Exam 19: Electrochemistry

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What is the concentration of Cu2+(aq)in the following cell at 25 °C if the cell voltage is 1.253 V? Zn(s)∣ Zn2+ (aq,0.125 M) What is the concentration of Cu<sup>2+</sup>(aq)in the following cell at 25 °C if the cell voltage is 1.253 V? Zn(s)∣ Zn<sup>2+</sup> (aq,0.125 M)   Cu<sup>2+</sup>(?)∣ Cu(s) Cu<sup>2+</sup>(aq)+ 2 e<sup>-</sup> → Cu(s)E° = 0.340 V Zn<sup>2+</sup>(aq)+ 2 e<sup>-</sup> → Zn(s)E° = -0.763 V Cu2+(?)∣ Cu(s) Cu2+(aq)+ 2 e- → Cu(s)E° = 0.340 V Zn2+(aq)+ 2 e- → Zn(s)E° = -0.763 V

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Choose the INCORRECT statement.

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What is E° of the spontaneous cell made from the Zn2+(aq)/Zn(s)(-0.76 V)and Br2(l)/2 Br-(aq)(1.07 V)half cells?

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Choose the INCORRECT completion of the following sentence: "In the electrolysis of water...

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Determine E°cell for the reaction: Pb(s)+ Zn2+(aq)→ Pb2+(aq)+ Zn(s). The half reactions are: Pb2+(aq)+ 2 e- → Pb(s)E° = -0.125 V Zn2+(aq)+ 2 e- → Zn(s)E° = -0.763 V

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What is the standard cell potential if the Gibbs energy is -2108 kJ in the reaction: C3H8(g)+ O2(g)→ CO2(g)+ H2O(l)(not balanced)?

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Consider the cell: Ni(s)∣ Ni2+ (aq,?M) Consider the cell: Ni(s)∣ Ni<sup>2+</sup> (aq,?M)   Cu<sup>2</sup><sup>+</sup> (aq,0.136 M)∣ Cu(s) Ni<sup>2+</sup>(aq)/Ni(s) E° = -0.257 V Cu<sup>2+</sup>(aq)/Cu(s) E° = 0.340 V The measured potential of the cell is 0.621 V.What is [Ni<sup>2+]</sup> at 25 °C? Cu2+ (aq,0.136 M)∣ Cu(s) Ni2+(aq)/Ni(s) E° = -0.257 V Cu2+(aq)/Cu(s) E° = 0.340 V The measured potential of the cell is 0.621 V.What is [Ni2+] at 25 °C?

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Two cells containing solutions of AgNO3(aq)and CuSO4(aq),respectively,were connected in series and electrolyzed.The cathode in the AgNO3(aq)cell was found to gain 1.078 grams in weight.How much had the cathode in the other cell gained?

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What is Keq at 25 °C of the spontaneous cell made from Ag+(aq)/Ag(s)(0.80 V)and Cl2(g)/Cl-(aq)(1.36 V)half cells?

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Given that E°red = -1.66 V for Al3+(aq)/Al(s)at 25 °C,find E° and E for the concentration cell expressed using shorthand notation below: Al(s)∣ Al3+(aq,1.0 × 10-5 mol L-1)∣∣ Al3+(aq,0.100 mol L-1)∣ Al(s)

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Primary batteries' cell reactions cannot be reversed.

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Determine E°cell at 25 °C for the following reaction: Pb2+(aq)+ Cu(s)→ Cu2+(aq)+ Pb(s) The half-reactions are: Pb2+(aq)+ 2 e- → Pb(s)E° = -0.125 V Cu2+(aq)+ 2 e- → Cu(s)E° = +0.337 V

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What is the balanced equation for the galvanic cell reaction expressed using shorthand notation below? Ni(s)∣ Ni2+(aq)∣∣ Cl2(g)∣ Cl-(aq)∣ C(s)

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How long would it take to deposit 15.0 g copper metal at the cathode of an electrolysis cell running with a current of 150 mA?

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Consider the following standard reduction potentials: Ni2+(aq)+ 2 e- → Ni(s)E° = -0.26 V I2(s)+ 2 e- → 2 I-(aq)E° = +0.54 V Under standard conditions:

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A voltaic cell is constructed with two silver-silver chloride electrodes,where the half-reaction is AgCl(s)+ A voltaic cell is constructed with two silver-silver chloride electrodes,where the half-reaction is AgCl(s)+   → Ag(s)+   (aq) E° = +0.222 V The concentrations of chloride ion in the two compartments are 0.0222 mol L<sup>-1</sup> and 2.22 mol L<sup>-1</sup>,respectively.The cell emf is ________ V. → Ag(s)+ A voltaic cell is constructed with two silver-silver chloride electrodes,where the half-reaction is AgCl(s)+   → Ag(s)+   (aq) E° = +0.222 V The concentrations of chloride ion in the two compartments are 0.0222 mol L<sup>-1</sup> and 2.22 mol L<sup>-1</sup>,respectively.The cell emf is ________ V. (aq) E° = +0.222 V The concentrations of chloride ion in the two compartments are 0.0222 mol L-1 and 2.22 mol L-1,respectively.The cell emf is ________ V.

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Choose the INCORRECT statement.

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For the galvanic cell reaction,expressed below using shorthand notation,what half-reaction occurs at the cathode? Zn(s)∣ Zn2+(aq)∣∣ Ni2+(aq)∣ Ni(s)

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What is the shorthand notation that represents the following galvanic cell reaction? 2 Fe2+(aq)+ F2(g)→ 2 Fe3+(aq)+ 2 F-(aq)

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A voltaic cell is constructed with two A voltaic cell is constructed with two   -Zn electrodes,where the half-reaction is   (aq)+   → Zn(s)E° = -0.763 V The concentrations of zinc ion in the two compartments are 5.50 mol L<sup>-1</sup> and 1.11 ×   Mol L<sup>-1</sup>,respectively.The cell emf is ________ V. -Zn electrodes,where the half-reaction is A voltaic cell is constructed with two   -Zn electrodes,where the half-reaction is   (aq)+   → Zn(s)E° = -0.763 V The concentrations of zinc ion in the two compartments are 5.50 mol L<sup>-1</sup> and 1.11 ×   Mol L<sup>-1</sup>,respectively.The cell emf is ________ V. (aq)+ A voltaic cell is constructed with two   -Zn electrodes,where the half-reaction is   (aq)+   → Zn(s)E° = -0.763 V The concentrations of zinc ion in the two compartments are 5.50 mol L<sup>-1</sup> and 1.11 ×   Mol L<sup>-1</sup>,respectively.The cell emf is ________ V. → Zn(s)E° = -0.763 V The concentrations of zinc ion in the two compartments are 5.50 mol L-1 and 1.11 × A voltaic cell is constructed with two   -Zn electrodes,where the half-reaction is   (aq)+   → Zn(s)E° = -0.763 V The concentrations of zinc ion in the two compartments are 5.50 mol L<sup>-1</sup> and 1.11 ×   Mol L<sup>-1</sup>,respectively.The cell emf is ________ V. Mol L-1,respectively.The cell emf is ________ V.

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