Exam 9: Chemical Bonding I: Lewis Theory

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Identify the compound with the smallest dipole moment in the gas phase.

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Draw the best Lewis structure for the free radical,NO2.What is the formal charge on the N?

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Choose the bond below that is the weakest.

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Choose the best Lewis structure for SO42⁻.

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Which element can expand its valence shell to accommodate more than eight electrons?

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Which compound has the highest carbon-carbon bond strength?

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Use the data given below to construct a Born-Haber cycle to determine the heat of formation of KCl. DH°(kJ) K(s)→ K(g)89 K(g)→ K⁺(g)+ e⁻ 418 Cl2(g)→ 2 Cl(g)244 Cl(g)+ e⁻ → Cl⁻(g)-349 KCl(s)→ K⁺(g)+ Cl⁻(g)717

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Choose the best Lewis structure for NO3⁻.

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Identify an ionic bond.

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Identify the number of bonding pairs and lone pairs of electrons in H2O2.

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Draw the Lewis structure for the acetate ion,CH3CO2⁻,including any important resonance structures.Label each atom with its formal charge.

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Choose the best Lewis structure for NH4⁺.

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Identify the ionic compound that is used as an image enhancer in x-rays.

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Use the data given below to construct a Born-Haber cycle to determine the lattice energy of CaO. DH°(kJ) Ca(s)→ Ca(g)193 Ca(g)→ Ca⁺(g)+ e⁻ 590 Ca⁺(g)→ Ca2⁺(g)+ e⁻ 1010 2 O(g)→ O2(g)-498 O(g)+ e⁻ → O⁻(g)-141 O⁻(g)+ e⁻ → O2⁻(g)878 Ca(s)+ Use the data given below to construct a Born-Haber cycle to determine the lattice energy of CaO. DH°(kJ) Ca(s)→ Ca(g)193 Ca(g)→ Ca⁺(g)+ e⁻ 590 Ca⁺(g)→ Ca<sup>2</sup>⁺(g)+ e⁻ 1010 2 O(g)→ O<sub>2</sub>(g)-498 O(g)+ e⁻ → O⁻(g)-141 O⁻(g)+ e⁻ → O<sup>2</sup>⁻(g)878 Ca(s)+   O<sub>2</sub>(g)→ CaO(s)-635 O2(g)→ CaO(s)-635

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Use the data given below to construct a Born-Haber cycle to determine the second ionization energy of Ca. DH°(kJ) Ca(s)→ Ca(g)193 Ca(g)→ Ca⁺(g)+ e⁻ 590. 2 O(g)→ O2(g)-498 O(g)+ e⁻ → O⁻(g)-141 O⁻(g)+ e⁻ → O2⁻(g)878 Ca(s)+ Use the data given below to construct a Born-Haber cycle to determine the second ionization energy of Ca. DH°(kJ) Ca(s)→ Ca(g)193 Ca(g)→ Ca⁺(g)+ e⁻ 590. 2 O(g)→ O<sub>2</sub>(g)-498 O(g)+ e⁻ → O⁻(g)-141 O⁻(g)+ e⁻ → O<sup>2</sup>⁻(g)878 Ca(s)+   O<sub>2</sub>(g)→ CaO(s)-635 Ca<sup>2</sup>⁺(g)+ O<sup>2</sup>⁻(g)→ CaO(s)-3414 O2(g)→ CaO(s)-635 Ca2⁺(g)+ O2⁻(g)→ CaO(s)-3414

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Identify the compound with covalent bonding.

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Which of the following represents the Lewis structure for Br⁻?

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Use Lewis theory to determine the chemical formula for the compound formed between Al and F.

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Use Lewis theory to determine the chemical formula for the compound formed between Al and O.

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Draw the Lewis structure for BrO3-.Make sure to include any important resonance structures.

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