Exam 4: Thermodynamics
Exam 1: Atoms202 Questions
Exam 2: Molecules181 Questions
Exam 3: States of Matter287 Questions
Exam 4: Thermodynamics192 Questions
Exam 5: Equilibrium191 Questions
Exam 6: Reactions282 Questions
Exam 7: Kinetics87 Questions
Exam 8: The Main-Group Elements191 Questions
Exam 9: The D-Block Elements95 Questions
Exam 10: Nuclear Chemistry96 Questions
Exam 11: Organic Chemistry193 Questions
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The standard free energy of formation of benzene,C6H6(l),is +124.3 kJ.mol-1 at 298 K.This means that at 298 K benzene is thermodynamically unstable even though it can be kept indefinitely without decomposing.Explain.
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A CD player and its battery together do 500 kJ of work .The battery also releases 250 kJ of energy as heat and the CD player releases 50 kJ as heat due to friction from spinning.What is the change in internal energy of the system,
With the system regarded as the CD player alone? Assume that the battery does 500 kJ of work on the CD player,
Which then does the same amount of work on the surroundings.
(Multiple Choice)
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The standard enthalpy of formation of gaseous water is -241.82 kJ.mol-1 at 298 K .Estimate this value at 370 K.The molar heat capacities of hydrogen,Oxygen,And gaseous waterare 28.82,29.36,And 33.58J.k.mol-1
(Multiple Choice)
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Calculate the change in internal energy when 2.50 kJ of energy is transferred as heat to 1.50 mol N2 at 298 K and 1 atm at constant pressure.
(Multiple Choice)
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The experimental value of the molar entropy of 1 mol NO at 0 K is about 5 J.K-1.We can conclude that in the crystal the molecules of NO are arranged randomly.
(True/False)
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For gaseous hydrogen atoms at 298 K is +217 .
kJ.mol-1 ,The standard enthalpy of formation can be best written as:
(Multiple Choice)
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Calculate the standard enthalpy of combustion of ethanol at 298 K from standard enthalpy of formation data.
(Multiple Choice)
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The lattice enthalpy of calcium bromide is the energy change for the reaction
(Multiple Choice)
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Why is the entropy of vaporization of a material always smaller than its entropy of fusion?
(Multiple Choice)
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What is the change in entropy when the pressure of an ideal gas is increased at constant temperature? Choose from +,0,-.
(Short Answer)
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The lattice enthalpy of calcium oxide is the energy change for the reaction
(Multiple Choice)
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Calculate the standard enthalpy of vaporization of liquid bromine if the standard enthalpy of sublimation of solid bromine is +40.1 kJ.mol-1 and the standard enthalpy of fusion of solid bromine is +10.6 kJ.mol-1
(Multiple Choice)
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If the standard enthalpy of combustion of ethanol, C2H5OH(l),At 298 K is -1368 kJ.mol-1 ,What is the standard enthalpy of formation of ethanol? The standard enthalpies of formation of carbon dioxide and liquid water are -393.51 and -285.83 kJ.mol-1 ,Respectively.
(Multiple Choice)
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Consider the compounds
PCl5(g),HCN(g),CuO(s),NO(g),NH3(g),And SO2(g).
Which compound will become more stable with respect to its elements if the temperature is raised?
(Multiple Choice)
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An isolated system can exchange energy and small particles with the surroundings.
(True/False)
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When calculating the entropy of vaporization of water at 25 C, the dominant contribution is
(Multiple Choice)
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Use the following information to determine the standard enthalpy of formation of NH3(g).
N-H bond enthalpy = 390 kJ.mol-1
Hf (H(g))= 217.9 kJ.mol-1
Hf (N(g))= 472.6 kJ.mol-1
(Multiple Choice)
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