Exam 18: Thermodynamics and Equilibrium

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For the reaction CaCO3(s)→ CaO(s)+ O2(g)at 1 atm pressure,the values of ΔH and ΔS are both positive,and the process is spontaneous at high temperatures.Which of the following statements about this reaction is true?

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For which of the following substances is the standard free energy of formation not equal to zero at 298 K?

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Which of the following has a value of zero for the standard free energy of formation at 298 K?

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For the isothermal (constant-temperature)expansion of an ideal gas,

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For a reaction,if ΔG° = 0,then

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The reaction CaO(s)+ SO3(g)→ CaSO4(s)is nonspontaneous at 2200 K,whereas it is spontaneous at room temperature.Which of the following statements is false?

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What is the thermodynamic quantity that provides the criterion for the spontaneity of a chemical reaction?

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Which of the following is correct for the condensation of gaseous ammonia at -38°C? The normal boiling point of ammonia is -33°C.

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What is ΔG° at 298 K for the following equilibrium? Ag+(aq)+ 2NH3(aq) What is ΔG° at 298 K for the following equilibrium? Ag<sup>+</sup>(aq)+ 2NH<sub>3</sub>(aq)  Ag(NH<sub>3</sub>)<sub>2</sub><sup>+</sup>(aq); K<sub>f</sub> = 1.7 × 10<sup>7</sup> at 298 KAg(NH3)2+(aq); Kf = 1.7 × 107 at 298 K

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What is the change in internal energy (ΔU)of the system if q = -8 kJ and w = -1 kJ for a certain process?

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ΔH and ΔU are nearly the same in all the following processes except

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According to the first law of thermodynamics,the energy of the universe is constant.Does this mean that ΔE is always equal to zero?

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Consider the following reaction: 3C(s)+ 4H2(g)→ C3H8(g); ΔH° = -104.7 kJ; ΔS° = -287.4J/K at 298 K What is the equilibrium constant at 400.0 K for this reaction?

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What is ΔS° at 298 K for the following reaction? CH4(g)+ N2(g)→ HCN(g)+ NH3(g); ΔH° = 164.1 kJ; ΔG° = 159.1 kJ at 298 K

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