Exam 18: Solubility and Complex-Ion Equilibria

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If iron(III)acetate is added to be 1 × 10-10 M in an aqueous solution that is 0.10 M NH3,what is Qsp and will Fe(OH)3 precipitate? The Ksp of Fe(OH)3(s)is 4 × 10-38 and Kb for NH3 is 1.8 × 10-5.

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When solid silver chloride is shaken with a 0.1 molar aqueous solution of potassium iodide,most of the silver chloride is converted to silver iodide.This transformation takes place because:

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The solubility of magnesium fluoride is 1.17 × 10-3 M.Find the value of Ksp for this compound.

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What is the concentration of Ca2+ in ppm (mg/L)in cave water saturated with calcite (calcium carbonate,Ksp = 4.7 × 10-9)?

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What ratio of [NH4+]/[NH3] would provide a buffer of pH low enough to avoid precipitation of Co(OH)2(s)from a 0.50 M Co2+(aq)solution? (Kb for NH3 = 1.8 × 10-5 and Ksp for Co(OH)2= 2.0 × 10-14

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A small amount of solid calcium hydroxide is shaken vigorously in a test tube almost full of water until no further change occurs and most of the solid settles out.The resulting solution is:

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What molar concentration of silver ion could exist in a solution in which the concentration of CrO42- is 1.0 × 10-4 M? (Ksp of Ag2CrO4 = 1.1 × 10-12)

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The diverse ion effect is also called the salt effect.

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Which of the following is most soluble?

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In which of the following one molar aqueous solutions would you expect cadmium sulfide,CdS,to be the most soluble?

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When 100 mL each of 2.0 × 10-6 M Ag+(aq)and 2.0 × 10-3 M Br-(aq)are mixed,what is the remaining Ag+(aq)ion concentration and is precipitation complete? The solubility product constant of AgBr(s)is 5.0 × 10-13.

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The relationship between the molar concentration of silver ion in a saturated solution of silver phosphate and the solubility product constant for silver phosphate is ________.

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Write the solubility product constant expression for the following salt: Ag2SO4(s).

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Write the solubility product constant expression for the following salt: Ca3(PO4)2(s).

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Predict the molar solubility of the following salt in an aqueous solution that contains the given concentration of one of its ions: BaSO4;[SO42-] = 4.3 × 10-5 M;Ksp = 1.1 × 10-10

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Write the solubility product constant expression for the following salt: CoS(s).

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Equal volumes of 0.020 M Ag+(aq)solution and 2.0 M NH3(aq)solution are mixed.Kf for [Ag(NH3)2]+ is 1.6 × 107.If trisodium arsenate is added so that the arsenate ion concentration is 0.10 M,will silver arsenate precipitate? What is Qsp? Ksp for silver arsenate is 1.0 × 10-22.

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To a concentrated buffer of pH 4.0 is added an equal volume of an aqueous solution that is 0.020 M in Cr3+,Cd2+ and Al3+.The expected precipitate would consist of ________. To a concentrated buffer of pH 4.0 is added an equal volume of an aqueous solution that is 0.020 M in Cr<sup>3+</sup>,Cd<sup>2+</sup> and Al<sup>3+</sup>.The expected precipitate would consist of ________.

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At a temperature for which the solubility product constant of calcium carbonate is 4.7 × 10-9,what mass of the salt will dissolve in 100 mL of water?

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A swimming pool was sufficiently alkaline so that the carbon dioxide absorbed from the air produced a solution in the pool that was 2 × 10-4 M in carbonate ion.If the pool originally contained 4 × 10-3 M Mg2+,6 × 10-4 M Ca2+,and 8 × 10-7 M Fe2+,then the precipitate that was formed consisted of ________. (Ksp values are: CaCO3,4.7 × 10-9;MgCO3,4.0 × 10-5;FeCO3,2.0 × 10-11)

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