Exam 6: Thermochemistry

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A bomb calorimeter has a heat capacity of 2.47 kJ/K.When a 0.106-g sample of a certain hydrocarbon was burned in this calorimeter,the temperature increased by 2.14 K.Calculate the energy of combustion for 1 g of the hydrocarbon.

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Which of the following is not a fuel-oxidizer mixture used in rockets?

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Which of the following is an endothermic process?

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A 86.9-g sample of chromium (s = 0.447 J/(g ∙ °C)),initially at 338.33°C,is added to an insulated vessel containing 189.9 g of water (s = 4.18 J/(g ∙ °C)),initially at 16.17°C.At equilibrium,the final temperature of the metal-water mixture is 28.06°C.How much heat was absorbed by the water? The heat capacity of the vessel is 0.220 kJ/°C.

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Given: Given:   what is ΔH for the following thermochemical equation?  what is ΔH for the following thermochemical equation? Given:   what is ΔH for the following thermochemical equation?

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Which of the following sentences accurately describes the thermochemical equation given below? 2Ag(s)+ F2(g)→ 2AgF(s); ΔH = -409.2 kJ

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How much heat is released at constant pressure if 12.3 mL of 0.161 M silver nitrate is mixed with 41.7 mL of 0.493 M potassium chloride? AgNO3(aq)+ KCl(aq)→ AgCl(s)+ KNO3(aq); ΔH° = -65.5 kJ

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Which of the following statements is true concerning the decomposition of liquid water to form hydrogen gas and oxygen gas? 2H2O(l)→ 2H2(g)+ O2(g)

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The energy associated with an object held above the surface of the earth is called _____.

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A 3.540-g sample of an unknown metal M is burned in the presence of excess oxygen,producing the oxide M2O3(s)and liberating 18.56 kJ of heat at constant pressure.What is the identity of the metal? 4M(s)+ 3O2(g)→ 2M2O3(s) Substance ΔH°f (kJ/mol) Yb2O3(s) -1814.6 Tb2O3(s) -1865.2 Sm2O3(s) -1823.0 Sc2O3(s) -1908.8 Y2O3(s) -1905.3

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What is the change in enthalpy at 25°C and 1 atm for the production of 3.00 mol SnO(s)? Sn(s)+ SnO2(s)→ 2SnO(s); ΔH° = 16.2 kJ

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Given the following thermochemical data at 25°C and 1 atm pressure, Given the following thermochemical data at 25°C and 1 atm pressure,   O<sub>2</sub>(g)+ 2B(s)→ B<sub>2</sub>O<sub>3</sub>(s); ΔH° = -1264 kJ O<sub>3</sub>(g)+ 2B(s)→ B<sub>2</sub>O<sub>3</sub>(s); ΔH° = -1406 kJ Determine ΔH° for the following reaction at 25°C and 1 atm pressure. 3O<sub>2</sub>(g)→ 2O<sub>3</sub>(g) O2(g)+ 2B(s)→ B2O3(s); ΔH° = -1264 kJ O3(g)+ 2B(s)→ B2O3(s); ΔH° = -1406 kJ Determine ΔH° for the following reaction at 25°C and 1 atm pressure. 3O2(g)→ 2O3(g)

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When 56.8 g of lead reacts with 3.50 L of oxygen gas,measured at 1.00 atm and 25.0°C,60.1 kJ of heat is released at constant pressure.What is ΔH° for this reaction? (R = 0.0821 L • atm/(K • mol)) 2Pb(s)+ O2(g)→ 2PbO(s)

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In a certain experiment,0.7000 mol of hydrogen gas reacted with 0.7000 mol of solid iodine at a constant 1 atm pressure,producing 1.4000 mol of solid hydrogen iodide and absorbing 36.9 kJ of heat in the process.Which of the following thermochemical equations correctly describes this experiment?

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Which of the following has a standard enthalpy of formation value of zero at 25°C?

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What is ΔH° of the following reaction? CO2(g)+ 2CH4(g)→ C3H8(g)+ O2(g) Substance ΔH°f (kJ/mol) CO2(g) -393.5 CH4(g) -74)9 C3H8(g) -104.7

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Given that O(g)+ e- → O-(g); ΔH = -142 kJ O(g)+ 2e- → O2-(g); ΔH = 702 kJ The enthalpy change for the reaction represented by the equation O-(g)+ e- → O2-(g)is

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A 84.8-g piece of silver (s = 0.237 J/(g ∙ °C)),initially at 268.0°C,is added to 128.4 g of a liquid,initially at 24.9°C,in an insulated container.The final temperature of the metal-liquid mixture at equilibrium is 39.6°C.What is the identity of the liquid? Neglect the heat capacity of the container.

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The units for specific heat are

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