Exam 6: Thermochemistry

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Two aqueous solutions are both at room temperature and are then mixed in a coffee cup calorimeter. The reaction causes the temperature of the resulting solution to fall below room temperature. Which of the following statements is TRUE?

(Multiple Choice)
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Calculate the internal energy change, ΔrU, for the combustion of 29.3 g of vitamin C (C6H8O6, molar mass = 176.124 g mol-1) if the combustion inside a bomb calorimeter, Ccal = 8.31 kJ °C-1, causes a temperature change from 21.5 °C to 68.3 °C.

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How much heat is absorbed/released when 40.00 g of NH3(g) reacts in the presence of excess How much heat is absorbed/released when 40.00 g of NH<sub>3</sub>(g) reacts in the presence of excess   (g) to produce NO(g) and H<sub>2</sub>O(l) according to the following chemical equation?  4NH<sub>3</sub>(g) + 5O<sub>2</sub>(g) → 4NO(g) + 6H<sub>2</sub>O(l)   H° = 1168 kJ (g) to produce NO(g) and H2O(l) according to the following chemical equation? 4NH3(g) + 5O2(g) → 4NO(g) + 6H2O(l) How much heat is absorbed/released when 40.00 g of NH<sub>3</sub>(g) reacts in the presence of excess   (g) to produce NO(g) and H<sub>2</sub>O(l) according to the following chemical equation?  4NH<sub>3</sub>(g) + 5O<sub>2</sub>(g) → 4NO(g) + 6H<sub>2</sub>O(l)   H° = 1168 kJ H° = 1168 kJ

(Multiple Choice)
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Using the following thermochemical equation, determine the amount of heat produced from the combustion of 24.3 g benzene (C6H6). The molar mass of benzene is 78.11 g Using the following thermochemical equation, determine the amount of heat produced from the combustion of 24.3 g benzene (C<sub>6</sub>H<sub>6</sub>). The molar mass of benzene is 78.11 g   . 2C<sub>6</sub>H<sub>6</sub>(l) + 15O<sub>2</sub>(g) → 12CO<sub>2</sub>(g) + 6H<sub>2</sub>O(g)   H°<sub> </sub>= -6278 kJ . 2C6H6(l) + 15O2(g) → 12CO2(g) + 6H2O(g) Using the following thermochemical equation, determine the amount of heat produced from the combustion of 24.3 g benzene (C<sub>6</sub>H<sub>6</sub>). The molar mass of benzene is 78.11 g   . 2C<sub>6</sub>H<sub>6</sub>(l) + 15O<sub>2</sub>(g) → 12CO<sub>2</sub>(g) + 6H<sub>2</sub>O(g)   H°<sub> </sub>= -6278 kJ H° = -6278 kJ

(Multiple Choice)
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Use the Use the   H° and   H°<sub> </sub>information provided to calculate   H° for SO<sub>3</sub>(g):   H°<sub> </sub>(kJ   ) 2SO<sub>2</sub>(g) + O<sub>2</sub>(g) → 2SO<sub>3</sub>(g)   H°<sub> </sub>= -198 kJ SO<sub>2</sub>(g) -297 H° and Use the   H° and   H°<sub> </sub>information provided to calculate   H° for SO<sub>3</sub>(g):   H°<sub> </sub>(kJ   ) 2SO<sub>2</sub>(g) + O<sub>2</sub>(g) → 2SO<sub>3</sub>(g)   H°<sub> </sub>= -198 kJ SO<sub>2</sub>(g) -297 H° information provided to calculate Use the   H° and   H°<sub> </sub>information provided to calculate   H° for SO<sub>3</sub>(g):   H°<sub> </sub>(kJ   ) 2SO<sub>2</sub>(g) + O<sub>2</sub>(g) → 2SO<sub>3</sub>(g)   H°<sub> </sub>= -198 kJ SO<sub>2</sub>(g) -297 H° for SO3(g): Use the   H° and   H°<sub> </sub>information provided to calculate   H° for SO<sub>3</sub>(g):   H°<sub> </sub>(kJ   ) 2SO<sub>2</sub>(g) + O<sub>2</sub>(g) → 2SO<sub>3</sub>(g)   H°<sub> </sub>= -198 kJ SO<sub>2</sub>(g) -297 H° (kJ Use the   H° and   H°<sub> </sub>information provided to calculate   H° for SO<sub>3</sub>(g):   H°<sub> </sub>(kJ   ) 2SO<sub>2</sub>(g) + O<sub>2</sub>(g) → 2SO<sub>3</sub>(g)   H°<sub> </sub>= -198 kJ SO<sub>2</sub>(g) -297 ) 2SO2(g) + O2(g) → 2SO3(g) Use the   H° and   H°<sub> </sub>information provided to calculate   H° for SO<sub>3</sub>(g):   H°<sub> </sub>(kJ   ) 2SO<sub>2</sub>(g) + O<sub>2</sub>(g) → 2SO<sub>3</sub>(g)   H°<sub> </sub>= -198 kJ SO<sub>2</sub>(g) -297 H° = -198 kJ SO2(g) -297

