Exam 15: Chemical Equilibrium

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Consider the following chemical reaction: CO (g)+ 2H2(g) Consider the following chemical reaction: CO (g)+ 2H<sub>2</sub>(g)   CH<sub>3</sub>OH(g) At equilibrium in a particular experiment,the concentrations of CO and H<sub>2</sub> were   and   respectively.What is the equilibrium concentration of CH<sub>3</sub>OH? The value of K<sub>eq</sub> for this reaction is 14.5 at the temperature of the experiment. CH3OH(g) At equilibrium in a particular experiment,the concentrations of CO and H2 were Consider the following chemical reaction: CO (g)+ 2H<sub>2</sub>(g)   CH<sub>3</sub>OH(g) At equilibrium in a particular experiment,the concentrations of CO and H<sub>2</sub> were   and   respectively.What is the equilibrium concentration of CH<sub>3</sub>OH? The value of K<sub>eq</sub> for this reaction is 14.5 at the temperature of the experiment. and Consider the following chemical reaction: CO (g)+ 2H<sub>2</sub>(g)   CH<sub>3</sub>OH(g) At equilibrium in a particular experiment,the concentrations of CO and H<sub>2</sub> were   and   respectively.What is the equilibrium concentration of CH<sub>3</sub>OH? The value of K<sub>eq</sub> for this reaction is 14.5 at the temperature of the experiment. respectively.What is the equilibrium concentration of CH3OH? The value of Keq for this reaction is 14.5 at the temperature of the experiment.

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Which of the following expressions is the correct equilibrium-constant expression for the reaction below? 2SO2 (g)+ O2 (g) Which of the following expressions is the correct equilibrium-constant expression for the reaction below? 2SO<sub>2</sub> (g)+ O<sub>2</sub> (g)   2SO<sub>3</sub> (g) 2SO3 (g)

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Consider the following reaction at equilibrium: 2N Consider the following reaction at equilibrium: 2N   (g)     (g)+ 3   (g)ΔH° = +92.4 kJ Le Châtelier's principle predicts that removing   to the system at equilibrium will result in ________. (g) Consider the following reaction at equilibrium: 2N   (g)     (g)+ 3   (g)ΔH° = +92.4 kJ Le Châtelier's principle predicts that removing   to the system at equilibrium will result in ________. Consider the following reaction at equilibrium: 2N   (g)     (g)+ 3   (g)ΔH° = +92.4 kJ Le Châtelier's principle predicts that removing   to the system at equilibrium will result in ________. (g)+ 3 Consider the following reaction at equilibrium: 2N   (g)     (g)+ 3   (g)ΔH° = +92.4 kJ Le Châtelier's principle predicts that removing   to the system at equilibrium will result in ________. (g)ΔH° = +92.4 kJ Le Châtelier's principle predicts that removing Consider the following reaction at equilibrium: 2N   (g)     (g)+ 3   (g)ΔH° = +92.4 kJ Le Châtelier's principle predicts that removing   to the system at equilibrium will result in ________. to the system at equilibrium will result in ________.

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The Keq for the equilibrium below is 7.16 × 10-2 at 440.0 °C. 2Cl2 (g)+ 2H2O (g) The K<sub>eq</sub> for the equilibrium below is 7.16 × 10<sup>-2</sup> at 440.0 °C. 2Cl<sub>2</sub> (g)+ 2H<sub>2</sub>O (g)   4HCl (g)+ O<sub>2</sub> (g) What is the value of K<sub>eq</sub> at this temperature for the following reaction? Cl<sub>2</sub> (g)+ H<sub>2</sub>O (g)   2HCl (g)+   O<sub>2</sub> (g) 4HCl (g)+ O2 (g) What is the value of Keq at this temperature for the following reaction? Cl2 (g)+ H2O (g) The K<sub>eq</sub> for the equilibrium below is 7.16 × 10<sup>-2</sup> at 440.0 °C. 2Cl<sub>2</sub> (g)+ 2H<sub>2</sub>O (g)   4HCl (g)+ O<sub>2</sub> (g) What is the value of K<sub>eq</sub> at this temperature for the following reaction? Cl<sub>2</sub> (g)+ H<sub>2</sub>O (g)   2HCl (g)+   O<sub>2</sub> (g) 2HCl (g)+ The K<sub>eq</sub> for the equilibrium below is 7.16 × 10<sup>-2</sup> at 440.0 °C. 2Cl<sub>2</sub> (g)+ 2H<sub>2</sub>O (g)   4HCl (g)+ O<sub>2</sub> (g) What is the value of K<sub>eq</sub> at this temperature for the following reaction? Cl<sub>2</sub> (g)+ H<sub>2</sub>O (g)   2HCl (g)+   O<sub>2</sub> (g) O2 (g)

