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Consider the Reaction The Kinetic Parameters Are Given by K10 = 10-9 mol

Question 36

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Consider the reaction
M⇄k1k−1Mads++e−Mads++M⟶k2Mads++Msol++e−\begin{array} { l } M \underset { k _ { - 1 } } { \stackrel { k _ { 1 } } { \rightleftarrows } } M _ { a ds } ^ { + } + e ^ { - } \\M _ { a ds } ^ { + } + M \stackrel { k _ {2 } } { \longrightarrow } M _ { ads} ^ { + } +M _ { sol } ^ { + } + e ^ { - }\end{array}

The kinetic parameters are given by k10 = 10-9 mol cm-2 s-1, b1 = 10 V-1, k-10 = 10-8 mol cm-2 s-1, b-1 = -10 V-1, k20 = 10-8 mol cm-2 s-1, b2 = 10 V-1 and Γ\varGamma = 10-8 mol cm-2.
-To model a system with the above mechanism, the minimum number of dc potentials at which EIS data should be taken to avoid an infinite number of solutions is __________

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