Exam 14: Chemical Equilibrium

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Consider the following reaction at equilibrium.What effect will increasing the temperature have on the system? C3H8(g)+ 5 O2(g)⇌ 3 CO2(g)+ 4 H2O(l)ΔH° = -2220 kJ

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Express the equilibrium constant for the following reaction. KClO3(s)⇌ KClO(s)+ O2(g)

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The equilibrium constant,Kp,equals 3.40 at 25°C for the isomerization reaction: Cis-2-butene ⇌ trans-2-butene. If a flask initially contains 5.00 atm of each gas,in what direction will the system shift to reach equilibrium?

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Consider the following reaction: NO(g)+ SO3(g)⇌ NO2(g)+ SO2(g) A reaction mixture initially contains 0.86 atm NO and 0.86 atm SO3.Determine the equilibrium pressure of NO2 if Kp for the reaction at this temperature is 0.0118.

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Express the equilibrium constant for the following reaction. N2(g)+ 3 H2(g)⇌ 2 NH3(g)

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At 900.0 K,the equilibrium constant (Kp)for the following reaction is 0.345. 2SO2 + O2(g)⇌ 2SO3(g) At equilibrium,the partial pressure of SO2 is 35.0 atm and that of O2 is 15.9 atm.The partial pressure of SO3 is ________ atm.

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The reaction below has a Kc value of 61.What is the value of Kp for this reaction at 500 K? N2(g)+ 3 H2(g)⇌ 2 NH3(g)

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Consider the following reaction at equilibrium.What effect will adding some C have on the system? CO2(g)+ C(graphite)⇌ 2 CO(g)

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Calculate P [NO]eq,if P [NOCl]eq = 0.33 atm,P [Cl2]eq = 0.50 atm,and Kp = 1.9 × 10-2. 2 NOCl(g)⇌ 2 NO(g)+ Cl2(g)

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Consider the following reaction at equilibrium.What effect will adding a catalyst have on the system? CO2(g)+ 2 H2O(l)⇌ CH4(g)+ 2 O2(g)ΔH° = +890 kJ

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At a certain temperature,Kc equals 1.4 × 102 for the reaction: 2 CO(g)+ O2(g)⇌ 2 CO2(g). If a 3.00-L flask contains 0.400 mol of CO2 and 0.100 mol of O2 at equilibrium,how many moles of CO are also present in the flask?

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Consider the following reaction and its equilibrium constant: SO2(g)+ NO2(g)⇌ SO3(g)+ NO(g)Kc = 0.33 A reaction mixture contains 0.39 M SO2,0.14 M NO2,0.11 M SO3 and 0.14 M NO.Which of the following statements is true concerning this system?

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At a certain temperature,nitrogen and hydrogen react to form ammonia: N2(g)+ 3 H2(g)⇌ 2 NH3(g). When initial amounts of N2,H2,and NH3 are mixed,the concentration of NH3 increases.Which statement below is true?

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What will happen to the following endothermic reaction in equilibrium if the temperature is raised? N2O4(g) ⇌ 2NO2(g)

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Which statement is true for the following reaction at equilibrium at 25 C? N2(g)+ O2 (g)⇌ 2NO(g);K = 4.1 × 10-31

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In which of the following reactions will Kc = Kp?

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Determine the value of Kp for the following reaction if the equilibrium concentrations are as follows: P(CO)eq = 6.8 × 10-11 atm,P(O2)eq = 1.3 × 10-3 atm,P(CO2)eq = 0.041 atm. 2 CO(g)+ O2(g)⇌ 2 CO2(g)

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Consider the following reaction: CH4(g)+ 2 H2S(g)⇌ CS2(g)+ 4 H2(g) A reaction mixture initially contains 0.50 M CH4 and 0.75 M H2S.If the equilibrium concentration of H2 is 0.44 M,find the equilibrium constant (Kc)for the reaction.

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Consider the following reaction at equilibrium.What effect will increasing the volume of the reaction mixture have on the system? 2 H2S(g)+ 3 O2(g)⇌ 2 H2O(g)+ 2 SO2(g)

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What is △n for the following equation in relating Kc to Kp? N2(g)+ 3 H2(g)⇌ 2 NH3(g)

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