(Multiple Choice)
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Which of the following expressions is the correct equilibrium-constant expression for the reaction below? CO2 (s)+ H2O (l) Which of the following expressions is the correct equilibrium-constant expression for the reaction below? CO<sub>2</sub> (s)+ H<sub>2</sub>O (l)   H<sup>+</sup> (aq)+ HCO<sub>3</sub><sup>-</sup> (aq) H+ (aq)+ HCO3- (aq)

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Which of the following expressions is the correct equilibrium-constant expression for the following reaction? CO2 (g)+ 2H2 (g) Which of the following expressions is the correct equilibrium-constant expression for the following reaction? CO<sub>2</sub> (g)+ 2H<sub>2</sub> (g)   CH<sub>3</sub>OH (g) CH3OH (g)

(Multiple Choice)
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Given the following reaction at equilibrium,if Kc = 5.84 x 105 at 230.0 °C,Kp = ________. 2NO (g)+ O2 (g) Given the following reaction at equilibrium,if K<sub>c</sub> = 5.84 x 10<sup>5 </sup>at 230.0 °C,K<sub>p</sub> = ________. 2NO (g)+ O<sub>2</sub> (g)     (g) Given the following reaction at equilibrium,if K<sub>c</sub> = 5.84 x 10<sup>5 </sup>at 230.0 °C,K<sub>p</sub> = ________. 2NO (g)+ O<sub>2</sub> (g)     (g) (g)

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The Keq for the equilibrium below is 0.112 at 700.0 °C. SO2 (g)+ The K<sub>eq</sub> for the equilibrium below is 0.112 at 700.0 °C. SO<sub>2</sub> (g)+   O<sub>2</sub> (g)   SO<sub>3</sub> (g) What is the value of K<sub>eq</sub> at this temperature for the following reaction? 2SO<sub>2</sub> (g)+ O<sub>2</sub> (g)   2SO<sub>3</sub> (g) O2 (g) The K<sub>eq</sub> for the equilibrium below is 0.112 at 700.0 °C. SO<sub>2</sub> (g)+   O<sub>2</sub> (g)   SO<sub>3</sub> (g) What is the value of K<sub>eq</sub> at this temperature for the following reaction? 2SO<sub>2</sub> (g)+ O<sub>2</sub> (g)   2SO<sub>3</sub> (g) SO3 (g) What is the value of Keq at this temperature for the following reaction? 2SO2 (g)+ O2 (g) The K<sub>eq</sub> for the equilibrium below is 0.112 at 700.0 °C. SO<sub>2</sub> (g)+   O<sub>2</sub> (g)   SO<sub>3</sub> (g) What is the value of K<sub>eq</sub> at this temperature for the following reaction? 2SO<sub>2</sub> (g)+ O<sub>2</sub> (g)   2SO<sub>3</sub> (g) 2SO3 (g)

(Multiple Choice)
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At 1000.0 K,the equilibrium constant for the reaction 2NO (g)+ Br2 (g) At 1000.0 K,the equilibrium constant for the reaction 2NO (g)+ Br<sub>2</sub> (g)   2NOBr (g) Is K<sub>p</sub> = 0.016.Calculate K<sub>p</sub> for the reverse reaction, 2NOBr (g)   2NO (g)+ Br<sub>2 </sub>(g). 2NOBr (g) Is Kp = 0.016.Calculate Kp for the reverse reaction, 2NOBr (g) At 1000.0 K,the equilibrium constant for the reaction 2NO (g)+ Br<sub>2</sub> (g)   2NOBr (g) Is K<sub>p</sub> = 0.016.Calculate K<sub>p</sub> for the reverse reaction, 2NOBr (g)   2NO (g)+ Br<sub>2 </sub>(g). 2NO (g)+ Br2 (g).

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Given the following reaction at equilibrium,if Kp = 1.10 at 250.0 °C,Kc = ________. PCl5 (g) Given the following reaction at equilibrium,if K<sub>p</sub> = 1.10 at 250.0 °C,K<sub>c</sub> = ________. PCl<sub>5</sub> (g)   PCl<sub>3</sub> (g)+ Cl<sub>2</sub> (g) PCl3 (g)+ Cl2 (g)

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Which one of the following will change the value of an equilibrium constant?

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The equilibrium expression for Kp for the reaction below is ________. 2O3 (g) The equilibrium expression for K<sub>p</sub> for the reaction below is ________. 2O<sub>3 </sub>(g)   3O<sub>2 </sub>(g) 3O2 (g)

(Multiple Choice)
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Exactly 1.75 moles of N2O4 is placed in an empty 1.0-L container.After a period of time,equilibrium is reached and described by the equation below: N2O4 (g)⇌ 2NO2 (g) If at equilibrium the N2O4 is 25% dissociated,what is the value of the equilibrium constant for the reaction?

