Exam 20: The Micromacro Connection

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The root-mean-square speed (thermal speed)of the molecules of a gas is 200 m/s at 23.0°C.At 227°C the root-mean-square speed (thermal speed)of the molecules will be closest to

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Assuming the radius of diatomic molecules is approximately Assuming the radius of diatomic molecules is approximately   for what pressure will the mean free path in room-temperature (20°C)nitrogen be 4.6 m? The Boltzmann constant is 1.38 × 10<sup>-23</sup> J/K,Avogadro's number is 6.02 × 10<sup>23</sup> molecules/mole,and the ideal gas constant is   = 0.0821 L ∙ atm/mol ∙ K. for what pressure will the mean free path in room-temperature (20°C)nitrogen be 4.6 m? The Boltzmann constant is 1.38 × 10-23 J/K,Avogadro's number is 6.02 × 1023 molecules/mole,and the ideal gas constant is Assuming the radius of diatomic molecules is approximately   for what pressure will the mean free path in room-temperature (20°C)nitrogen be 4.6 m? The Boltzmann constant is 1.38 × 10<sup>-23</sup> J/K,Avogadro's number is 6.02 × 10<sup>23</sup> molecules/mole,and the ideal gas constant is   = 0.0821 L ∙ atm/mol ∙ K. = 0.0821 L ∙ atm/mol ∙ K.

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A mole of oxygen (O2)molecules and a mole of carbon dioxide (CO2)molecules at the same temperature and pressure have

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An ice cube at 0°C is placed in a very large bathtub filled with water at 30°C and allowed to melt,causing no appreciable change in the temperature of the bath water.Which one of the following statements is true?

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The mean free path of an oxygen molecule is 2.0 × 10-5 m,when the gas is at a pressure of 120 Pa and a temperature of 275 K.The molecular mass of oxygen is 32.0 g/mol and the Boltzmann constant is 1.38 × 10-23 J/K,Avogadro's number is 6.02 × 1023 molecules/mole,and the ideal gas constant is R = 8.314 J/mol ∙ K = 0.0821 L ∙ atm/mol ∙ K.Assuming that the molecules are moving at their root-mean-square speeds,the average time interval between collisions of an oxygen molecule is closest to

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At 50.0°C,the average translational kinetic energy of a gas molecule is K.If the temperature is now increased to 100.0°C,the average translational kinetic energy of a molecule will be closest to

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What is the mean free path for the molecules in an ideal gas when the pressure is 100 kPa and the temperature is 300 K given that the collision cross-section for the molecules of that gas is 2.0 × 10-20 m2? The Boltzmann constant is 1.38 × 10-23 J/K,Avogadro's number is 6.02 × 1023 molecules/mole,and the ideal gas constant is R = 8.314 J/mol ∙ K = 0.0821 L ∙ atm/mol ∙ K.

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According to the second law of thermodynamics,the entropy of any system always increases.

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An ideal gas is kept in a rigid container that expands negligibly when heated.The gas starts at a temperature of 20.0°C,and heat is added to increase its temperature.At what temperature will its root-mean-square speed (thermal speed)be double its value at 20.0°C?

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A sample of an ideal gas is slowly compressed to one-half its original volume with no change in temperature.What happens to the average speed of the molecules in the sample?

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On a hot summer day,the temperature is 40.0°C and the pressure is 1.01 × 105 Pa.Let us model the air as all nitrogen of molecular mass 28.0 g/mol having molecules of diameter 0.500 nm that are moving at their root-mean-square speed.Avogadro's number is 6.02 × 1023 molecules/mol,the ideal gas constant is 8.31 J/mol ∙ K,and the Boltzmann constant is 1.38 × 10-23 J/K.Calculate reasonable estimates for (a)the root-mean-square speed of the nitrogen molecules. (b)the average distance a typical molecule travels between collisions. (c)the average time a molecule travels between collisions,assuming that the molecules are moving at their root-mean-square speeds. (d)the number of collisions an average molecule undergoes per second.

