Exam 6: Thermochemistry
Exam 1: Units of Measurement for Physical and Chemical Change192 Questions
Exam 2: Atoms and Elements174 Questions
Exam 3: Molecules, Compounds, and Nomenclature187 Questions
Exam 4: Chemical Reactions and Stoichiometry261 Questions
Exam 5: Gases163 Questions
Exam 6: Thermochemistry161 Questions
Exam 7: The Quantum-Mechanical Model of the Atom170 Questions
Exam 8: Periodic Properties of the Elements144 Questions
Exam 9: Chemical Bonding I: Lewis Theory155 Questions
Exam 10: Chemical Bonding Ii: Molecular Shapes, Valence Bond Theory, and Molecular Orbital Theory180 Questions
Exam 11: Liquids, Solids, and Intermolecular Forces144 Questions
Exam 12: Solutions167 Questions
Exam 13: Chemical Kinetics170 Questions
Exam 14: Chemical Equilibrium150 Questions
Exam 15: Acids and Bases156 Questions
Exam 16: Aqueous Ionic Equilibrium173 Questions
Exam 17: Gibbs Energy and Thermodynamics134 Questions
Exam 18: Electrochemistry122 Questions
Exam 19: Radioactivity and Nuclear Chemistry116 Questions
Exam 20: Organic Chemistry I: Structures109 Questions
Exam 21: Organic Chemistry Ii: Reactions102 Questions
Exam 22: Biochemistry55 Questions
Exam 23: Chemistry of the Nonmetals50 Questions
Exam 24: Metals and Metallurgy49 Questions
Exam 25: Transition Metals and Coordination Compounds55 Questions
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Two aqueous solutions are both at room temperature and are then mixed in a coffee cup calorimeter. The reaction causes the temperature of the resulting solution to fall below room temperature. Which of the following statements is TRUE?
(Multiple Choice)
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Calculate the internal energy change, ΔrU, for the combustion of 29.3 g of vitamin C (C6H8O6, molar mass = 176.124 g mol-1) if the combustion inside a bomb calorimeter, Ccal = 8.31 kJ °C-1, causes a temperature change from 21.5 °C to 68.3 °C.
(Multiple Choice)
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How much heat is absorbed/released when 40.00 g of NH3(g) reacts in the presence of excess
(g) to produce NO(g) and H2O(l) according to the following chemical equation?
4NH3(g) + 5O2(g) → 4NO(g) + 6H2O(l)
H° = 1168 kJ
(Multiple Choice)
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Using the following thermochemical equation, determine the amount of heat produced from the combustion of 24.3 g benzene (C6H6). The molar mass of benzene is 78.11 g
. 2C6H6(l) + 15O2(g) → 12CO2(g) + 6H2O(g)
H° = -6278 kJ
(Multiple Choice)
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Use the
H° and
H° information provided to calculate
H° for SO3(g):
H° (kJ
) 2SO2(g) + O2(g) → 2SO3(g)
H° = -198 kJ SO2(g) -297
(Multiple Choice)
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Calculate the change in internal energy (ΔU) for a system that is giving off 45.0 kJ of heat and is performing 855 J of work on the surroundings.
(Multiple Choice)
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Calculate the amount of heat (in kJ) necessary to raise the temperature of 47.8 g benzene by 57.0 K. The specific heat capacity of benzene is 1.05 J g-1 °C-1.
(Multiple Choice)
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Which of the following signs on q and w represent a system that is doing work on the surroundings as well as gaining heat from the surroundings?
(Multiple Choice)
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Calculate the amount (mass) of acetaldehyde (C2H4O, molar mass = 44.0526 g mol-1) that causes a bomb calorimeter with a heat capacity of 12.91 kJ °C-1 to have a temperature increase from 27.8 °C to 41.7 °C. The ΔrU for the combustion of acetaldehyde is -1166.9 kJ mol-1.
(Multiple Choice)
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9.26 g of an unknown solid is dissolved in a coffee cup calorimeter that contains 62.0 mL of water. The measured temperature increased from 23.4 °C to 24.7 °C. The specific heat of water is 4.184 J g-1 °C-1, and assume the density of the solution is 1.00 g mL-1. Calculate the molecular weight of the unknown solid if the
H was determined to be -2.51 kJ mol-1 via another experiment.
(Multiple Choice)
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A piece of gold with a mass of 21.0 g was heated to 100.0 °C and placed inside a coffee cup calorimeter. The temperature of the water inside the calorimeter increased from 23.8 °C to 25.5 °C. The specific heat capacity of water is 4.184 J g-1 °C-1 and the specific heat capacity of gold is 0.129 J g-1 °C-1. Calculate the mass of water contained inside the calorimeter.
(Multiple Choice)
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Calculate the mass of sodium cyanate (NaOCN, molar mass = 65.0066 g mol-1) required to lower the temperature from 24.1 °C to 23.0 °C in a coffee cup calorimeter containing 98 mL of water. The enthalpy of solution for NaOCN is 19.20 kJ mol-1. The specific heat of water is 4.184 J g-1 °C-1 and assume the density of the solution is 1.00 g mL-1.
(Multiple Choice)
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Match the following.
-energy associated with the position of an object
(Multiple Choice)
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Use the standard reaction enthalpies given below to determine
H° for the following reaction: 2NO(g) + O2(g) → 2NO2(g)
H° = ?
Given:
N2(g) + O2(g) → 2NO(g)
H° = +183 kJ
1/2 N2(g) + O2(g) → NO2(g)
H° = +33 kJ
(Multiple Choice)
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Use the standard reaction enthalpies given below to determine
H° for the following reaction: P4(g) + 10Cl2(g) → 4PCl5(s)
H° = ?
Given:
PCl5(s) → PCl3(g) + Cl2(g)
H°= +157 kJ
P4(g) + 6Cl2(g) → 4PCl3(g)
H° = -1207 kJ
(Multiple Choice)
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Calculate the amount of heat (in kJ) required to raise the temperature of a 79.0 g sample of ethanol from 298.0 K to 385.0 K. The specific heat capacity of ethanol is 2.42 J g-1 °C-1.
(Multiple Choice)
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