Exam 15: Principles of Chemical Equilibrium
Exam 1: Matter: Its Properties and Measurement136 Questions
Exam 2: Atoms and the Atomic Theory119 Questions
Exam 3: Chemical Compounds152 Questions
Exam 4: Chemical Reactions170 Questions
Exam 5: Introduction to Reactions in Aqueous Solutions124 Questions
Exam 6: Gases113 Questions
Exam 7: Thermochemistry125 Questions
Exam 8: Electrons in Atoms123 Questions
Exam 9: The Periodic Table and Some Atomic Properties93 Questions
Exam 10: Chemical Bonding I: Basic Concepts107 Questions
Exam 11: Chemical Bonding Ii: Valence Bond and Molecular Orbital Theories104 Questions
Exam 12: Intermolecular Forces: Liquids and Solids121 Questions
Exam 13: Spontaneous Change: Entropy and Gibbs Energy123 Questions
Exam 14: Solutions and Their Physical Properties132 Questions
Exam 15: Principles of Chemical Equilibrium118 Questions
Exam 16: Acids and Bases137 Questions
Exam 17: Additional Aspects of Acidbase Equilibria130 Questions
Exam 18: Solubility and Complex-Ion Equilibria104 Questions
Exam 19: Electrochemistry127 Questions
Exam 20: Chemical Kinetics124 Questions
Exam 21: Chemistry of the Main-Group Elements I: Groups 1,2,13,and 14116 Questions
Exam 22: Chemistry of the Main-Group Elements Ii: Groups 18,17,16,15,and Hydrogen100 Questions
Exam 23: The Transition Elements108 Questions
Exam 24: Complex Ions and Coordination Compounds104 Questions
Exam 25: Nuclear Chemistry116 Questions
Exam 26: Structures of Organic Compounds99 Questions
Exam 27: Reactions of Organic Compounds94 Questions
Exam 28: Chemistry of the Living State104 Questions
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At 35 °C,Kp = 0.315 for the reaction N2O4(g)⇌ 2 NO2(g),if the initial pressure of NO2(g)in a container is 3.00 atm,what is the equilibrium pressure of N2O4(g)?
(Multiple Choice)
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Choose the correct statement about a container in which the chemical equilibrium is established:
2 SO2(g)+ O2(g)⇌ 2 SO3(g)+ heat
(Multiple Choice)
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For the reaction: CH4(g)+ 2 H2O(g)⇌ CO2(g)+ 4 H2(g),ΔH° = +190 kJ,when H2(g)is added:
(Multiple Choice)
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A mixture containing 0.392 M A(g)and 0.452 M B(g)is allowed to come to equilibrium at 300 K.The reaction 3 A(g)+ 2 B(g)⇌ C(g)+ D(g)occurs.At equilibrium,[C] = 0.00128 M.What is the value of Kc?
(Multiple Choice)
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Consider the following chemical reaction at equilibrium:
2 Cl2(g)+ 2 H2O(g)⇌ 4 HCl(g)+ O2(g)
This equilibrium can be shifted to the right by:
(Multiple Choice)
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The decomposition of ammonia is 2 NH3(g)→ N2(g)+ 3 H2(g).If Kp is 1.5 × 103 at 400 °C,what is the partial pressure of ammonia at equilibrium when the partial pressure of N2(g)is 0.10 bar and that of H2(g)is 0.15 bar?
(Multiple Choice)
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2.5 moles H2O and 100 g of C are placed in a 50-L container.At equilibrium for the reaction C(s)+ H2O(g)⇌ CO(g)+ H2(g),[H2] = 0.040 M.Which of the following is true?
(Multiple Choice)
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Given the following:
I.N2O(g)+ 1/2 O2(g)⇌ 2 NO(g)Kc = 1.7 × 10-13
II.N2(g)+ O2(g)⇌ 2 NO(g)Kc = 4.1 × 10-31
Find the value of the equilibrium constant for the following equilibrium reaction:
N2(g)+ 1/2 O2(g)⇌ N2O(g)
(Multiple Choice)
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Consider the following equilibrium reaction: PCl3(g)+ Cl2(g)⇌ PCl5(g)Kc = 96.2 The equilibrium constant for the decomposition of PCl5(g)to PCl3(g)and Cl2(g)is ________.
(Multiple Choice)
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At a certain temperature,nitogen and hydrogen react to form ammonia:
N2(g)+ 3 H2(g)⇌ 2 NH3(g)
When initial amounts of N2,H2,and NH3 are mixed,the concentration of NH3 increases.Which statement below is TRUE?
(Multiple Choice)
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Given that the equilibrium concentrations of [N2] = 0.035 M,[C2H2] = 0.057 M,and [HCN] = 6.8 × 10-4 M,find the value of the equilibrium constant expression for the reaction:
N2(g)+ C2H2(g)⇌ 2 HCN
(Multiple Choice)
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For a solute (X)aq,in an ideal aqueous solution,its activity equals its concentration.
(True/False)
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The equilibrium constant,Kp,equals 3.40 at 25 °C for the isomerization reaction:
Cis-2-butene ⇌ trans-2-butene
If a flask initially contains 5.00 bar of each gas,in what direction will the system shift to reach equilibrium?
(Multiple Choice)
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For the reaction: 2 SO2(g)+ O2(g)⇌ 2 SO3(g),Kc = 6.9 × 1024 at 25 °C.If a reaction vessel is filled with these gases,such that [SO2] = 6.0 M,[O2] = 6.0 M and [SO3] = 6.0 M,in which direction will the reaction proceed?
(Multiple Choice)
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Which of the following substances present in the chemical reaction would be excluded from the equilibrium constant expression?
(Multiple Choice)
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For the reaction: CH4(g)+ 2 H2O(g)⇌ CO2(g)+ 4 H2(g),ΔrH° = +190 kJ,when CH4 is added:
(Multiple Choice)
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Both products and reactants will be present in an equilibrium reaction unless K is very small or very large.
(True/False)
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Large value for equilibrium constant K means the reaction will be less complete at the equilibrium point.
(True/False)
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For a reaction,the reaction quotient,Qc > Kc ,the reaction ________.
(Multiple Choice)
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