Exam 18: Solubility and Complex-Ion Equilibria
Exam 1: Matter: Its Properties and Measurement136 Questions
Exam 2: Atoms and the Atomic Theory119 Questions
Exam 3: Chemical Compounds152 Questions
Exam 4: Chemical Reactions170 Questions
Exam 5: Introduction to Reactions in Aqueous Solutions124 Questions
Exam 6: Gases113 Questions
Exam 7: Thermochemistry125 Questions
Exam 8: Electrons in Atoms123 Questions
Exam 9: The Periodic Table and Some Atomic Properties93 Questions
Exam 10: Chemical Bonding I: Basic Concepts107 Questions
Exam 11: Chemical Bonding Ii: Valence Bond and Molecular Orbital Theories104 Questions
Exam 12: Intermolecular Forces: Liquids and Solids121 Questions
Exam 13: Spontaneous Change: Entropy and Gibbs Energy123 Questions
Exam 14: Solutions and Their Physical Properties132 Questions
Exam 15: Principles of Chemical Equilibrium118 Questions
Exam 16: Acids and Bases137 Questions
Exam 17: Additional Aspects of Acidbase Equilibria130 Questions
Exam 18: Solubility and Complex-Ion Equilibria104 Questions
Exam 19: Electrochemistry127 Questions
Exam 20: Chemical Kinetics124 Questions
Exam 21: Chemistry of the Main-Group Elements I: Groups 1,2,13,and 14116 Questions
Exam 22: Chemistry of the Main-Group Elements Ii: Groups 18,17,16,15,and Hydrogen100 Questions
Exam 23: The Transition Elements108 Questions
Exam 24: Complex Ions and Coordination Compounds104 Questions
Exam 25: Nuclear Chemistry116 Questions
Exam 26: Structures of Organic Compounds99 Questions
Exam 27: Reactions of Organic Compounds94 Questions
Exam 28: Chemistry of the Living State104 Questions
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If iron(III)acetate is added to be 1 × 10-10 M in an aqueous solution that is 0.10 M NH3,what is Qsp and will Fe(OH)3 precipitate? The Ksp of Fe(OH)3(s)is 4 × 10-38 and Kb for NH3 is 1.8 × 10-5.
(Multiple Choice)
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When solid silver chloride is shaken with a 0.1 molar aqueous solution of potassium iodide,most of the silver chloride is converted to silver iodide.This transformation takes place because:
(Multiple Choice)
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The solubility of magnesium fluoride is 1.17 × 10-3 M.Find the value of Ksp for this compound.
(Multiple Choice)
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What is the concentration of Ca2+ in ppm (mg/L)in cave water saturated with calcite (calcium carbonate,Ksp = 4.7 × 10-9)?
(Multiple Choice)
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What ratio of [NH4+]/[NH3] would provide a buffer of pH low enough to avoid precipitation of Co(OH)2(s)from a 0.50 M Co2+(aq)solution? (Kb for NH3 = 1.8 × 10-5 and Ksp for Co(OH)2= 2.0 × 10-14
(Multiple Choice)
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A small amount of solid calcium hydroxide is shaken vigorously in a test tube almost full of water until no further change occurs and most of the solid settles out.The resulting solution is:
(Multiple Choice)
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What molar concentration of silver ion could exist in a solution in which the concentration of CrO42- is 1.0 × 10-4 M? (Ksp of Ag2CrO4 = 1.1 × 10-12)
(Multiple Choice)
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In which of the following one molar aqueous solutions would you expect cadmium sulfide,CdS,to be the most soluble?
(Multiple Choice)
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When 100 mL each of 2.0 × 10-6 M Ag+(aq)and 2.0 × 10-3 M Br-(aq)are mixed,what is the remaining Ag+(aq)ion concentration and is precipitation complete? The solubility product constant of AgBr(s)is 5.0 × 10-13.
(Multiple Choice)
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The relationship between the molar concentration of silver ion in a saturated solution of silver phosphate and the solubility product constant for silver phosphate is ________.
(Multiple Choice)
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Write the solubility product constant expression for the following salt: Ag2SO4(s).
(Multiple Choice)
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Write the solubility product constant expression for the following salt: Ca3(PO4)2(s).
(Multiple Choice)
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Predict the molar solubility of the following salt in an aqueous solution that contains the given concentration of one of its ions:
BaSO4;[SO42-] = 4.3 × 10-5 M;Ksp = 1.1 × 10-10
(Multiple Choice)
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Write the solubility product constant expression for the following salt: CoS(s).
(Multiple Choice)
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Equal volumes of 0.020 M Ag+(aq)solution and 2.0 M NH3(aq)solution are mixed.Kf for [Ag(NH3)2]+ is 1.6 × 107.If trisodium arsenate is added so that the arsenate ion concentration is 0.10 M,will silver arsenate precipitate?
What is Qsp? Ksp for silver arsenate is 1.0 × 10-22.
(Multiple Choice)
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To a concentrated buffer of pH 4.0 is added an equal volume of an aqueous solution that is 0.020 M in Cr3+,Cd2+ and Al3+.The expected precipitate would consist of ________.

(Multiple Choice)
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At a temperature for which the solubility product constant of calcium carbonate is 4.7 × 10-9,what mass of the salt will dissolve in 100 mL of water?
(Multiple Choice)
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A swimming pool was sufficiently alkaline so that the carbon dioxide absorbed from the air produced a solution in the pool that was 2 × 10-4 M in carbonate ion.If the pool originally contained 4 × 10-3 M Mg2+,6 × 10-4 M Ca2+,and 8 × 10-7 M Fe2+,then the precipitate that was formed consisted of ________.
(Ksp values are: CaCO3,4.7 × 10-9;MgCO3,4.0 × 10-5;FeCO3,2.0 × 10-11)
(Multiple Choice)
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