Exam 15: Chemical Equilibrium

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Consider the following reaction: CuS(s)+ O2(g)⇌ Cu(s)+ SO2(g) A reaction mixture initially contains 2.9 M O2.Determine the equilibrium concentration of O2 if Kc for the reaction at this temperature is 1.5.

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In a reaction mixture containing only products,what is the value of Q?

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Consider the following reaction and its equilibrium constant: I2(g)⇌ 2 I(g)Kp = 0.209 A reaction mixture contains 0.72 atm I2 and 1.80 atm I.Which of the following statements is TRUE concerning this system?

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Give the direction of the reaction,if K >> 1.

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Consider the following reaction: CO2(g)+ C(graphite)⇌ 2 CO(g) A reaction mixture initially contains 0.56 atm CO2 and 0.32 atm CO.Determine the equilibrium pressure of CO if Kp for the reaction at this temperature is 2.25.

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Give the direction of the reaction,if K << 1.

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Express the reverse equilibrium constant for the following reaction. 8 H2(g)+ 8 Br2(g)⇌ 16 HBr(g)

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The equilibrium constant is given for two of the reactions below.Determine the value of the missing equilibrium constant. A(g)+ 2 B(g)⇌ AB2(g)Kc = 59 AB2(g)+ B(g)⇌ AB3(g)Kc = ? A(g)+ 3 B(g)⇌ AB3(g)Kc = 478

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What is △n for the following equation in relating Kc to Kp? P4(s)+ 5 O2(g)⇌ P4O10(s)

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The equilibrium constant,Kp,equals 3.40 at 25°C for the isomerization reaction: cis-2-butene ⇌ trans-2-butene. If a flask initially contains 41.00 atm of trans-2-butene and 10.00 atm of cis-2-butene,in what direction will the system shift to reach equilibrium?

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For the reaction: N2(g)+ 2 O2(g)⇌ 2 NO2(g),Kc = 8.3 × 10-10 at 25°C.What is the concentration of N2 gas at equilibrium when the concentration of NO2 is five times the concentration of O2 gas?

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How is the reaction quotient different from an equilibrium constant for a given reaction?

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Consider the following reaction,equilibrium concentrations,and equilibrium constant at a particular temperature.Determine the equilibrium pressure of H2. D2(g)+ H2(g)⇌ 2 HD(g)Kp = 1.80 P(D2)eq = 1.1 × 10-3 atm P(HD)eq = 2.7 × 10-3 atm

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Consider the following reaction: CH4(g)+ 2 H2S(g)⇌ CS2(g)+ 4 H2(g) A reaction mixture initially contains 0.50 M CH4 and 0.75 M H2S.If the equilibrium concentration of H2 is 0.44 M,find the equilibrium constant (Kc)for the reaction.

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Which of the following statements is TRUE?

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Consider the following reaction at equilibrium.What will happen if FeS2 is added to the reaction? 4 FeS2(s)+ 11 O2(g)⇌ 2 Fe2O3(s)+ 8 SO2(g)

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At a certain temperature,bromine and nitric oxide react to form nitrosyl bromide: Br2(g)+ 2 NO (g)⇌ 2 NOBr (g). When initial amounts of Br2,NO ,and NOBr are mixed,the concentration of NOBr increases.Which statement below is TRUE?

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Consider the following reaction,equilibrium concentrations,and equilibrium constant at a particular temperature.Determine the equilibrium pressure of CO. CO(g)+ 2 H2(g)⇌ CH3OH(l)Kp = 2.25 × 104 P(H2)eq = 0.52 atm

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What is Δn for the following equation in relating Kc to Kp? SO3(g)+ NO(g)⇌ SO2(g)+ NO2(g)

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Dinitrogen tetroxide partially decomposes according to the following equilibrium: N2O4(g)⇌ 2 NO2(g) A 1)000-L flask is charged with 3.00 × 10-2 mol of N2O4.At equilibrium,2.36 × 10-2 mol of N2O4 remains.Keq for this reaction is ________.

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