Exam 6: Thermochemistry
Exam 1: Chemistry and Measurement111 Questions
Exam 2: Atoms, molecules, and Ions149 Questions
Exam 3: Calculations With Chemical Formulas and Equations139 Questions
Exam 4: Chemical Reactions159 Questions
Exam 5: The Gaseous State104 Questions
Exam 6: Thermochemistry119 Questions
Exam 7: Quantum Theory of the Atom68 Questions
Exam 8: Electron Configurations and Periodicity100 Questions
Exam 9: Ionic and Covalent Bonding125 Questions
Exam 10: Molecular Geometry and Chemical Bonding Theory101 Questions
Exam 11: States of Matter; Liquids and Solids123 Questions
Exam 12: Solutions119 Questions
Exam 13: Rates of Reaction113 Questions
Exam 14: Chemical Equilibrium97 Questions
Exam 15: Acids and Bases83 Questions
Exam 16: Acid-Base Equilibria148 Questions
Exam 17: Solubility and Complex-Ion Equilibria115 Questions
Exam 18: Thermodynamics and Equilibrium94 Questions
Exam 19: Electrochemistry122 Questions
Exam 20: Nuclear Chemistry90 Questions
Exam 21: Chemistry of the Main-Group Metals121 Questions
Exam 22: The Transition Elements and Coordination Compounds75 Questions
Exam 23: Organic Chemistry79 Questions
Exam 24: Polymer Materials: Synthetic and Biological56 Questions
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What is the standard enthalpy of formation of liquid n-butanol,CH3CH2CH2CH2OH?
CH3CH2CH2CH2OH(l)+ 6O2(g)→ 4CO2(g)+ 5H2O(l); ΔH° = -2675 kJ
Substance
ΔH°f (kJ/mol)
CO2(g)
-393.5
H2O(l)
-285.8
(Multiple Choice)
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Which of the following statements is not true for an exothermic reaction?
(Multiple Choice)
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The phrase "the heat absorbed or released by a system undergoing a physical or chemical change at constant pressure" is
(Multiple Choice)
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What is the standard enthalpy of formation of liquid butyraldehyde,CH3CH2CH2CHO(l)?
CH3CH2CH2CHO(l)+
O2(g)→ 4H2O(l)+ 4CO2(g); ΔH° = -2471.8 kJ
Substance
ΔH°f (kJ/mol)
CO2(g)
-393.5
H2O(l)
-285.8
(Multiple Choice)
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A 8.22-g sample of solid calcium reacted in excess fluorine gas to give a 16-g sample of pure solid CaF2.The heat given off in this reaction was 251 kJ at constant pressure.Given this information,what is the enthalpy of formation of CaF2(s)?
(Multiple Choice)
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What is the standard enthalpy change for the following reaction?
N2H4(l)+ 2NO2(g)→ 2N2O(g)+ 2H2O(l)
Substance
ΔH°f (kJ/mol)
N2H4(l)
+50)6
NO2(g)
+33)1
N2O(g)
+82)1
H2O(l)
-285.8
(Multiple Choice)
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Using two or more of the following,
N2(g)+
O2(g)→ N2O3(s); ΔH° = 83.7 kJ
N2(g)+ O2(g)→ 2NO(g); ΔH° = 180.4 kJ
N2(g)+ O2(g)→ NO2(g); ΔH° = 33.2 kJ
N2(g)+
H2(g)→ NH3(g); ΔH° = −45.9 kJ
Determine ΔH° for the following reaction.
NO(g)+ NO2(g)→ N2O3(g)
(Multiple Choice)
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H2 and F2 react according to the following equation,forming HF.
H2(g)+ F2(g)→ 2HF(g); ΔH° = -271 kJ
If H2(g)and F2(g)were mixed in a thermally insulated vessel,the reaction that occurred would be
(Multiple Choice)
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Under conditions of constant pressure,for which of the following reactions is the magnitude of pressure-volume work going to be smallest?
(Multiple Choice)
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What quantity,in moles,of oxygen is consumed when 717.4 kJ of energy is evolved from the combustion of a mixture of H2(g)and O2(g)?
H2(g)+
O2(g)→ H2O(l); ΔH° = -285.8 kJ
(Multiple Choice)
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At constant pressure,the sign of q for the process H2O(l)→ H2O(s)is expected to be
(Multiple Choice)
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A 70.4-L sample of a gaseous hydrocarbon,measured at 1.00 atm pressure and 25.0°C,is burned in excess oxygen,liberating 4.06 × 103 kJ of heat at constant pressure.What is the identity of the hydrocarbon? (R = 0.0821 L ∙ atm/(K ∙ mol))
Substance
ΔH°f (kJ/mol)
CO2(g)
-393.5
H2O(l)
-285.8
(Multiple Choice)
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At 25°C,when 1.00 g of sulfur is burned at constant pressure in excess oxygen to give SO2(g),9.28 kJ of heat is liberated.What is the enthalpy of formation of SO2(g)?
(Multiple Choice)
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When 22.0 mL of liquid benzene (C6H6,d = 0.879 g/mL)reacts with 34.2 L of oxygen gas,measured at 1.00 atm pressure and 25°C,6.09 × 102 kJ of heat is released at constant pressure.What is ΔH° for the following reaction? (R = 0.0821 L • atm/(K • mol))
2C6H6(l)+ 15O2(g)→ 12CO2(g)+ 6H2O(l)
(Multiple Choice)
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The energy associated with the motion of molecules in a gas is called _____.
(Multiple Choice)
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The quantity of heat required to raise the temperature of a sample of a substance by 1°C is the sample's
(Multiple Choice)
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Given:
Pb(s)+ PbO2(s)+ 2H2SO4(l)→ 2PbSO4(s)+ 2H2O(l); ΔH° = -509.2 kJ
SO3(g)+ H2O(l)→ H2SO4(l); ΔH° = -130.kJ
Determine ΔH° for the following thermochemical equation.
Pb(s)+ PbO2(s)+ 2SO3(g)→ 2PbSO4(s)
(Multiple Choice)
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The standard enthalpies of formation of various iodine species are as follows:
Substance
ΔH°f (kJ/mol)
I(g)
+107
I2(g)
+21
HI(g)
+26
What additional information is needed to calculate the standard enthalpy change of the following reaction?
H2(g)+ I2(g)→ 2HI(g)
(Multiple Choice)
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Consider the following thermochemical equation:
N2(g)+ 2O2(g)→ 2NO2(g); ΔH° = 66.2 kJ
From this equation,we may conclude that 66.2 kJ is the quantity of heat that is
(Multiple Choice)
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