Exam 19: Amines

When aniline is treated with molecular bromine in the presence of a mild base (NaHCO₃), polyhalogenation occurs. However, when aniline is treated with molecular bromine in the presence of a strong Lewis Acid like FeBr₃, no reaction takes place. Briefly explain this difference in reactivity.

sec-Butylamine is the common name of what compound?

Which has the higher boiling point, butan-1-ol or 1-butanamine? Explain briefly.

Provide the major organic compound in the following reaction.

Which of the following amines is most basic?

Provide the major organic compound in the following reaction.

Which of the following is a secondary amine?

Provide the structure of the major organic product in the reaction below.

Provide the structure of the major organic product in the reaction below.

A sample of cyclohexylamine is contaminated with considerable hydrocarbon impurity. How might the sample be purified using a technique based on solubility differences?

Complete the following reaction by filling in the necessary reagents.

Provide the systematic name for the compound below. (CH₃)₄N⁺Cl^-

Identify the correct name for the following structure.

In the mass spectrum of compounds with one nitrogen ________.

Draw the structure of N-ethyl-N-methyl-1-hexanamine.

Which compound would react most rapidly with sodium methoxide and heat?

Provide the systematic name for the compound below.

Draw the structure of piperidine.

Provide the structure of the major organic product in the reaction below.

Provide the structure of the major organic product in the reaction below.