Exam 6: Thermochemistry
Exam 1: Units of Measurement for Physical and Chemical Change173 Questions
Exam 2: Atoms and Elements161 Questions
Exam 3: Molecules,compounds,and Nomenclature172 Questions
Exam 4: Chemical Reactions and Stoichiometry247 Questions
Exam 5: Gases146 Questions
Exam 6: Thermochemistry145 Questions
Exam 7: The Quantum-Mechanical Model of the Atom164 Questions
Exam 8: Periodic Properties of the Elements129 Questions
Exam 9: Chemical Bonding I: Lewis Theory136 Questions
Exam 10: Chemical Bonding II: Molecular Shapes, valence Bond Theory, and Molecular Orbital Theory158 Questions
Exam 11: Liquids, solids, and Intermolecular Forces127 Questions
Exam 12: Solutions153 Questions
Exam 13: Chemical Kinetics156 Questions
Exam 14: Chemical Equilibrium124 Questions
Exam 15: Acids and Bases141 Questions
Exam 16: Aqueous Ionic Equilibrium159 Questions
Exam 17: Gibbs Energy and Thermodynamics119 Questions
Exam 18: Electrochemistry107 Questions
Exam 19: Radioactivity and Nuclear Chemistry108 Questions
Exam 20: Organic Chemistry I: Structures103 Questions
Exam 21: Organic Chemistry II: Reactions93 Questions
Exam 22: Biochemistry49 Questions
Exam 23: Chemistry of the Nonmetals45 Questions
Exam 24: Metals and Metallurgy42 Questions
Exam 25: Transition Metals and Coordination Compounds50 Questions
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A 4.98 g sample of aniline (C6H5NH2,molar mass = 93.13 g )was combusted in a bomb calorimeter with a heat capacity of 4.25 kJ .If the temperature rose from 29.5 °C to 69.8 °C,determine the value of U for the combustion of aniline.
(Multiple Choice)
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Use the information provided to determine r H° for the following reaction:
H° (kJ ) 3Fe2O3(s)+ CO(g)? 2Fe3O4(s)+ CO2(g) r H°= ? Fe2O3(s) -824
Fe3O4(s) -1118
CO(g) -111
CO2(g) -394
(Multiple Choice)
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Calculate the initial temperature of 648 g of cucumber (specific heat capacity = 1.88 J g-1 °C-1)that absorbs 19857 J of heat while warming up to room temperature,24.8 °C.
(Multiple Choice)
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The temperature rises from 25.00 °C to 29.00 °C when 3.50 g of sucrose undergoes combustion in a bomb calorimeter.Calculate rU for the combustion of sucrose in kJ sucrose.The heat capacity of the calorimeter is 4.90 kJ .The molar mass of sugar is 342.3 g .
(Multiple Choice)
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Choose the thermochemical equation that illustrates DfH° for Li2SO4.
(Multiple Choice)
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A 6.00 g sample of copper metal at 25.0 °C is heated by the addition of 97.0 J of energy.The final temperature of the copper is ________°C.The specific heat capacity of copper is
(Multiple Choice)
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Sodium metal reacts with water to produce hydrogen gas and sodium hydroxide according to the chemical equation shown below.When 0.015 mol of Na is added to 100.00 g of water,the temperature of the resulting solution rises from 25.00 °C to 31.45 °C.If the specific heat of the solution is 4.18 J ,calculate ?H for the reaction,as written.
2Na(s)+ 2H2O(l)? 2NaOH(aq)+ H2(g) H= ?
(Multiple Choice)
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Using the following thermochemical equation,determine the amount of heat produced from the combustion of 24.3 g benzene (C6H6).The molar mass of benzene is 78.11 g 2C6H6(l)+ 15O2(g)? 12CO2(g)+ 6H2O(g)
DrH° = -6278 kJ
(Multiple Choice)
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When 1.50 mol of CH4(g)reacts with excess Cl2(g)at constant pressure according to the chemical equation shown below,1062 kJ of heat are released.Calculate the value of ?H for this reaction,as written.
2CH4(g)+ 3Cl2(g)? 2CHCl3(l)+ 3H2(g) H° = ?
(Multiple Choice)
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Calculate the amount of heat (in kJ)necessary to raise the temperature of 47.8 g benzene by 57.0 K.The specific heat capacity of benzene is 1.05 J g-1 °C-1.
(Multiple Choice)
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Calculate the change in internal energy (ΔU)for a system that is giving off 45.0 kJ of heat and is performing 855 J of work on the surroundings.
(Multiple Choice)
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Given w = 0,an endothermic reaction has which of the following properties?
(Multiple Choice)
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Using the following equation for the combustion of octane,calculate the heat of reaction for 100.0 g of octane.The molar mass of octane is 114.33 g . 2C8H18 + 25O2 ? 16CO2 + 18H2O
DrH° = -11018 kJ
(Multiple Choice)
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Why are the standard heats of formation for elements in their most stable form assigned a value of 0?
(Essay)
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Calculate the initial temperature of 21.8 g of lithium (specific heat capacity = 3.582 J g-1 °C-1)that absorbs 1642 J of energy from the surroundings and has a final temperature of 31.08 °C.
(Multiple Choice)
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Which of the following is not a major contributor to energy consumption?
(Multiple Choice)
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Calculate the mass of sodium cyanate (NaOCN,molar mass = 65.0066 g mol-1)required to lower the temperature from 24.1 °C to 23.0 °C in a coffee cup calorimeter containing 98 mL of water.The enthalpy of solution for NaOCN is 19.20 kJ mol-1.The specific heat of water is 4.184 J g-1 °C-1 and assume the density of the solution is 1.00 g mL-1.
(Multiple Choice)
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Two solutions,initially at 24.60 °C,are mixed in a coffee cup calorimeter (Ccal = 15.5 J °C-1).When a 100.0 mL volume of 0.100 mol L-1 AgNO3 solution is mixed with a 100.0 mL sample of 0.200 mol L-1 NaCl solution,the temperature in the calorimeter rises to 25.30 °C.Determine the DrH° for the reaction as written below.Assume that the density and specific heat capacity of the solutions is the same as that of water. NaCl(aq)+ AgNO3(aq)→ AgCl(s)+ NaNO3(aq)DrH° = ?
(Multiple Choice)
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