Exam 14: Chemical Equilibrium

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The equilibrium constant is given for one of the reactions below.Determine the value of the missing equilibrium constant. 2 HD(g)⇌ H2(g)+ D2(g)Kc = 0.28 6 H2(g)+ 6 D2(g)⇌ 12 HD(g)Kc = ?

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Which of the following statements are true?

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Consider the following reaction at equilibrium.What effect will reducing the volume of the reaction mixture have on the system? CuS(s)+ O2(g)⇌ Cu(s)+ SO2(g)

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What is △n for the following equation in relating Kc to Kp? H2(g)+ Br2(g)⇌ 2 HBr(g)

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Express the equilibrium constant for the following reaction. 2 CH3Cl(g)+ Cl2(g)⇌ 2 CH2Cl2(g)+ H2(g)

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Cyclohexane (C6H12)undergoes a molecular rearrangement in the presence of AlCl3 to form methylcyclopentane (MCP)according to the equation: C6H12 ⇌ MCP If Kc = 0.143 at 25°C for this reaction,predict the direction in which the system will shift if the initial concentrations of C6H12 and MCP are 0.0400 M and 0.0200 M,respectively.The system

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Define reaction quotient.

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What is △n for the following equation in relating Kc to Kp? 2 NH3(g)⇌ N2(g)+ 3 H2(g)

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Consider the following reaction: 2 H2O(g)+ 2 SO2(g)⇌ 2 H2S(g)+ 3 O2(g) A reaction mixture initially contains 2.8 M H2O and 2.6 M SO2.Determine the equilibrium concentration of H2S if Kc for the reaction at this temperature is 1.3 × 10-6.

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Determine the value of Kc for the following reaction if the equilibrium concentrations are as follows: [N2]eq = 3.6 M,[O2]eq = 4.1 M,[N2O]eq = 3.3 × 10-18 M. 2 N2(g)+ O2(g)⇌ 2 N2O(g)

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Dinitrogen tetroxide partially decomposes according to the following equilibrium: N2O4(g)→ 2NO2(g) A 1.000-L flask is charged with 3.00 × 10-2 mol of N2O4.At equilibrium,2.36 × 10-2 mol of N2O4 remains.Keq for this reaction is ________.

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Which of the following statements is false?

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Cyclohexane,C6H12,undergoes a molecular rearrangement in the presence of AlCl3 to form methylcyclopentane,CH3C5H9, according to the equation: C6H12 ⇌ CH3C5H9 If Kc = 0.143 at 25°C for this reaction,find the equilibrium concentrations of C6H12 and CH3C5H9 if the initial concentrations are 0.200 M and 0.075 M,respectively.

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Explain dynamic equilibrium.Use the generic reaction A(g)⇌ B(g)to explain.

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The Kp for the reaction below is 1.49 × 108 at 100.0°C: CO(g)+ Cl2(g)⇌ COCl2(g) In an equilibrium mixture of the three gases,PCO = PCl2 = 2.22 × 10-4 atm.The partial pressure of the product,phosgene (COCl2),is ________ atm.

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Consider the following reaction at equilibrium.What effect will increasing the temperature have on the system? Fe3O4(s)+ CO(g)⇌ 3 FeO(s)+ CO2(g)ΔH°= +35.9 kJ

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What is △n for the following equation in relating Kc to Kp? 2 Rb(s)+ 2 H2O(l)⇌ 2 RbOH(aq)+ H2(g)

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The equilibrium constant is given for two of the reactions below.Determine the value of the missing equilibrium constant. A(g)+ 2B(g)⇌ AB2(g)Kc = 59 AB2(g)+ B(g)⇌ AB3(g)Kc = ? A(g)+ 3B(g)⇌ AB3(g)Kc = 478

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Which is true for a chemical reaction at equilibrium?

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Consider the following reaction: CuS(s)+ O2(g)⇌ Cu(s)+ SO2(g) A reaction mixture initially contains 2.9 M O2.Determine the equilibrium concentration of O2 if Kc for the reaction at this temperature is 1.5.

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