Exam 19: Free Energy and Thermodynamics
Exam 1: Essentials: Units, Measurements, and Problem Solving101 Questions
Exam 2: Atoms137 Questions
Exam 3: The Quantum Mechanical Model of the Atom141 Questions
Exam 4: Periodic Properties of the Elements144 Questions
Exam 5: Molecules and Compounds202 Questions
Exam 6: Chemical Bonding I138 Questions
Exam 7: Chemical Bonding Ii64 Questions
Exam 8: Chemical Reactions and Chemical Quantities79 Questions
Exam 9: Introduction to Solutions and Aqueous Reactions177 Questions
Exam 10: Thermochemistry145 Questions
Exam 11: Gases185 Questions
Exam 12: Liquids, Solids, and Intermolecular Forces132 Questions
Exam 13: Crystalline Solids and Modern Materials43 Questions
Exam 14: Solutions148 Questions
Exam 15: Chemical Kinetics155 Questions
Exam 16: Chemical Equilibrium141 Questions
Exam 17: Acids and Bases159 Questions
Exam 18: Aqueous Ionic Equilibrium188 Questions
Exam 19: Free Energy and Thermodynamics130 Questions
Exam 20: Electrochemistry148 Questions
Exam 21: Radioactivity and Nuclear Chemistry136 Questions
Exam 22: Organic Chemistry104 Questions
Exam 23: Transition Metals and Coordination Compounds74 Questions
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Consider the following reaction at constant P.Use the information here to determine the value of ΔSsurr at 355 K.Predict whether or not this reaction will be spontaneous at this temperature. 2 NO(g)+ O2(g)→ 2 NO2(g)ΔH = -114 kJ
(Multiple Choice)
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Which of the following reactions will have the smallest equilibrium constant (K)at 298 K?
(Multiple Choice)
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Place the following in order of decreasing standard molar entropy. K Cl(s)Na3PO4(aq)K Cl(aq)
(Multiple Choice)
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Determine ΔG°rxn using the following information. 2 H2S(g)+ 3 O2(g)→ 2 H2O(l)+ 2 SO2(g)ΔH°= +1.12 kJ; ΔS°= -390.7 J/K
(Multiple Choice)
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Phosphorous and chlorine gases combine to produce phosphorous trichloride: P2(g)+ 3Cl2(g)→ 2PCl3(g)
ΔG° at 298 K for this reaction is -642.9 kJ/mol.The value of ΔG at 298 K for a reaction mixture that consists of
and
is
(Multiple Choice)
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Given the following equation, N2O(g)+ NO2(g)→ 3 NO(g)ΔG°rxn = -23.0 kJ
Calculate ΔG°rxn for the following reaction.
3 NO(g)→ N2O(g)+ NO2(g)
(Multiple Choice)
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Consider a reaction that has a negative ΔH and a positive ΔS.Which of the following statements is TRUE?
(Multiple Choice)
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Determine ΔG°rxn for the following reaction at 378 K. CaCO3(s)→ CaO(s)+ CO2(g)ΔH°= +179.2 kJ; DS°= +160.2 J/K
(Multiple Choice)
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Calculate ΔGrxn at 318 K under the conditions shown below for the following reaction. Fe2O3(s)+ 3 CO(g)→ 2 Fe(s)+ 3 CO2(g)ΔG° = -28.0 kJ
P(CO)= 1.4 atm,P(CO2)= 2.1 atm
(Multiple Choice)
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Given the following equation, H2O(g)+ CO(g)→ H2(g)+ CO2(g)ΔG°rxn = -28.6 kJ
Calculate ΔG°rxn for the following reaction.
8 H2(g)+ 8 CO2(g)→ 8 H2O(g)+ 8 CO(g)
(Multiple Choice)
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Determine the equilibrium constant for the following reaction at 549 K. CH2O(g)+ 2 H2(g)→ CH4(g)+ H2O(g)ΔH° = -94.9 kJ; ΔS°= -224.2 J/K
(Multiple Choice)
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For the following example,identify the following. H2O(l)→ H2O(g)
(Multiple Choice)
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Calculate ΔS°rxn for the following reaction.The S° for each species is shown below the reaction. N2H4(l)+ H2(g)→ 2 NH3(g)
S° (J/mol∙K)121.2 130.7 192.8
(Multiple Choice)
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For a given reaction,ΔH = + 29.9 kJ/mol and ΔS = + 57.0 J/Kmol.The reaction is spontaneous ________.Assume that ΔH and ΔS do not vary with temperature.
(Multiple Choice)
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Give the name of the reaction that does not achieve the theoretical limits with respect to free energy in thermodynamics.
(Multiple Choice)
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