Exam 18: Electrochemistry

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Calculate the cell potential for the following reaction that takes place in an electrochemical cell at 25 °C: \quad\quad\quad Mg(s)| Mg2+(aq,2.74 mol L-1) ∥\| Cu2+(aq,0.0033 mol L-1)| Cu(s) E°(Mg2+/Mg)= -2.37 V and E°(Cu2+/Cu)= +0.34 V

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Determine which of the following pairs of reactants will result in a spontaneous reaction at 25 °C.

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Which of the following is the strongest reducing agent?

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What is undergoing reduction in the redox reaction represented by the following cell notation? \quad\quad\quad Pb(s)| Pb2+(aq) ∥\| H+(aq)| H2(g)| Pt(s)

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Why are iron nails coated with zinc?

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Use the provided reduction potentials to calculate ΔrG° for the following balanced redox reaction: \quad\quad Pb2+(aq)+ Cu(s)→ Pb(s)+ Cu2+(aq) E°(Pb2+/Pb)= -0.13 V and E°(Cu2+/Cu)= +0.34 V

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Identify the battery that is used as a common flashlight battery.

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What is the balanced chemical equation for the galvanic cell reaction expressed using shorthand notation below? \quad\quad\quad Al(s)| Al3+(aq)|| Fe2+(aq)| Fe(s)

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What is the reducing agent in the redox reaction represented by the following cell notation? \quad\quad\quad Ni(s)| Ni2+(aq) ∥\| Ag+(aq)| Ag(s)

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A galvanic cell consists of one half-cell that contains Ag(s)and Ag+(aq),and one half-cell that contains Cu(s)and Cu2+(aq).What species are produced at the electrodes under standard conditions? \quad\quad Ag+(aq)+ e- → Ag(s)E° = +0.80 V \quad\quad Cu2+(aq)+ 2 e- → Cu(s)E° = +0.34 V

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Which of the following is the strongest oxidizing agent?

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Which of the following is the strongest oxidizing agent?

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Which of the following is TRUE about standard electrode potentials?

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Predict the species that will be oxidized first if a mixture of molten salts containing the following ions undergoes electrolysis: \quad\quad\quad Cu2+,Mg2+,Cl-,Br-,F-

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Consider the galvanic cell, Zn(s)∣Zn2+(aq)∣∣Pb2+(aq)∣Pb(s)\mathrm { Zn } ( s ) \left| \mathrm { Zn } ^ { 2 } + ( a q ) \right| | \mathrm { Pb } 2 + ( a q ) | \mathrm { Pb } ( \mathrm { s } ) Which one of the following changes to the cell would cause the cell potential to increase (i.e.,become more positive)?

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How long must a constant current of 50.0 A be passed through an electrolytic cell containing aqueous Cu2+ ions to produce 5.00 moles of copper metal?

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Calculate the cell potential for the following unbalanced reaction that takes place in an electrochemical cell at 25 °C when [ Mg2+\mathrm { Mg } ^ { 2 + } ] = 3.20 M and [ Fe3+\mathrm { Fe } ^ { 3 + } ] = 0.000100 M \quad\quad\quad Mg(s)+ Fe3+\mathrm { Fe } ^ { 3 + } (aq)? Mg2+\mathrm { Mg } ^ { 2 + } (aq)+ Fe(s) E°(Mg2+/Mg)= -2.37 V and E°(Fe3+/Fe)= -0.036 V

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Determine the cell notation for the redox reaction given below: \quad\quad\quad 3Cl2(g)+ 2Fe(s)? 6Cl- (aq)+ 2Fe3+(aq)

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Nickel can be plated from aqueous solution according to the following half-reaction.How long would it take (in min)to plate 29.6 g of nickel at 4.7 A? \quad\quad Ni2+(aq)+ 2 e - → Ni(s)

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Given that E°red = -1.66 V for Al3+/Al at 25 °C,find E° and E for the concentration cell expressed using shorthand notation below: \quad\quad Al(s)| Al3+(1.0 × 10-5 mol L-1)|| Al3+(0.100 mol L-1)| Al(s)

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