Exam 19: Free Energy and Thermodynamics

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________ is a thermodynamic function that increases with the number of energetically equivalent ways to arrange components of a system to achieve a particular state.

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Place the following in order of increasing entropy at 298 K. C2H6(g),Pb(s),Mg(s),CH4(g)

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Consider the following reaction at constant P.Use the information here to determine the value of ΔSsurr at 298 K.Predict whether or not this reaction will be spontaneous at this temperature. N2(g)+ 2 O2(g)→ 2 NO2(g)ΔH = +66.4 kJ

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What is the sign of ΔSuniv for a biological system?

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Estimate ΔG°rxn for the following reaction at 449.0 K. CH2O(g)+ 2 H2(g)→ CH4(g)+ H2O(g)ΔH°= -94.9 kJ; ΔS°= -224.2 J/K

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Above what temperature does the following reaction become nonspontaneous? 2 H2S(g)+ 3 O2(g)→ 2 SO2(g)+ 2 H2O(g)ΔH = -1036 kJ; ΔS = -153.2 J/K

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Which of the following relationships is correct at constant T and P?

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Which of the following reactions will have the largest equilibrium constant (K)at 298 K?

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Determine ΔG°rxn for the following reaction at 338 K. FeO(s)+ CO(g)→ Fe(s)+ CO2(g)ΔH°= -11.0 kJ; ΔS°= -17.4 J/K

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The value of ΔG° at 221.0°C for the formation of calcium chloride from its constituent elements: Ca(s)+ Cl2(g)→ CaCl2(s) Is ________ kJ/mol.At 25.0°C for this reaction,ΔH° is -795.8 kJ/mol,ΔG° is -748.1 kJ/mol,and ΔS° is -159.8 J/K.

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