Exam 6: Thermochemistry

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What is the standard enthalpy of formation of liquid n-butanol,CH3CH2CH2CH2OH? CH3CH2CH2CH2OH(l)+ 6O2(g)→ 4CO2(g)+ 5H2O(l); ΔH° = -2675 kJ Substance ΔH°f (kJ/mol) CO2(g) -393.5 H2O(l) -285.8

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Which of the following statements is not true for an exothermic reaction?

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The phrase "the heat absorbed or released by a system undergoing a physical or chemical change at constant pressure" is

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What is the standard enthalpy of formation of liquid butyraldehyde,CH3CH2CH2CHO(l)? CH3CH2CH2CHO(l)+ What is the standard enthalpy of formation of liquid butyraldehyde,CH<sub>3</sub>CH<sub>2</sub>CH<sub>2</sub>CHO(l)? CH<sub>3</sub>CH<sub>2</sub>CH<sub>2</sub>CHO(l)+   O<sub>2</sub>(g)→ 4H<sub>2</sub>O(l)+ 4CO<sub>2</sub>(g); ΔH° = -2471.8 kJ Substance ΔH°<sub>f</sub> (kJ/mol) CO<sub>2</sub>(g) -393.5 H<sub>2</sub>O(l) -285.8 O2(g)→ 4H2O(l)+ 4CO2(g); ΔH° = -2471.8 kJ Substance ΔH°f (kJ/mol) CO2(g) -393.5 H2O(l) -285.8

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A 8.22-g sample of solid calcium reacted in excess fluorine gas to give a 16-g sample of pure solid CaF2.The heat given off in this reaction was 251 kJ at constant pressure.Given this information,what is the enthalpy of formation of CaF2(s)?

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What is the standard enthalpy change for the following reaction? N2H4(l)+ 2NO2(g)→ 2N2O(g)+ 2H2O(l) Substance ΔH°f (kJ/mol) N2H4(l) +50)6 NO2(g) +33)1 N2O(g) +82)1 H2O(l) -285.8

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Using two or more of the following, N2(g)+ Using two or more of the following, N<sub>2</sub>(g)+   O<sub>2</sub>(g)→ N<sub>2</sub>O<sub>3</sub>(s); ΔH° = 83.7 kJ N<sub>2</sub>(g)+ O<sub>2</sub>(g)→ 2NO(g); ΔH° = 180.4 kJ   N<sub>2</sub>(g)+ O<sub>2</sub>(g)→ NO<sub>2</sub>(g); ΔH° = 33.2 kJ   N<sub>2</sub>(g)+   H<sub>2</sub>(g)→ NH<sub>3</sub>(g); ΔH° = −45.9 kJ Determine ΔH° for the following reaction. NO(g)+ NO<sub>2</sub>(g)→ N<sub>2</sub>O<sub>3</sub>(g) O2(g)→ N2O3(s); ΔH° = 83.7 kJ N2(g)+ O2(g)→ 2NO(g); ΔH° = 180.4 kJ Using two or more of the following, N<sub>2</sub>(g)+   O<sub>2</sub>(g)→ N<sub>2</sub>O<sub>3</sub>(s); ΔH° = 83.7 kJ N<sub>2</sub>(g)+ O<sub>2</sub>(g)→ 2NO(g); ΔH° = 180.4 kJ   N<sub>2</sub>(g)+ O<sub>2</sub>(g)→ NO<sub>2</sub>(g); ΔH° = 33.2 kJ   N<sub>2</sub>(g)+   H<sub>2</sub>(g)→ NH<sub>3</sub>(g); ΔH° = −45.9 kJ Determine ΔH° for the following reaction. NO(g)+ NO<sub>2</sub>(g)→ N<sub>2</sub>O<sub>3</sub>(g) N2(g)+ O2(g)→ NO2(g); ΔH° = 33.2 kJ Using two or more of the following, N<sub>2</sub>(g)+   O<sub>2</sub>(g)→ N<sub>2</sub>O<sub>3</sub>(s); ΔH° = 83.7 kJ N<sub>2</sub>(g)+ O<sub>2</sub>(g)→ 2NO(g); ΔH° = 180.4 kJ   N<sub>2</sub>(g)+ O<sub>2</sub>(g)→ NO<sub>2</sub>(g); ΔH° = 33.2 kJ   N<sub>2</sub>(g)+   H<sub>2</sub>(g)→ NH<sub>3</sub>(g); ΔH° = −45.9 kJ Determine ΔH° for the following reaction. NO(g)+ NO<sub>2</sub>(g)→ N<sub>2</sub>O<sub>3</sub>(g) N2(g)+ Using two or more of the following, N<sub>2</sub>(g)+   O<sub>2</sub>(g)→ N<sub>2</sub>O<sub>3</sub>(s); ΔH° = 83.7 kJ N<sub>2</sub>(g)+ O<sub>2</sub>(g)→ 2NO(g); ΔH° = 180.4 kJ   N<sub>2</sub>(g)+ O<sub>2</sub>(g)→ NO<sub>2</sub>(g); ΔH° = 33.2 kJ   N<sub>2</sub>(g)+   H<sub>2</sub>(g)→ NH<sub>3</sub>(g); ΔH° = −45.9 kJ Determine ΔH° for the following reaction. NO(g)+ NO<sub>2</sub>(g)→ N<sub>2</sub>O<sub>3</sub>(g) H2(g)→ NH3(g); ΔH° = −45.9 kJ Determine ΔH° for the following reaction. NO(g)+ NO2(g)→ N2O3(g)

