Exam 19: Electrochemistry
Exam 1: Matter: Its Properties and Measurement136 Questions
Exam 2: Atoms and the Atomic Theory119 Questions
Exam 3: Chemical Compounds152 Questions
Exam 4: Chemical Reactions170 Questions
Exam 5: Introduction to Reactions in Aqueous Solutions124 Questions
Exam 6: Gases113 Questions
Exam 7: Thermochemistry125 Questions
Exam 8: Electrons in Atoms123 Questions
Exam 9: The Periodic Table and Some Atomic Properties93 Questions
Exam 10: Chemical Bonding I: Basic Concepts107 Questions
Exam 11: Chemical Bonding Ii: Valence Bond and Molecular Orbital Theories104 Questions
Exam 12: Intermolecular Forces: Liquids and Solids121 Questions
Exam 13: Spontaneous Change: Entropy and Gibbs Energy123 Questions
Exam 14: Solutions and Their Physical Properties132 Questions
Exam 15: Principles of Chemical Equilibrium118 Questions
Exam 16: Acids and Bases137 Questions
Exam 17: Additional Aspects of Acidbase Equilibria130 Questions
Exam 18: Solubility and Complex-Ion Equilibria104 Questions
Exam 19: Electrochemistry127 Questions
Exam 20: Chemical Kinetics124 Questions
Exam 21: Chemistry of the Main-Group Elements I: Groups 1,2,13,and 14116 Questions
Exam 22: Chemistry of the Main-Group Elements Ii: Groups 18,17,16,15,and Hydrogen100 Questions
Exam 23: The Transition Elements108 Questions
Exam 24: Complex Ions and Coordination Compounds104 Questions
Exam 25: Nuclear Chemistry116 Questions
Exam 26: Structures of Organic Compounds99 Questions
Exam 27: Reactions of Organic Compounds94 Questions
Exam 28: Chemistry of the Living State104 Questions
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The Ecell for the following concentration cell at 25 °C is 0.006 V.
Pt ∣ H2 (g,0.025 atm)∣ H+ (0.012 M)
H+ (1 M)∣ H2 (g,1 atm)∣ Pt
2 H+(aq)+ 2 e- → H2(g)E° = 0.V
(True/False)
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(77)
The net reaction in a voltaic cell with E°cell = +0.726 V is,
2 Fe3+(aq)+ 3 Zn(s)→ 2 Fe(s)+ 3 Zn2+(aq)
What is ΔG° for this reaction at 25 °C?
(Multiple Choice)
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Consider the following reaction:
2 Al(s)+ 3 Ni2+(aq)→ 2 Al3+(aq)+ 3 Ni(s)E° = 1.410 V
What would be the cell potential at 25 °C as calculated from the Nernst equation if [Ni2+] = 0.020 M,[Al3+] = 3.60 M?
(Multiple Choice)
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The standard emf for the cell using the overall cell reaction below is +2.20 V:
2 Al(s)+
(s)→
(aq)+
(aq)
The emf generated by the cell when [
] = 5.0 ×
Mol L-1 and [
] = 0.10 mol L-1 is ![The standard emf for the cell using the overall cell reaction below is +2.20 V: 2 Al(s)+ (s)→ (aq)+ (aq) The emf generated by the cell when [ ] = 5.0 × Mol L<sup>-1</sup> and [ ] = 0.10 mol L<sup>-1</sup> is](https://storage.examlex.com/TB5343/11ea7a5e_3e7b_da73_89bd_bfaf91da49cc_TB5343_11.jpg)
(Multiple Choice)
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Determine E°cell for the reaction: Pb2+(aq)+ Zn(s)→ Pb(s)+ Zn2+(aq).The half reactions are:
Pb2+(aq)+ 2 e- → Pb(s)E° = -0.125 V
Zn2+(aq)+ 2 e- → Zn(s)E° = -0.763 V
(Multiple Choice)
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Calculate Ecell at 25 °C for the following voltaic cell.Ksp for NiCO3(s)is 1.42 × 10-7.
Ni(s)∣ Ni2+(aq)[sat'd NiCO3(s)]
Ni2+(aq)(0.010M)∣ Ni(s)
The half-reaction is: Ni2+(aq)+ 2 e- → Ni(s)E° = -0.257 V
(Multiple Choice)
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What is the shorthand notation that represents the following galvanic cell reaction?
Pb(s)+ Cu(NO3)2(aq)→ Pb(NO3)2(aq)+ Cu(s)
(Multiple Choice)
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For the following voltaic cell,determine the [Cl-] when
= 0.500 atm,[Zn2+] = 1.77 × 10-2 M,and Ecell = 2.250 V.The half-reactions at 25 °C are:
Cl2(g)+ 2 e- → 2 Cl-(aq)E° = +1.358 V
Zn2+(aq)+ 2 e- → Zn(s)E° = -0.763 V
Zn(s)∣ Zn2+(aq)
Cl-(aq),Cl2(g)∣ Pt(s)
(Multiple Choice)
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A solution of Al(NO3)3(aq)is electrolyzed by passing 144 A of current for 102 min.What mass of aluminum plates out?
(Multiple Choice)
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The standard Gibbs energy change for the following voltaic cell is ΔG° = -89.3 kJ at 25 °C.What is E°cell?
Ag(s)
(Multiple Choice)
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Determine E°cell for the reaction: 2 Al(aq)+ 3 Zn2+(aq)→ 2 Al3+(aq)+ 3 Zn(s).The half reactions are:
Al3+(aq)+ 3 e- → Al(s)E° = -1.676 V
Zn2+(aq)+ 2 e- → Zn(s)E° = -0.763 V
(Multiple Choice)
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Determine E°cell for the reaction: MnO4-(aq)+ 8 H+(aq)+ 5 Fe2+(aq)→ Mn2+(aq)+ 4 H2O(l)+ 5 Fe3+(aq).The half reactions are:
Fe3+(aq)+ e- → Fe2+(aq)E° = +0.771 V
MnO4-(aq)+ 8 H+(aq)+ 5 e- → Mn2+(aq)+ 4 H2O(l)E° = 1.507 V
(Multiple Choice)
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Find Ecell at 25 °C for the following voltaic cell:
Cu(s)∣ Cu2+(aq)(0.10 M)
Cu2+(aq)(0.85 M)∣ Cu(s)
The half-reaction is:
Cu2+(aq)+ 2 e- → Cu(s)E° = +0.377 volts
(Multiple Choice)
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Determine E°cell for the reaction: 2 Al3+(aq)+ 3 Zn(s)→ 2 Al + 3 Zn2+(aq).The half reactions are:
Al3+(aq)+ 3 e- → Al(s)E° = -1.676 V
Zn2+(aq)+ 2 e- → Zn(s)E° = -0.763 V
(Multiple Choice)
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Find Ecell for the following voltaic cell at 25 °C:
Ti(s)∣ Ti2+(aq)(0.550M)
Sn2+(aq)(0.005 M)∣ Sn(s)
The half-reactions are:
Ti2+(aq)+ 2 e- ⇔ Ti(s)E° = -1.630 V
Sn2+(aq)+ 2 e- ⇔ Sn(s)E° = -0.137 V
(Multiple Choice)
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Based on the following information,
F2(g)+ 2 e- → 2 F-(aq)E° = +2.87 V
Li +(aq)+ e- → Li(s)E° = -3.04 V
Which of the following chemical species is the strongest reducing agent?
(Multiple Choice)
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