Exam 4: Thermodynamics

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The standard enthalpy of formation of ammonia gas is -46.11 kJ.mol-1 at 298 K .What is the standard reaction enthalpy for the Haber process at 500 ο\omicron C? The molar heat capacities of nitrogen,Hydrogen,And ammonia are29.12,28.82,And 35.06J.k.mol-1 respectively.

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The energy levels of two particle in a box systems are given below: The energy levels of two particle in a box systems are given below:    Which molecule,N<sub>2</sub>,or F<sub>2</sub>,is better represented by (b)? Which molecule,N2,or F2,is better represented by (b)?

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For any isothermal process, Δ\Delta U > 0 for an ideal gas.

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Calculate the change in molar entropy when the pressure of argon is allowed to double isothermally (assume ideal behavior).

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The heat flow for the reactionC2H6(g)+ 3.5O2(g) →\rightarrow 2CO2(g)+ 3H2O(l)Measured in a bomb calorimeter is -1553.5 kJ/mol at 298 K.At this temperature, Δ\Delta U is

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Estimate the minimum temperature at which magnetite can be reduced to iron by graphite. Fe3O4(s)+ 2C(s) →\rightarrow 2CO2(g)+ 3Fe(s) Δ\Delta Sr ο\omicron = +351.44 kJ.mol-1 The standard molar enthalpies of formation of magnetite and CO2(g) Are -1118.4 and -393.51 kJ.mol-1 ,Respectively.

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What equation corresponds to the standard enthalpy of formation of gaseous hydrogen atoms,which,at 298 K is +217 kJ.mol-1 ?

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Consider the following compounds and their standard free energies of formation: 1 2 3 4 5 () cyclohexane () methanol () hydrazine () hydrogen peroxide () carbon disulfide +6.4\cdot -166\cdot +149\cdot -120\cdot +65.3\cdot Which of these liquids is (are)Thermodynamically stable?

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The formation of solid calcium chloride from a gas of its ions is an exothermic process.

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When a solution of 1.691 g of silver nitrate is mixed with an excess of sodium chloride in a calorimeter of heat capacity 216 J.( ο\omicron C)-1, the temperature rises 3.03 ο\omicron C.What is the reaction enthalpy?

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If the standard reaction enthalpy for the reaction NO2(g) →\rightarrow NO(g)+ O(g) Is needed,Calculate it from the standard enthalpy of formation of ozone,+142.7kJ.mol-1 ,And from the reactions listed below: O2(g) →\rightarrow 2O(g) Δ\Delta H° = +498.4 kJ.mol-1 NO(g)+ O3(g) →\rightarrow NO2(g)+ O2(g) Δ\Delta H° = -200 kJ.mol-1

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Calculate the average H-S bond enthalpy in H2S(g) given the standard enthalpies of formation for H2S(g),H(g),And S(g):-20.1,218,And 223kJ.mol-1 ,Respectively.

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Which of the following quantities is not equal to zero at 298 K?

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A piece of a newly synthesized material of mass 25.0 g at 80.0 ο\omicron C is placed in a calorimeter containing 100.0 g of water at 20.0 ο\omicron C .If the final temperature of the system is 24.0 ο\omicron C,What is the specific heat capacity of this material?

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Calculate the standard reaction enthalpy for the reaction. ()+()\rightarrow2() Given: ()+()\rightarrow()+2() \Delta=-543\cdot 2()+()\rightarrow2() \Delta=-484\cdot ()+3()\rightarrow2() \Delta=-92.2\cdot

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For the reaction 2C(s)+ 2H2(g) →\rightarrow C2H4(g) Δ\Delta Hr ο\omicron = +52.3 kJ.mol-1 and Δ\Delta Sr ο\omicron = -53.07 J.K-1.mol-1 at 298 K. The reverse reaction will be spontaneous at

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Use Trouton's constant to estimate the enthalpy of condensation of diethyl ether, which boils at 309 K.

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Use tabulated thermodynamic data to estimate the temperature at which the vapor pressure of benzene is 1.33 kPa. Hint: Assume that the enthalpy and entropy of the reaction are independent of temperature.

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Iodine sublimes at room temperature .The reaction free energy,Enthalpy, And entropy for this reaction,Respectively,Are

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Sketch a plot of the molar entropy of oxygen gas from 0 K to 200 K.The normal melting and boiling points of oxygen are 55 K and 90 K, respectively.

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