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The internal energy of a substance is defined as

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H2 and F2 react according to the following equation,forming HF. H2(g)+ F2(g)→ 2HF(g); ΔH° = -271 kJ If H2(g)and F2(g)were mixed in a thermally insulated vessel,the reaction that occurred would be

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Under conditions of constant pressure,for which of the following reactions is the magnitude of pressure-volume work going to be smallest?

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What quantity,in moles,of oxygen is consumed when 717.4 kJ of energy is evolved from the combustion of a mixture of H2(g)and O2(g)? H2(g)+ What quantity,in moles,of oxygen is consumed when 717.4 kJ of energy is evolved from the combustion of a mixture of H<sub>2</sub>(g)and O<sub>2</sub>(g)? H<sub>2</sub>(g)+   O<sub>2</sub>(g)→ H<sub>2</sub>O(l); ΔH° = -285.8 kJ O2(g)→ H2O(l); ΔH° = -285.8 kJ

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At constant pressure,the sign of q for the process H2O(l)→ H2O(s)is expected to be

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A 70.4-L sample of a gaseous hydrocarbon,measured at 1.00 atm pressure and 25.0°C,is burned in excess oxygen,liberating 4.06 × 103 kJ of heat at constant pressure.What is the identity of the hydrocarbon? (R = 0.0821 L ∙ atm/(K ∙ mol)) Substance ΔH°f (kJ/mol) CO2(g) -393.5 H2O(l) -285.8

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At 25°C,when 1.00 g of sulfur is burned at constant pressure in excess oxygen to give SO2(g),9.28 kJ of heat is liberated.What is the enthalpy of formation of SO2(g)?

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When 22.0 mL of liquid benzene (C6H6,d = 0.879 g/mL)reacts with 34.2 L of oxygen gas,measured at 1.00 atm pressure and 25°C,6.09 × 102 kJ of heat is released at constant pressure.What is ΔH° for the following reaction? (R = 0.0821 L • atm/(K • mol)) 2C6H6(l)+ 15O2(g)→ 12CO2(g)+ 6H2O(l)

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The energy associated with the motion of molecules in a gas is called _____.

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The quantity of heat required to raise the temperature of a sample of a substance by 1°C is the sample's

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Given: Pb(s)+ PbO2(s)+ 2H2SO4(l)→ 2PbSO4(s)+ 2H2O(l); ΔH° = -509.2 kJ SO3(g)+ H2O(l)→ H2SO4(l); ΔH° = -130.kJ Determine ΔH° for the following thermochemical equation. Pb(s)+ PbO2(s)+ 2SO3(g)→ 2PbSO4(s)

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The standard enthalpies of formation of various iodine species are as follows: Substance ΔH°f (kJ/mol) I(g) +107 I2(g) +21 HI(g) +26 What additional information is needed to calculate the standard enthalpy change of the following reaction? H2(g)+ I2(g)→ 2HI(g)

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Consider the following thermochemical equation: N2(g)+ 2O2(g)→ 2NO2(g); ΔH° = 66.2 kJ From this equation,we may conclude that 66.2 kJ is the quantity of heat that is

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