Exam 6: Thermochemistry

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A 4.98 g sample of aniline (C6H5NH2,molar mass = 93.13 g mol−1\mathrm { mol } ^ { - 1 } )was combusted in a bomb calorimeter with a heat capacity of 4.25 kJ ∘C−1{ } ^ { \circ } \mathrm { C } ^ { - 1 } .If the temperature rose from 29.5 °C to 69.8 °C,determine the value of DrD _ { \mathrm { r } } U for the combustion of aniline.

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Use the information provided to determine Δ\Delta r H° for the following reaction: \quadDfD _ { f } H° (kJ mol−1\mathrm { mol } ^ { - 1 } ) \quad 3Fe2O3(s)+ CO(g)? 2Fe3O4(s)+ CO2(g) Δ\Delta r H°= ? Fe2O3(s) \quad -824 Fe3O4(s) \quad -1118 CO(g) \quad\quad -111 CO2(g) \quad\quad\quad\quad\quad\quad\quad -394

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Calculate the initial temperature of 648 g of cucumber (specific heat capacity = 1.88 J g-1 °C-1)that absorbs 19857 J of heat while warming up to room temperature,24.8 °C.

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The temperature rises from 25.00 °C to 29.00 °C when 3.50 g of sucrose undergoes combustion in a bomb calorimeter.Calculate Δ\Delta rU for the combustion of sucrose in kJ mol−1\mathrm { mol } ^ { - 1 } sucrose.The heat capacity of the calorimeter is 4.90 kJ ∘C−1{ } ^ { \circ } \mathrm { C } ^ { - 1 } .The molar mass of sugar is 342.3 g mol−1\mathrm { mol } ^ { - 1 } .

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Choose the thermochemical equation that illustrates DfH° for Li2SO4.

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A 6.00 g sample of copper metal at 25.0 °C is heated by the addition of 97.0 J of energy.The final temperature of the copper is ________°C.The specific heat capacity of copper is 0.38 J g−1 K−10.38 \mathrm {~J} \mathrm {~g} ^ { - 1 } \mathrm {~K} ^ { - 1 }

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Sodium metal reacts with water to produce hydrogen gas and sodium hydroxide according to the chemical equation shown below.When 0.015 mol of Na is added to 100.00 g of water,the temperature of the resulting solution rises from 25.00 °C to 31.45 °C.If the specific heat of the solution is 4.18 J g−1g ^ { - 1 } ∘C−1{ } ^ { \circ } \mathrm { C } ^ { - 1 } ,calculate ?H for the reaction,as written. 2Na(s)+ 2H2O(l)? 2NaOH(aq)+ H2(g) Δr\Delta _ { \mathrm { r } } H= ?

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Using the following thermochemical equation,determine the amount of heat produced from the combustion of 24.3 g benzene (C6H6).The molar mass of benzene is 78.11 g mol−1\mathrm { mol } ^ { - 1 } 2C6H6(l)+ 15O2(g)? 12CO2(g)+ 6H2O(g) DrH° = -6278 kJ

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When 1.50 mol of CH4(g)reacts with excess Cl2(g)at constant pressure according to the chemical equation shown below,1062 kJ of heat are released.Calculate the value of ?H for this reaction,as written. 2CH4(g)+ 3Cl2(g)? 2CHCl3(l)+ 3H2(g) Δr\Delta _ { \mathrm { r } } H° = ?

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Calculate the amount of heat (in kJ)necessary to raise the temperature of 47.8 g benzene by 57.0 K.The specific heat capacity of benzene is 1.05 J g-1 °C-1.

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Calculate the change in internal energy (ΔU)for a system that is giving off 45.0 kJ of heat and is performing 855 J of work on the surroundings.

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Given w = 0,an endothermic reaction has which of the following properties?

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Using the following equation for the combustion of octane,calculate the heat of reaction for 100.0 g of octane.The molar mass of octane is 114.33 g mol−1\mathrm { mol } ^ { - 1 } . 2C8H18 + 25O2 ? 16CO2 + 18H2O DrH° = -11018 kJ

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Which of the following processes is endothermic?

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Why are the standard heats of formation for elements in their most stable form assigned a value of 0?

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Calculate the initial temperature of 21.8 g of lithium (specific heat capacity = 3.582 J g-1 °C-1)that absorbs 1642 J of energy from the surroundings and has a final temperature of 31.08 °C.

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Which of the following is not a major contributor to energy consumption?

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Calculate the mass of sodium cyanate (NaOCN,molar mass = 65.0066 g mol-1)required to lower the temperature from 24.1 °C to 23.0 °C in a coffee cup calorimeter containing 98 mL of water.The enthalpy of solution for NaOCN is 19.20 kJ mol-1.The specific heat of water is 4.184 J g-1 °C-1 and assume the density of the solution is 1.00 g mL-1.

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Identify the unit of specific heat capacity.

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Two solutions,initially at 24.60 °C,are mixed in a coffee cup calorimeter (Ccal = 15.5 J °C-1).When a 100.0 mL volume of 0.100 mol L-1 AgNO3 solution is mixed with a 100.0 mL sample of 0.200 mol L-1 NaCl solution,the temperature in the calorimeter rises to 25.30 °C.Determine the DrH° for the reaction as written below.Assume that the density and specific heat capacity of the solutions is the same as that of water. NaCl(aq)+ AgNO3(aq)→ AgCl(s)+ NaNO3(aq)DrH° = ?

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