Exam 7: Energy,rate and Equilibrium

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In the potential energy diagram for a chemical reaction,what is the name used for the unstable species corresponding to the top of the energy barrier separating reactants from products?

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Which of the following is always necessary for a chemical reaction to occur between two reactants,A and B?

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Which of the following is FALSE about the energy diagram shown? Which of the following is FALSE about the energy diagram shown?

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What is the name and symbol of the thermodynamic quantity that represents the heat absorbed or liberated in a chemical reaction at constant pressure?

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Lowering the activation energy of a reaction will increase its rate.

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45.Which of the following is a process with a negative ∆S?

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For the reaction shown below,Keq=2×1011.Which of the following statements concerning this system at equilibrium is true? 2CO(g)+ O2(g)⇌ 2CO2(g)

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The reaction A + 2B + C → D + 2E is first order in reactant A,first order in B,and second order in C.What is the rate law equation for this reaction?

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Which statement concerning energy changes in chemical reactions is FALSE?

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The formation of rust (Fe2O3)on an exposed piece of metal typically takes several months.Which of the following statements is NOT a reasonable assumption about this chemical reaction? 4Fe(s)+ 3O2(g)→ 2Fe2O3(s)

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The rate of a chemical reaction increases with an increase in concentration of one or more of the reactants.This is best explained by which of the following statements?

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When a sample of aqueous hydrochloric acid was neutralized with aqueous sodium hydroxide in a calorimeter,the temperature of 100.0 g of water surrounding the reaction increased from 25.0°C to 31.5°C.If the specific heat of water is 1.00 cal/(g•°C),calculate the quantity of energy in calories involved in this neutralization reaction.

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Which of the following pairs of substances has the substance with the highest entropy listed first?

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One effect of a catalyst being added to a reaction mixture is

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A reaction that leads to an increase in the entropy of the system is always spontaneous.

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Removal of a gaseous product from an equilibrium reaction mixture shifts the equilibrium toward formation of more products.

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What instrument is used for measuring the heat energy absorbed or released in a chemical reaction?

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Under normal conditions,which of the following would have the highest entropy?

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10.0 grams of octane are burned in a bomb calorimeter containing 2.00 × 102 g H2O.If the water temperature increases from 25.00oC to 37.00oC,how much energy was released by the system? [SHw = 1.00 cal/(g•°C)]

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Which of the following statements concerning the reversible reaction below is FALSE? N2O4(g)⇌ 2NO2(g)

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