Exam 18: Thermodynamics and Equilibrium
Exam 1: Chemistry and Measurement111 Questions
Exam 2: Atoms, molecules, and Ions149 Questions
Exam 3: Calculations With Chemical Formulas and Equations139 Questions
Exam 4: Chemical Reactions159 Questions
Exam 5: The Gaseous State104 Questions
Exam 6: Thermochemistry119 Questions
Exam 7: Quantum Theory of the Atom68 Questions
Exam 8: Electron Configurations and Periodicity100 Questions
Exam 9: Ionic and Covalent Bonding125 Questions
Exam 10: Molecular Geometry and Chemical Bonding Theory101 Questions
Exam 11: States of Matter; Liquids and Solids123 Questions
Exam 12: Solutions119 Questions
Exam 13: Rates of Reaction113 Questions
Exam 14: Chemical Equilibrium97 Questions
Exam 15: Acids and Bases83 Questions
Exam 16: Acid-Base Equilibria148 Questions
Exam 17: Solubility and Complex-Ion Equilibria115 Questions
Exam 18: Thermodynamics and Equilibrium94 Questions
Exam 19: Electrochemistry122 Questions
Exam 20: Nuclear Chemistry90 Questions
Exam 21: Chemistry of the Main-Group Metals121 Questions
Exam 22: The Transition Elements and Coordination Compounds75 Questions
Exam 23: Organic Chemistry79 Questions
Exam 24: Polymer Materials: Synthetic and Biological56 Questions
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For the reaction CaCO3(s)→ CaO(s)+ O2(g)at 1 atm pressure,the values of ΔH and ΔS are both positive,and the process is spontaneous at high temperatures.Which of the following statements about this reaction is true?
(Multiple Choice)
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For which of the following substances is the standard free energy of formation not equal to zero at 298 K?
(Multiple Choice)
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Which of the following has a value of zero for the standard free energy of formation at 298 K?
(Multiple Choice)
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For the isothermal (constant-temperature)expansion of an ideal gas,
(Multiple Choice)
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The reaction CaO(s)+ SO3(g)→ CaSO4(s)is nonspontaneous at 2200 K,whereas it is spontaneous at room temperature.Which of the following statements is false?
(Multiple Choice)
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What is the thermodynamic quantity that provides the criterion for the spontaneity of a chemical reaction?
(Multiple Choice)
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Which of the following is correct for the condensation of gaseous ammonia at -38°C? The normal boiling point of ammonia is -33°C.
(Multiple Choice)
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What is ΔG° at 298 K for the following equilibrium?
Ag+(aq)+ 2NH3(aq)
Ag(NH3)2+(aq); Kf = 1.7 × 107 at 298 K
(Multiple Choice)
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What is the change in internal energy (ΔU)of the system if q = -8 kJ and w = -1 kJ for a certain process?
(Multiple Choice)
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ΔH and ΔU are nearly the same in all the following processes except
(Multiple Choice)
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According to the first law of thermodynamics,the energy of the universe is constant.Does this mean that ΔE is always equal to zero?
(Multiple Choice)
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Consider the following reaction:
3C(s)+ 4H2(g)→ C3H8(g); ΔH° = -104.7 kJ; ΔS° = -287.4J/K at 298 K
What is the equilibrium constant at 400.0 K for this reaction?
(Multiple Choice)
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What is ΔS° at 298 K for the following reaction?
CH4(g)+ N2(g)→ HCN(g)+ NH3(g); ΔH° = 164.1 kJ; ΔG° = 159.1 kJ at 298 K
(Multiple Choice)
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