Question 1

Provide the structure of o-bromobenzoyl chloride.

Accepted Answer

The answer of Provide the structure of o-bromobenzoyl chloride....

Question 2

Cyclic esters are called ________.

Accepted Answer

A)  lactones 
B)  lactams 
C)  lacrimals 
D)  imides 
E)  enamines 
A)  lactones 
B)  lactams 
C)  lacrimals 
D)  imides 
E)  enamines

Question 3

Complete the following reaction by filling in the necessary starting material.

Accepted Answer

The answer of Complete the following reaction by filling in...

Question 4

Provide the major organic product in the reaction of propanoyl chloride with CH3SH.

Accepted Answer

Question 5

Provide the name of CH3O2CH2CH2CH2CH3.

Accepted Answer

Question 6

Provide the structure of γ-butyrolactam.

Accepted Answer

The answer of Provide the structure of γ-butyrolactam....

Question 7

Provide the name of the compound shown below.

Accepted Answer

N,N-diprop

Question 8

What compound is produced when N,N-dimethylpropanamide is treated with LiAlH4?

Accepted Answer

A)  CH3CH2CONH2 
B)  CH3CH2CH2NH2 
C)  CH3CH2CH2OH 
D)  CH3CH2CH2N(CH3)2 
E)  CH3CH2N(CH3)2 
A)  CH3CH2CONH2 
B)  CH3CH2CH2NH2 
C)  CH3CH2CH2OH 
D)  CH3CH2CH2N(CH3)2 
E)  CH3CH2N(CH3)2

Question 9

What is the predicted major product of the following reaction?

Accepted Answer

A)    
B)    
C)    
D)    
E)    
A)    
B)    
C)    
D)    
E)

Question 10

Name the compound which results when δ-valerolactone is heated in a large excess of methanol in the presence of catalytic acid.

Accepted Answer

methyl 5-h

Question 11

What is the correct IUPAC name for the following compound?

Accepted Answer

A)  N-ethyl-2,N-dimethylbutanamide 
B)  N-ethyl-N-methylisobutyramide 
C)  2,N-dimethyl-N-ethylbutanamide 
D)  1-(ethylmethylamino)-2-methylbutanamide 
A)  N-ethyl-2,N-dimethylbutanamide 
B)  N-ethyl-N-methylisobutyramide 
C)  2,N-dimethyl-N-ethylbutanamide 
D)  1-(ethylmethylamino)-2-methylbutanamide

Question 12

Propose a synthesis of PhNHCHO from benzene.

Accepted Answer

1) HNO₃, H₂S

Question 13

Show how you could perform the following synthesis:

Accepted Answer

1) LiAlH₄ 2

Question 14

The hydrolysis of esters, amides, and nitriles ________.

Accepted Answer

A)  can be carried out under acidic or basic conditions 
B)  must be acid-catalyzed 
C)  must be base-catalyzed 
D)  should be carried out at pH 7.0 for optimum efficiency 
E)  is not pH dependent 
A)  can be carried out under acidic or basic conditions 
B)  must be acid-catalyzed 
C)  must be base-catalyzed 
D)  should be carried out at pH 7.0 for optimum efficiency 
E)  is not pH dependent

Question 15

While the carbonyl stretching frequency for simple aldehydes, ketones, and carboxylic acids is about 1710 cm-1, the carbonyl stretching frequency for acid chlorides is about ________.

Accepted Answer

A)  1700 cm-1 
B)  1735 cm-1 
C)  1800 cm-1 
D)  1660 cm-1 
E)  2200 cm-1 
A)  1700 cm-1 
B)  1735 cm-1 
C)  1800 cm-1 
D)  1660 cm-1 
E)  2200 cm-1

Question 16

Provide the proper IUPAC name for the compound below.

Accepted Answer

isopropyl

Question 17

Predict the major product of the following reaction.

Accepted Answer

The answer of Predict the major product of the following...

Question 18

Propose a synthesis of 2-phenylethylamine from toluene and any other necessary reagents.

Accepted Answer

1) Br₂, hν

Question 19

What are the major organic products when 1 equivalent of acetic formic anhydride reacts with 1 equivalent of methanol?

Accepted Answer

acetic aci

Question 20

While the carbonyl stretching frequency for simple aldehydes, ketones, and carboxylic acids is about 1710 cm-1, the carbonyl stretching frequency for amides is about ________.

Accepted Answer

A)  1700 cm-1 
B)  1735 cm-1 
C)  1800 cm-1 
D)  1660 cm-1 
E)  2200 cm-1 
A)  1700 cm-1 
B)  1735 cm-1 
C)  1800 cm-1 
D)  1660 cm-1 
E)  2200 cm-1

Exam 21: Carboxylic Acid Derivatives

Provide the structure of o-bromobenzoyl chloride.

Cyclic esters are called ________.

Complete the following reaction by filling in the necessary starting material.

Provide the major organic product in the reaction of propanoyl chloride with CH3SH.

Provide the name of CH3O2CH2CH2CH2CH3.

Provide the structure of γ-butyrolactam.

Provide the name of the compound shown below.

What compound is produced when N,N-dimethylpropanamide is treated with LiAlH4?

What is the predicted major product of the following reaction?

Name the compound which results when δ-valerolactone is heated in a large excess of methanol in the presence of catalytic acid.

What is the correct IUPAC name for the following compound?

Propose a synthesis of PhNHCHO from benzene.

Show how you could perform the following synthesis:

The hydrolysis of esters, amides, and nitriles ________.

While the carbonyl stretching frequency for simple aldehydes, ketones, and carboxylic acids is about 1710 cm-1, the carbonyl stretching frequency for acid chlorides is about ________.

Provide the proper IUPAC name for the compound below.

Predict the major product of the following reaction.

Propose a synthesis of 2-phenylethylamine from toluene and any other necessary reagents.

What are the major organic products when 1 equivalent of acetic formic anhydride reacts with 1 equivalent of methanol?

While the carbonyl stretching frequency for simple aldehydes, ketones, and carboxylic acids is about 1710 cm-1, the carbonyl stretching frequency for amides is about ________.

Structure and Bonding

Acids and Bases; Functional Groups

Structure and Stereochemistry of Alkanes

The Study of Chemical Reactions

Stereochemistry

Alkyl Halides; Nucleophilic Substitution

Structure and Synthesis of Alkenes; Elimination

Reactions of Alkenes

Structure and Synthesis of Alcohols

Reactions of Alcohols

Infrared Spectroscopy and Mass Spectrometry

Nuclear Magnetic Resonance Spectroscopy

Ethers, Epoxides, and Thioethers

Conjugated Systems, Orbital Symmetry, and Ultraviolet Spectroscopy

Aromatic Compounds

Reactions of Aromatic Compounds

Ketones and Aldehydes

Amines

Carboxylic Acids

Condensations and Alpha Substitutions of Carboxyl Compounds

Carbohydrates and Nucleic Acids

Amino Acids, Peptides, and Proteins

Lipids

Synthetic Polymers

Filters

Provide the major organic product in the reaction of propanoyl chloride with CH₃SH.

Provide the name of CH₃O₂CH₂CH₂CH₂CH₃.

What compound is produced when N,N-dimethylpropanamide is treated with LiAlH₄?

While the carbonyl stretching frequency for simple aldehydes, ketones, and carboxylic acids is about 1710 cm^-1, the carbonyl stretching frequency for acid chlorides is about ________.

While the carbonyl stretching frequency for simple aldehydes, ketones, and carboxylic acids is about 1710 cm^-1, the carbonyl stretching frequency for amides is about ________.