Exam 15: Principles of Chemical Equilibrium

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Consider the equilibrium system: N2O4(g)⇌ 2 NO2(g)for which Kp = 0.1134 at 25 °C and ΔrH° = 58.03 kJ/mol.Assuming that the total pressure inside the container is 10 atm at equilibrium and that initially only N2O4 was present inside the container,compute Consider the equilibrium system: N<sub>2</sub>O<sub>4</sub>(g)⇌ 2 NO<sub>2</sub>(g)for which K<sub>p</sub> = 0.1134 at 25 °C and Δ<sub>r</sub>H° = 58.03 kJ/mol.Assuming that the total pressure inside the container is 10 atm at equilibrium and that initially only N<sub>2</sub>O<sub>4</sub> was present inside the container,compute   At equilibrium. At equilibrium.

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4.000 mol chlorine and 2.000 mol bromine were placed in a 50.0 L container and kept at 293 K until equilibrium was achieved for the reaction: Br2(l)+ Cl2(g)⇌ 2 BrCl(g) At the point of equilibrium there were 82.63 g of Br2(l).Determine the total pressure in the 50.0 L container at equilibrium.

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For the reaction;N2(g)+ 3 H2(g)⇌ 2 NH3(g),the equilibrium amount of NH3 will be increased by: I.increasing the pressure II.adding H2 III.removing N2 IV.decreasing the pressure

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Consider the following gas phase reaction at 25 °C. N2(g)+ C2H2(g)⇌ 2 HCN(g) 1.600 mol N2(g)and 1.750 mol C2H2(g)are placed in a 1.000 L vessel and the mixture is allowed to react.At equilibrium,there are 1.587 mol N2(g)in the mixture.What is Kc for this reaction at 25 °C?

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Write the equilibrium expression Kc for the reaction: Sodium sulfite(aq)+ chloric acid (aq)⇌ sodium chlorate(aq)+ sulfur dioxide(g)+ water(l).

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A mixture,containing 0.0750 M HCl(g)and 0.0330 M O2(g)is allowed to come to equilibrium at 480 °C. 4 HCl(g)+ O2(g)⇌ 2 Cl2(g)+ 2 H2O(g) At equilibrium [Cl2] = 0.030 M.What is the value of Kc?

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For the following reaction O2(g)⇌ 2 O(g) What conditions favor production of oxygen atoms?

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In a reaction at equilibrium involving only gases,a change in pressure of the reaction mixture shifts the position of equilibrium only when:

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For the reaction: PCl3(g)+ Cl2(g)⇌ PCl5(g)at 85 °C,Kp = 1.19 If one starts with 2.00 atm pressure of PCl3,1.00 atm pressure of Cl2 and no PCl5,what is the partial pressure of PCl5(g)at equilibrium?

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For CO2(g)+ H2(g)⇌ CO(g)+ H2O(g),Kc = [CO][H2]/[CO2][H2],if there are 1.43 mols each of CO and H2O,0.572 mol H2 and 4.572 mols CO2,in a 4.0 L container at equilibrium,what is Kc?

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For the reaction below CO(g)+ 2 H2(g)⇌ CH3OH(g) The equilibrium concentrations at 483 K are [CO] = 0.0753 M,[H2] = 0.151 M,and [CH3OH] = 0.0247 M.Calculate the value of Kc.

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Changes in temperature cause change in the equilibrium position.

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For 2 NO2(g)⇌ N2O4(g),Kc = [N2O4]/[NO2]2.At equilibrium there are 0.0270 mol N2O4 and 0.450 mol NO2 in a 50.0-L container.What is Kc?

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Consider the following reaction at a certain temperature. 2 SO3(g)⇌ 2 SO2(g)+ O2(g) When the initial concentration of SO3(g)is 0.128 M,the concentration of oxygen gas at equilibrium is found to be 0.0130 M.Calculate Kc for this reaction.

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For the reaction: H2(g)+ I2(g)⇌ 2 HI(g),Kc = 92.0 When equilibrium concentrations of HI and I2 are [HI] = 0.115 M and [I2] = 0.250 M,the equilibrium concentration of [H2] is:

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What will happen to the equilibrium in the reaction 2 A(g)⇌ B(g)+ C(g),Kc = 1.25 at 300 K,if a catalyst is added?

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For the reaction: CH4(g)+ 2 H2O(g)⇌ CO2(g)+ 4 H2(g),ΔrH° = +190 kJ,when the temperature is raised to 1200 K:

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Consider the following equation: N2O4(g)⇌ 2 NO2(g),Kc = 5.8 × 10-3 If the initial concentration of N2O4(g)= 0.040 M and the initial concentration of NO2(g)is 0 M,what is the equilibrium concentration of N2O4(g)?

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