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If the temperature of a fixed amount of an ideal gas is increased,it NECESSARILY follows that

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A 0.10- A 0.10-   gas tank holds 5.0 moles of nitrogen gas (N<sub>2</sub>),at a temperature of   The atomic mass of nitrogen is 14 g/mol,the molecular radius is 3.0 × 10<sup>-10</sup> m,and the Boltzmann constant is 1.38 × 10<sup>-23</sup> J/K.The root-mean-square speed (thermal speed)of the molecules is closest to gas tank holds 5.0 moles of nitrogen gas (N2),at a temperature of A 0.10-   gas tank holds 5.0 moles of nitrogen gas (N<sub>2</sub>),at a temperature of   The atomic mass of nitrogen is 14 g/mol,the molecular radius is 3.0 × 10<sup>-10</sup> m,and the Boltzmann constant is 1.38 × 10<sup>-23</sup> J/K.The root-mean-square speed (thermal speed)of the molecules is closest to The atomic mass of nitrogen is 14 g/mol,the molecular radius is 3.0 × 10-10 m,and the Boltzmann constant is 1.38 × 10-23 J/K.The root-mean-square speed (thermal speed)of the molecules is closest to

(Multiple Choice)
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What is the average translational kinetic energy per molecule of an ideal gas at a temperature of What is the average translational kinetic energy per molecule of an ideal gas at a temperature of   ? The Boltzmann constant is 1.38 × 10<sup>-23</sup> J/K. ? The Boltzmann constant is 1.38 × 10-23 J/K.

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What is the total translational kinetic energy in a test chamber filled with nitrogen (N2)at What is the total translational kinetic energy in a test chamber filled with nitrogen (N<sub>2</sub>)at   and   The dimensions of the chamber are   The ATOMIC weight of nitrogen is 28.0 g/mol,Avogadro's number is 6.022 × 10<sup>23</sup> molecules/mol and the Boltzmann constant is 1.38 × 10<sup>-23</sup> J/K. and What is the total translational kinetic energy in a test chamber filled with nitrogen (N<sub>2</sub>)at   and   The dimensions of the chamber are   The ATOMIC weight of nitrogen is 28.0 g/mol,Avogadro's number is 6.022 × 10<sup>23</sup> molecules/mol and the Boltzmann constant is 1.38 × 10<sup>-23</sup> J/K. The dimensions of the chamber are What is the total translational kinetic energy in a test chamber filled with nitrogen (N<sub>2</sub>)at   and   The dimensions of the chamber are   The ATOMIC weight of nitrogen is 28.0 g/mol,Avogadro's number is 6.022 × 10<sup>23</sup> molecules/mol and the Boltzmann constant is 1.38 × 10<sup>-23</sup> J/K. The ATOMIC weight of nitrogen is 28.0 g/mol,Avogadro's number is 6.022 × 1023 molecules/mol and the Boltzmann constant is 1.38 × 10-23 J/K.

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What is the root-mean-square value of the following velocity components: 2.0 m/s,-3.0 m/s,and 4.0 m/s?

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A hot piece of iron is thrown into the ocean and its temperature eventually stabilizes.Which of the following statements concerning this process is correct? (There may be more than one correct choice.)

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At what temperature would the root-mean-square speed (thermal speed)of oxygen molecules be 13.0 m/s? Assume that oxygen approximates an ideal gas.The mass of one O2 molecule is 5.312 × 10-26 kg.The Boltzmann constant is 1.38 × 10-23 J/K.

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A 5.0-liter gas tank holds 1.4 moles of helium (He)and 0.70 moles of oxygen (O2),at a temperature of 260 K.The atomic masses of helium and oxygen are 4.0 g/mol and 16.0 g/mol,respectively.Avogadro's number is 6.022 × 1023 molecules/mol and the Boltzmann constant is 1.38 × 10-23 J/K.The total random translational kinetic energy of the gas in the tank is closest to

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The second law of thermodynamics leads us to conclude that

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