Exam 19: The Second Law of Thermodynamics

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What is the entropy change when 4 kg of water at 0 ∘\circ C is frozen into 4 kg of ice at 0 ∘\circ C?

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What is the maximum possible efficiency of a steam engine operating between a high and low temperature of 550 ∘\circ C and 180 ∘\circ C?

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The change in the entropy of the universe due to an operating Carnot engine

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Three moles of a gas at T = 250 K expand quasi-statically and adiabatically from an initial volume of 30 L to a final volume of 60 L. The change in entropy of the gas during this expansion is (R = 8.314 J/mol·K)

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Of the four steps in the Carnot cycle,

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A car of mass 2000 kg is traveling at 22.0 m/s on a day when the temperature is 20.0ºC. The driver steps on the brakes and stops the car. By how much does the entropy of the universe increase?

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A heat pump with COP = 5 uses electrical energy W to heat a house. How much heat is pumped into the house?

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One mole of an ideal gas undergoes a reversible isothermal expansion from a volume of 1 L to a volume of 2 L. The change in entropy of the gas in terms of the universal gas constant R is

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The construction of a heat engine operating between temperatures T1 and T2, and having an efficiency greater than that of a Carnot engine operating between the same two temperatures, would constitute a violation of

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A container has 0.2 mole of O2 gas and the gas is heated from 0 ∘\circ C to 100 ∘\circ C. What is the change in entropy of the gas? (R = 8.314 J/mol·K)

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A Carnot engine operating between reservoir temperatures of 340º C and 40ºC has an efficiency of

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The Carnot efficiency for a heat engine operating between the temperatures of 227º C and 27ºC is

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What is the maximum possible coefficient of performance of a heat pump that is capable of maintaining the interior of a house at 23ºC when the temperature outside is -30ºC?

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When you make ice cubes, the entropy of the water

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Entropy is related to probability. An isolated system moves toward

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Use the following diagram to answer the next problem.  Use the following diagram to answer the next problem.    An ideal heat engine uses 0.01 mol of gas and operates between a hot reservoir at T<sub>H</sub> = 400 K and cold reservoir at T<sub>L</sub> = 300 K, in a cycle from a \to b \to c \to d \to a. From a \to b the gas undergoes an isothermal expansion, changing its volume from V<sub>a</sub> to 2.5V<sub>a</sub>. From b \to c, the pressure is reduced at a constant volume. From c \to d, the gas undergoes an isothermal compression, and from d \to a, the pressure is increased at a constant volume until the gas is back at the original condition at a. -How much heat is absorbed in going from a \to b? An ideal heat engine uses 0.01 mol of gas and operates between a hot reservoir at TH = 400 K and cold reservoir at TL = 300 K, in a cycle from a →\to b →\to c →\to d →\to a. From a →\to b the gas undergoes an isothermal expansion, changing its volume from Va to 2.5Va. From b →\to c, the pressure is reduced at a constant volume. From c →\to d, the gas undergoes an isothermal compression, and from d →\to a, the pressure is increased at a constant volume until the gas is back at the original condition at a. -How much heat is absorbed in going from a →\to b?

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If a steam engine operates at half of its theoretical maximum efficiency (emax) and does work at a rate of W J/s, calculate how much heat is discharged per second.

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A block of mass m = 0.2 kg slides across a rough horizontal surface with coefficient of kinetic friction μ\mu k = 0.5. What is the change in entropy after the block has moved a distance of 1 m? The temperature of the block and surrounding is 22 ∘\circ C.

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A heat pump needs to supply 20 kW of power to maintain the inside temperature of a house at 25 ∘\circ C while the outside temperature is 0 ∘\circ C. What is the savings in the electric bill per month by using the heat pump instead of direct electrical heating? Assume that the heat pump/direct heating is on for 4 hours per day and 1 kW.hr costs $0.10.

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A steam engine operates between a high and low temperature of 550 ∘\circ C and 180 ∘\circ C. If the steam engine operates at 40% of its theoretical maximum efficiency and does work at a rate of 1000 W, calculate how much heat is discharged per hour.

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