(Multiple Choice)
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Calculate the change in internal energy (ΔU) for a system that is giving off 45.0 kJ of heat and is performing 855 J of work on the surroundings.

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Calculate the amount of heat (in kJ) necessary to raise the temperature of 47.8 g benzene by 57.0 K. The specific heat capacity of benzene is 1.05 J g-1 °C-1.

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Which of the following signs on q and w represent a system that is doing work on the surroundings as well as gaining heat from the surroundings?

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Calculate the amount (mass) of acetaldehyde (C2H4O, molar mass = 44.0526 g mol-1) that causes a bomb calorimeter with a heat capacity of 12.91 kJ °C-1 to have a temperature increase from 27.8 °C to 41.7 °C. The ΔrU for the combustion of acetaldehyde is -1166.9 kJ mol-1.

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9.26 g of an unknown solid is dissolved in a coffee cup calorimeter that contains 62.0 mL of water. The measured temperature increased from 23.4 °C to 24.7 °C. The specific heat of water is 4.184 J g-1 °C-1, and assume the density of the solution is 1.00 g mL-1. Calculate the molecular weight of the unknown solid if the 9.26 g of an unknown solid is dissolved in a coffee cup calorimeter that contains 62.0 mL of water. The measured temperature increased from 23.4 °C to 24.7 °C. The specific heat of water is 4.184 J g<sup>-1</sup> °C<sup>-1</sup>, and assume the density of the solution is 1.00 g mL<sup>-1</sup>. Calculate the molecular weight of the unknown solid if the   H was determined to be -2.51 kJ mol<sup>-1</sup> via another experiment. H was determined to be -2.51 kJ mol-1 via another experiment.

(Multiple Choice)
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The standard state of carbon is ________.

(Short Answer)
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A piece of gold with a mass of 21.0 g was heated to 100.0 °C and placed inside a coffee cup calorimeter. The temperature of the water inside the calorimeter increased from 23.8 °C to 25.5 °C. The specific heat capacity of water is 4.184 J g-1 °C-1 and the specific heat capacity of gold is 0.129 J g-1 °C-1. Calculate the mass of water contained inside the calorimeter.

(Multiple Choice)
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Calculate the mass of sodium cyanate (NaOCN, molar mass = 65.0066 g mol-1) required to lower the temperature from 24.1 °C to 23.0 °C in a coffee cup calorimeter containing 98 mL of water. The enthalpy of solution for NaOCN is 19.20 kJ mol-1. The specific heat of water is 4.184 J g-1 °C-1 and assume the density of the solution is 1.00 g mL-1.

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For For   U to always be -, what must be true? U to always be -, what must be true?

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Identify the unit of heat capacity.

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Match the following. -energy associated with the position of an object

