Exam 16: Chemical Equilibrium

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The equilibrium constant is given for one of the reactions below.Determine the value of the missing equilibrium constant. H2(g)+ Br2(g)⇌ 2 HBr(g)Kc = 3.8 × 104 2 HBr(g)⇌ H2(g)+ Br2(g)Kc = ?

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What is Δn for the following equation in relating Kc to Kp? 4 NH3(g)+ 3 O2(g)⇌ 2 N2(g)+ 6 H2O(g)

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Explain dynamic equilibrium.Use the generic reaction A(g)⇌ B(g)to explain.

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At 900.0 K,the equilibrium constant (Kp)for the following reaction is 0.345. 2SO2 + O2(g)→ 2SO3(g) At equilibrium,the partial pressure of SO2 is 29.5 atm and that of O2 is 13.4 atm.The partial pressure of SO3 is ________ atm.

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Consider the following reaction,equilibrium concentrations,and equilibrium constant at a particular temperature.Determine the equilibrium concentration of CO2(g). NH2COONH4(s)⇌ 2 NH3(g)+ CO2(g)Kc = 1.58 × 10-8 [NH3]eq = 2.7 × 10-3 M

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Calculate the equilibrium constant for the following reaction given the listed equilibrium concentrations: [H2] = 0.50M,[NO] = 0.75 M,[N2] = 1.2 M [H2O] = 2.0 M 2 NO(g)+ 2 H2(g)⇌ N2(g)+ 2 H2O(g)

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The equilibrium constant is given for one of the reactions below.Determine the value of the missing equilibrium constant. H2(g)+ Br2(g)⇌ 2 HBr(g)Kc = 3.8 × 104 4 HBr(g)⇌ 2 H2(g)+ 2 Br2(g)Kc = ?

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Consider the following reaction: COCl2(g)⇌ CO(g)+ Cl2(g) A reaction mixture initially contains 1.6 M COCl2.Determine the equilibrium concentration of CO if Kc for the reaction at this temperature is 8.33 × 10-4.Calculate this based on the assumption that the answer is negligible compared to 1.6.

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Which of the following statements is TRUE?

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The decomposition of ammonia is: 2 NH3(g)→ N2(g)+ 3 H2(g).If Kp is 1.5 × 103 at 400°C,what is the partial pressure of ammonia at equilibrium when N2 is 0.10 atm and H2 is 0.15 atm?

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Express the equilibrium constant for the following reaction. 6H2(g)+ 6Br2(g)⇌ 12 HBr(g)

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Which of the following statements is TRUE?

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Determine the value of Kc for the following reaction if the equilibrium concentrations are as follows: [HCl]eq = 0.13 M,[HI]eq = 5.6 × 10-16 M,[Cl2]eq = 0.0019 M. 2 HI(g)+ Cl2(g)⇌ 2 HCl(g)+ I2(s)

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The following reaction is exothermic.Which change will shift the equilibrium to the left? 2 SO2(g)+ O2(g)⇌ 2 SO3(g)

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Consider the following reaction: CuS(s)+ O2(g)⇌ Cu(s)+ SO2(g) A reaction mixture initially contains 2.9 M O2.Determine the equilibrium concentration of O2 if Kc for the reaction at this temperature is 1.5.

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Express the equilibrium constant for the following reaction. Li ClO3(s)⇌ Li ClO(s)+ O2(g)

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Phosphorus pentachloride decomposes to phosphorus trichloride at high temperatures according to the equation: PCl5(g)⇌ PCl3(g)+ Cl2(g) At 250° 0.188 M PCl5 is added to the flask.If Kc = 1.80,what are the equilibrium concentrations of each gas?

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For the isomerization reaction: butane ⇌ isobutane Kp equals 25 at 500°C.If the initial pressures of butane and isobutane are 20.atm and 0.0 atm,respectively,what are the pressures of the two gases at equilibrium?

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Cyclohexane (C6H12)undergoes a molecular rearrangement in the presence of AlCl3 to form methylcyclopentane (MCP)according to the equation: C6H12 ⇌ MCP If Kc = 0.143 at 25°C for this reaction,predict the direction in which the system will shift if the initial concentrations of C6H12 and MCP are 0.0400 M and 0.0200 M,respectively.The system

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Consider the following reaction and its equilibrium constant: I2(g)+ Br2(g)⇌ 2 IBr(g)Kc = 1.1 × 102 A reaction mixture contains 0.35 M I2,0.31 M Br2 and 3.5 M IBr.Which of the following statements is TRUE concerning this system?

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