278 kJ

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The specific heat capacity of liquid water is 4.18 J/g-K.How many joules of heat are needed to raise the temperature of 6.00 g of water from 36.0°C to 75.0°C?

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Which of the following processes is endothermic?

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Define work.

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Calculate the change in internal energy (ΔE)for a system that is giving off 25.0 kJ of heat and is changing from 12.00 L to 6.00 L in volume at 1.50 atm pressure.(Remember that 101.3 J = 1 L∙atm)

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Match the following.
energy associated with the temperature of an object
potential energy
energy associated with the motion of an object
chemical energy
energy associated with the position of an object
thermal energy
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Responses:
energy associated with the temperature of an object
potential energy
energy associated with the motion of an object
chemical energy
energy associated with the position of an object
thermal energy
energy associated with the relative positions of electrons and nuclei in atoms and molecules
kinetic energy
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When 1.00 mol of benzene is vaporized at a constant pressure of 1.00 atm and at its normal boiling point of 80.1°C,33.9 kJ are absorbed and PΔV for the vaporization process is equal to 2.90 kJ,then

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How much heat is absorbed/released when 30.00 g of NH3(g)react in the presence of excess How much heat is absorbed/released when 30.00 g of NH<sub>3</sub>(g)react in the presence of excess   (g)to produce NO(g)and H<sub>2</sub>O(l)according to the following chemical equation? 4 NH<sub>3</sub>(g)+ 5 O<sub>2</sub>(g)→ 4 NO(g)+ 6 H<sub>2</sub>O(l)ΔH° = 1168 kJ (g)to produce NO(g)and H2O(l)according to the following chemical equation? 4 NH3(g)+ 5 O2(g)→ 4 NO(g)+ 6 H2O(l)ΔH° = 1168 kJ

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Which of the following processes is exothermic?

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When 1.365 g of anthracene,C14H10,is combusted in a bomb calorimeter that has a water jacket containing 500.0 g of water,the temperature of the water increases by 25.89°C.Assuming that the specific heat of water is 4.18 J/(g ∙ °C),and that the heat absorption by the calorimeter is negligible,estimate the enthalpy of combustion per mole of anthracene.

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A 6.55 g sample of aniline (C6H5NH2,molar mass = 93.13 g/mol)was combusted in a bomb calorimeter with a heat capacity of 14.25 kJ/°C.If the initial temperature was 32.9°C,use the information below to determine the value of the final temperature of the calorimeter. 4 C6H5NH2(l)+ 35 O2(g)→ 24 CO2(g)+ 14 H2O(g)+ 4 NO2(g) ΔH°rxn = -1.28 × 104 kJ

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A 35.6 g sample of ethanol (C2H5OH)is burned in a bomb calorimeter,according to the following reaction.If the temperature rose from 35.0 to 76.0°C and the heat capacity of the calorimeter is 23.3 kJ/°C,what is the value of DH°rxn? The molar mass of ethanol is 46.07 g/mol. C2H5OH(l)+ 3 O2(g)→ 2 CO2(g)+ 3 H2O(g)ΔH°rxn = ?

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Give the temperature and pressure for the standard state for a liquid.

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A piece of iron (mass = 25.0 g)at 398 K is placed in a styrofoam coffee cup containing 25.0 mL of water at 298 K.Assuming that no heat is lost to the cup or the surroundings,what will the final temperature of the water be? The specific heat capacity of iron = 0.449 J/g°C and water = 4.18 J/g°C.

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Which of the following (with specific heat capacity provided)would show the largest temperature change upon gaining 200.0 J of heat?

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An endothermic reaction has

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How much energy is evolved during the formation of 296 g of Fe,according to the reaction below? Fe2O3(s)+ 2 Al(s)→ Al2O3(s)+ 2 Fe(s)ΔH°rxn = -852 kJ

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Which of the following signs on q and w represent the surroundings that is doing work on the system,as well as losing heat to the surroundings?

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Explain the difference between ΔH and DE.

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Use the standard reaction enthalpies given below to determine ΔH°rxn for the following reaction: 2 NO(g)+ O2(g)→ 2 NO2(g)ΔH°rxn = ? Given: N2(g)+ O2(g)→ 2 NO(g)ΔH°rxn = +183 kJ 1/2 N2(g)+ O2(g)→ NO2(g)ΔH°rxn = +33 kJ

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