Exam 6: Thermochemistry

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Given the following data,calculate the standard enthalpy of reaction for the conversion of buckminsterfullerene (C60)into diamond: Given the following data,calculate the standard enthalpy of reaction for the conversion of buckminsterfullerene (C<sub>60</sub>)into diamond:   C(graphite)→ C(diamond); ΔH° = +1.897 kJ 60C(graphite)→ C<sub>60</sub>(fullerene); ΔH° = +2193 kJ C(graphite)→ C(diamond); ΔH° = +1.897 kJ 60C(graphite)→ C60(fullerene); ΔH° = +2193 kJ

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Using the following data,calculate the standard enthalpy of reaction for the coal gasification process 2C(s)+ 2H2O(g)→ CH4(g)+ CO2(g). C(s)+ H2O(g)→ CO(g)+ H2(g); ΔH° = +131.3 kJ CO(g)+ H2O(g)→ CO2(g)+ H2(g); ΔH° = -41.2 kJ CO(g)+ 3H2(g)→ CH4(g)+ H2O(g); ΔH° = -206.1 kJ

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At constant pressure and 25°C,what is ΔH° for the following reaction 2C2H6(g)+ 7O2(g)→ 4CO2(g)+ H2O(l) If the complete consumption of 38.2 g of C2H6 liberates 1981 kJ of heat energy?

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Determine the kinetic energy of an 88.0 kg body moving with an average speed of 52.6 m/s.

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Which of the following species does not have a standard enthalpy of formation equal to zero at 25°C?

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All of the following have a standard enthalpy of formation value of zero at 25°C except

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A 500-cm3 sample of 1.0 M NaOH(aq)is added to 500 cm3 of 1.0 M HCl(aq)in a Styrofoam cup,and the solution is quickly stirred.The rise in temperature (ΔT1)is measured.The experiment is repeated using 100 cm3 of each solution,and the rise in temperature (ΔT2)is measured.What conclusion can you draw about ΔT1 and ΔT2? HCl(aq)+ NaOH(aq)→ H2O(l)+ NaCl(aq); ΔH° = -55.8 kJ

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What is the standard enthalpy of formation of CaCO3(s)? CaO(s)+ CO2(g)→ CaCO3(s); ΔH° = -179.4 kJ Substance ΔH°f (kJ/mol) CaO(s) -634.9 CO2(g) -393.5

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What is the standard enthalpy of formation of liquid diethylamine,(CH3CH2)2NH? N2O5(g)+ 8CH4(g)→ 2(CH3CH2)2NH(l)+ 5H2O(l); ΔH° = -1103 kJ Substance ΔH°f (kJ/mol) N2O5(g) +11)3 CH4(g) -74)9 H2O(l) -285.8

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What is the change in internal energy of the system (ΔU)if 71 kJ of heat energy is absorbed by the system and 12 kJ of work is done on the system for a certain process?

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How much heat is liberated at constant pressure if 0.833 g of calcium carbonate reacts with 59.7 mL of 0.251 M hydrochloric acid? CaCO3(s)+ 2HCl(aq)→ CaCl2(aq)+ H2O(l)+ CO2(g); ΔH° = -15.2 kJ

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It is relatively easy to change the temperature of a substance that

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When 9.42 g of methane (CH4)is burned in a bomb calorimeter (heat capacity = 2.677 × 103 J/°C),the temperature rises from 24.00 to 27.08°C.How much heat is absorbed by the calorimeter? CH4(g)+ 2O2(g)→ CO2(g)+ 2H2O(l); ΔH° = -1283.8 kJ

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A 1.67-g sample of solid silver reacted in excess chlorine gas to give a 2.21-g sample of pure solid AgCl.The heat given off in this reaction was 1.96 kJ at constant pressure.Given this information,what is the enthalpy of formation of AgCl(s)?

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The standard enthalpy change for which of the following processes corresponds to the standard enthalpy of formation of solid lithium chloride?

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When 13.8 mL of 0.870 M lead(II)nitrate reacts with 90.0 mL of 0.777 M sodium chloride,0.279 kJ of heat is released at constant pressure.What is ΔH° for this reaction? Pb(NO3)2(aq)+ 2NaCl(aq)→ PbCl2(s)+ 2NaNO3(aq)

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Which of the following processes will result in the lowest final temperature of the metal-water mixture at equilibrium? The specific heat of cobalt is 0.421 J/(g ∙ °C).

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Which of the following statements about enthalpy is false?

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What is the change in enthalpy at 25°C and 1 atm for the reaction of 5.00 mol of elemental iron with excess oxygen gas? 4Fe(s)+ 3O2(g)→ 2Fe2O3(s); ΔH° = -1651 kJ

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Which of the following has a standard enthalpy of formation value of zero at 25°C?

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