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Use the standard reaction enthalpies given below to determine Use the standard reaction enthalpies given below to determine   H° for the following reaction: 2NO(g) + O<sub>2</sub>(g) → 2NO<sub>2</sub>(g)   H°<sub> </sub>= ? Given: N<sub>2</sub>(g) + O<sub>2</sub>(g) → 2NO(g)   H°<sub> </sub>= +183 kJ 1/2 N<sub>2</sub>(g) + O<sub>2</sub>(g) → NO<sub>2</sub>(g)   H°<sub> </sub>= +33 kJ H° for the following reaction: 2NO(g) + O2(g) → 2NO2(g) Use the standard reaction enthalpies given below to determine   H° for the following reaction: 2NO(g) + O<sub>2</sub>(g) → 2NO<sub>2</sub>(g)   H°<sub> </sub>= ? Given: N<sub>2</sub>(g) + O<sub>2</sub>(g) → 2NO(g)   H°<sub> </sub>= +183 kJ 1/2 N<sub>2</sub>(g) + O<sub>2</sub>(g) → NO<sub>2</sub>(g)   H°<sub> </sub>= +33 kJ H° = ? Given: N2(g) + O2(g) → 2NO(g) Use the standard reaction enthalpies given below to determine   H° for the following reaction: 2NO(g) + O<sub>2</sub>(g) → 2NO<sub>2</sub>(g)   H°<sub> </sub>= ? Given: N<sub>2</sub>(g) + O<sub>2</sub>(g) → 2NO(g)   H°<sub> </sub>= +183 kJ 1/2 N<sub>2</sub>(g) + O<sub>2</sub>(g) → NO<sub>2</sub>(g)   H°<sub> </sub>= +33 kJ H° = +183 kJ 1/2 N2(g) + O2(g) → NO2(g) Use the standard reaction enthalpies given below to determine   H° for the following reaction: 2NO(g) + O<sub>2</sub>(g) → 2NO<sub>2</sub>(g)   H°<sub> </sub>= ? Given: N<sub>2</sub>(g) + O<sub>2</sub>(g) → 2NO(g)   H°<sub> </sub>= +183 kJ 1/2 N<sub>2</sub>(g) + O<sub>2</sub>(g) → NO<sub>2</sub>(g)   H°<sub> </sub>= +33 kJ H° = +33 kJ

(Multiple Choice)
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Use the standard reaction enthalpies given below to determine Use the standard reaction enthalpies given below to determine   H° for the following reaction: P<sub>4</sub>(g) + 10Cl<sub>2</sub>(g) → 4PCl<sub>5</sub>(s)   H°<sub> </sub>= ? Given: PCl<sub>5</sub>(s) → PCl<sub>3</sub>(g) + Cl<sub>2</sub>(g)   H°= +157 kJ P<sub>4</sub>(g) + 6Cl<sub>2</sub>(g) → 4PCl<sub>3</sub>(g)   H° = -1207 kJ H° for the following reaction: P4(g) + 10Cl2(g) → 4PCl5(s) Use the standard reaction enthalpies given below to determine   H° for the following reaction: P<sub>4</sub>(g) + 10Cl<sub>2</sub>(g) → 4PCl<sub>5</sub>(s)   H°<sub> </sub>= ? Given: PCl<sub>5</sub>(s) → PCl<sub>3</sub>(g) + Cl<sub>2</sub>(g)   H°= +157 kJ P<sub>4</sub>(g) + 6Cl<sub>2</sub>(g) → 4PCl<sub>3</sub>(g)   H° = -1207 kJ H° = ? Given: PCl5(s) → PCl3(g) + Cl2(g) Use the standard reaction enthalpies given below to determine   H° for the following reaction: P<sub>4</sub>(g) + 10Cl<sub>2</sub>(g) → 4PCl<sub>5</sub>(s)   H°<sub> </sub>= ? Given: PCl<sub>5</sub>(s) → PCl<sub>3</sub>(g) + Cl<sub>2</sub>(g)   H°= +157 kJ P<sub>4</sub>(g) + 6Cl<sub>2</sub>(g) → 4PCl<sub>3</sub>(g)   H° = -1207 kJ H°= +157 kJ P4(g) + 6Cl2(g) → 4PCl3(g) Use the standard reaction enthalpies given below to determine   H° for the following reaction: P<sub>4</sub>(g) + 10Cl<sub>2</sub>(g) → 4PCl<sub>5</sub>(s)   H°<sub> </sub>= ? Given: PCl<sub>5</sub>(s) → PCl<sub>3</sub>(g) + Cl<sub>2</sub>(g)   H°= +157 kJ P<sub>4</sub>(g) + 6Cl<sub>2</sub>(g) → 4PCl<sub>3</sub>(g)   H° = -1207 kJ H° = -1207 kJ

(Multiple Choice)
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Define molar heat capacity.

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Calculate the amount of heat (in kJ) required to raise the temperature of a 79.0 g sample of ethanol from 298.0 K to 385.0 K. The specific heat capacity of ethanol is 2.42 J g-1 °C-1.

(Multiple Choice)
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