Exam 19: Electrochemistry
Exam 1: Matter: Its Properties and Measurement136 Questions
Exam 2: Atoms and the Atomic Theory119 Questions
Exam 3: Chemical Compounds152 Questions
Exam 4: Chemical Reactions170 Questions
Exam 5: Introduction to Reactions in Aqueous Solutions124 Questions
Exam 6: Gases113 Questions
Exam 7: Thermochemistry125 Questions
Exam 8: Electrons in Atoms123 Questions
Exam 9: The Periodic Table and Some Atomic Properties93 Questions
Exam 10: Chemical Bonding I: Basic Concepts107 Questions
Exam 11: Chemical Bonding Ii: Valence Bond and Molecular Orbital Theories104 Questions
Exam 12: Intermolecular Forces: Liquids and Solids121 Questions
Exam 13: Spontaneous Change: Entropy and Gibbs Energy123 Questions
Exam 14: Solutions and Their Physical Properties132 Questions
Exam 15: Principles of Chemical Equilibrium118 Questions
Exam 16: Acids and Bases137 Questions
Exam 17: Additional Aspects of Acidbase Equilibria130 Questions
Exam 18: Solubility and Complex-Ion Equilibria104 Questions
Exam 19: Electrochemistry127 Questions
Exam 20: Chemical Kinetics124 Questions
Exam 21: Chemistry of the Main-Group Elements I: Groups 1,2,13,and 14116 Questions
Exam 22: Chemistry of the Main-Group Elements Ii: Groups 18,17,16,15,and Hydrogen100 Questions
Exam 23: The Transition Elements108 Questions
Exam 24: Complex Ions and Coordination Compounds104 Questions
Exam 25: Nuclear Chemistry116 Questions
Exam 26: Structures of Organic Compounds99 Questions
Exam 27: Reactions of Organic Compounds94 Questions
Exam 28: Chemistry of the Living State104 Questions
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What is the concentration of Cu2+(aq)in the following cell at 25 °C if the cell voltage is 1.253 V?
Zn(s)∣ Zn2+ (aq,0.125 M)
Cu2+(?)∣ Cu(s)
Cu2+(aq)+ 2 e- → Cu(s)E° = 0.340 V
Zn2+(aq)+ 2 e- → Zn(s)E° = -0.763 V
(Multiple Choice)
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What is E° of the spontaneous cell made from the Zn2+(aq)/Zn(s)(-0.76 V)and Br2(l)/2 Br-(aq)(1.07 V)half cells?
(Multiple Choice)
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Choose the INCORRECT completion of the following sentence:
"In the electrolysis of water...
(Multiple Choice)
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Determine E°cell for the reaction:
Pb(s)+ Zn2+(aq)→ Pb2+(aq)+ Zn(s).
The half reactions are:
Pb2+(aq)+ 2 e- → Pb(s)E° = -0.125 V
Zn2+(aq)+ 2 e- → Zn(s)E° = -0.763 V
(Multiple Choice)
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What is the standard cell potential if the Gibbs energy is -2108 kJ in the reaction:
C3H8(g)+ O2(g)→ CO2(g)+ H2O(l)(not balanced)?
(Multiple Choice)
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Consider the cell:
Ni(s)∣ Ni2+ (aq,?M)
Cu2+ (aq,0.136 M)∣ Cu(s)
Ni2+(aq)/Ni(s) E° = -0.257 V Cu2+(aq)/Cu(s) E° = 0.340 V
The measured potential of the cell is 0.621 V.What is [Ni2+] at 25 °C?
(Multiple Choice)
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Two cells containing solutions of AgNO3(aq)and CuSO4(aq),respectively,were connected in series and electrolyzed.The cathode in the AgNO3(aq)cell was found to gain 1.078 grams in weight.How much had the cathode in the other cell gained?
(Multiple Choice)
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What is Keq at 25 °C of the spontaneous cell made from Ag+(aq)/Ag(s)(0.80 V)and Cl2(g)/Cl-(aq)(1.36 V)half cells?
(Multiple Choice)
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Given that E°red = -1.66 V for Al3+(aq)/Al(s)at 25 °C,find E° and E for the concentration cell expressed using shorthand notation below:
Al(s)∣ Al3+(aq,1.0 × 10-5 mol L-1)∣∣ Al3+(aq,0.100 mol L-1)∣ Al(s)
(Multiple Choice)
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Determine E°cell at 25 °C for the following reaction:
Pb2+(aq)+ Cu(s)→ Cu2+(aq)+ Pb(s)
The half-reactions are:
Pb2+(aq)+ 2 e- → Pb(s)E° = -0.125 V
Cu2+(aq)+ 2 e- → Cu(s)E° = +0.337 V
(Multiple Choice)
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What is the balanced equation for the galvanic cell reaction expressed using shorthand notation below?
Ni(s)∣ Ni2+(aq)∣∣ Cl2(g)∣ Cl-(aq)∣ C(s)
(Multiple Choice)
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How long would it take to deposit 15.0 g copper metal at the cathode of an electrolysis cell running with a current of 150 mA?
(Multiple Choice)
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Consider the following standard reduction potentials:
Ni2+(aq)+ 2 e- → Ni(s)E° = -0.26 V
I2(s)+ 2 e- → 2 I-(aq)E° = +0.54 V
Under standard conditions:
(Multiple Choice)
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A voltaic cell is constructed with two silver-silver chloride electrodes,where the half-reaction is
AgCl(s)+
→ Ag(s)+
(aq) E° = +0.222 V
The concentrations of chloride ion in the two compartments are 0.0222 mol L-1 and 2.22 mol L-1,respectively.The cell emf is ________ V.
(Multiple Choice)
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For the galvanic cell reaction,expressed below using shorthand notation,what half-reaction occurs at the cathode?
Zn(s)∣ Zn2+(aq)∣∣ Ni2+(aq)∣ Ni(s)
(Multiple Choice)
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What is the shorthand notation that represents the following galvanic cell reaction?
2 Fe2+(aq)+ F2(g)→ 2 Fe3+(aq)+ 2 F-(aq)
(Multiple Choice)
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A voltaic cell is constructed with two
-Zn electrodes,where the half-reaction is
(aq)+
→ Zn(s)E° = -0.763 V
The concentrations of zinc ion in the two compartments are 5.50 mol L-1 and 1.11 ×
Mol L-1,respectively.The cell emf is ________ V.
(Multiple Choice)
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