Exam 12: Chemical Kinetics: Rates of Reactions

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The rate constant for the first order decomposition of SO2Cl2 is 1.37 × 10-3 min-1 at a certain temperature. If the concentration is initially 0.500 M, predict it after 300 min.

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The solid catalysts used in many industrial processes where the reactants are liquids or gases are referred to as

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The rate of a chemical reaction may be expressed as

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Consider the reaction with the mechanism shown: Consider the reaction with the mechanism shown:  The first step is ____; the second step is ____; and the third step is ____.The first step is ____; the second step is ____; and the third step is ____.

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Which of the following factors increases the rate of a chemical reaction by decreasing the activation energy barrier?

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In a heterogeneous chemical reaction requiring the use of a solid catalyst, the rate of the reaction could not be increased by increasing the concentration of reactants, but was doubled by doubling the amount of solid catalyst added. This probably indicated that

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For many homogeneous reactions, the rate law has the general form

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For the reaction For the reaction   the integrated rate law for a particular order of reaction the integrated rate law for a particular order of reaction

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The table below gives the concentration of a substance A as a function of time at 473 K. The table below gives the concentration of a substance A as a function of time at 473 K.     a.	Establish whether the reaction is zeroth, first or second-order in A. b.	Calculate the rate constant at 473 K for this reaction. a. Establish whether the reaction is zeroth, first or second-order in A. b. Calculate the rate constant at 473 K for this reaction.

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The ____of a multistep reaction can be predicted unambiguously from the ____, but not vice versa.

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At a given temperature, the kinetics parameters for a new chemical reaction are determined in the following sequence from first to last

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Exhibit 12-2 For the following question(s), consider the following reaction mechanism: Exhibit 12-2 For the following question(s), consider the following reaction mechanism:   Refer to Exhibit 12-2. The catalysts in this reaction are Refer to Exhibit 12-2. The catalysts in this reaction are

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The best description of the induced fit model of enzyme function is

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Which of the following units may be used for describing reaction rates?

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The substrate in an enzyme-controlled biological reaction is a

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Which of the following factors increases the rate of a chemical reaction by increasing the fraction of molecules with energy in excess of a given value?

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Which of the following best describes a typical mechanism for an enzyme-catalyzed reaction?

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Exhibit 12-2 For the following question(s), consider the following reaction mechanism: Exhibit 12-2 For the following question(s), consider the following reaction mechanism:   Refer to Exhibit 12-2. The rate-limiting step in this reaction is Step ____, because ____. Refer to Exhibit 12-2. The rate-limiting step in this reaction is Step ____, because ____.

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The reaction The reaction   is ____ order with respect to NO, ____order with respect to Cl<sub>2</sub>, and ____ order overall. is ____ order with respect to NO, ____order with respect to Cl2, and ____ order overall.

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The function of an automobile catalytic converter is to convert

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