(Short Answer)
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Acetic acid is a weak acid that dissociates into the acetate ion and a proton in aqueous solution: HC2H3O2 (aq) Acetic acid is a weak acid that dissociates into the acetate ion and a proton in aqueous solution: HC<sub>2</sub>H<sub>3</sub>O<sub>2</sub> (aq)   C<sub>2</sub>H<sub>3</sub>O<sub>2</sub><sup>-</sup> (aq)+ H<sup>+</sup> (aq) At equilibrium at 25 °C a 0.100 M solution of acetic acid has the following concentrations:     and   The equilibrium constant,K<sub>eq</sub>,for the ionization of acetic acid at   is ________. C2H3O2- (aq)+ H+ (aq) At equilibrium at 25 °C a 0.100 M solution of acetic acid has the following concentrations: Acetic acid is a weak acid that dissociates into the acetate ion and a proton in aqueous solution: HC<sub>2</sub>H<sub>3</sub>O<sub>2</sub> (aq)   C<sub>2</sub>H<sub>3</sub>O<sub>2</sub><sup>-</sup> (aq)+ H<sup>+</sup> (aq) At equilibrium at 25 °C a 0.100 M solution of acetic acid has the following concentrations:     and   The equilibrium constant,K<sub>eq</sub>,for the ionization of acetic acid at   is ________. Acetic acid is a weak acid that dissociates into the acetate ion and a proton in aqueous solution: HC<sub>2</sub>H<sub>3</sub>O<sub>2</sub> (aq)   C<sub>2</sub>H<sub>3</sub>O<sub>2</sub><sup>-</sup> (aq)+ H<sup>+</sup> (aq) At equilibrium at 25 °C a 0.100 M solution of acetic acid has the following concentrations:     and   The equilibrium constant,K<sub>eq</sub>,for the ionization of acetic acid at   is ________. and Acetic acid is a weak acid that dissociates into the acetate ion and a proton in aqueous solution: HC<sub>2</sub>H<sub>3</sub>O<sub>2</sub> (aq)   C<sub>2</sub>H<sub>3</sub>O<sub>2</sub><sup>-</sup> (aq)+ H<sup>+</sup> (aq) At equilibrium at 25 °C a 0.100 M solution of acetic acid has the following concentrations:     and   The equilibrium constant,K<sub>eq</sub>,for the ionization of acetic acid at   is ________. The equilibrium constant,Keq,for the ionization of acetic acid at Acetic acid is a weak acid that dissociates into the acetate ion and a proton in aqueous solution: HC<sub>2</sub>H<sub>3</sub>O<sub>2</sub> (aq)   C<sub>2</sub>H<sub>3</sub>O<sub>2</sub><sup>-</sup> (aq)+ H<sup>+</sup> (aq) At equilibrium at 25 °C a 0.100 M solution of acetic acid has the following concentrations:     and   The equilibrium constant,K<sub>eq</sub>,for the ionization of acetic acid at   is ________. is ________.

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A reaction vessel is charged with hydrogen iodide,which partially decomposes to molecular hydrogen and iodine: 2HI (g) A reaction vessel is charged with hydrogen iodide,which partially decomposes to molecular hydrogen and iodine: 2HI (g)   H<sub>2</sub>(g)+ I<sub>2</sub>(g) When the system comes to equilibrium at 425 °C,P<sub>HI</sub> = 0.708 atm,and   =     The value of K<sub>p</sub> at this temperature is ________. H2(g)+ I2(g) When the system comes to equilibrium at 425 °C,PHI = 0.708 atm,and A reaction vessel is charged with hydrogen iodide,which partially decomposes to molecular hydrogen and iodine: 2HI (g)   H<sub>2</sub>(g)+ I<sub>2</sub>(g) When the system comes to equilibrium at 425 °C,P<sub>HI</sub> = 0.708 atm,and   =     The value of K<sub>p</sub> at this temperature is ________. = A reaction vessel is charged with hydrogen iodide,which partially decomposes to molecular hydrogen and iodine: 2HI (g)   H<sub>2</sub>(g)+ I<sub>2</sub>(g) When the system comes to equilibrium at 425 °C,P<sub>HI</sub> = 0.708 atm,and   =     The value of K<sub>p</sub> at this temperature is ________. A reaction vessel is charged with hydrogen iodide,which partially decomposes to molecular hydrogen and iodine: 2HI (g)   H<sub>2</sub>(g)+ I<sub>2</sub>(g) When the system comes to equilibrium at 425 °C,P<sub>HI</sub> = 0.708 atm,and   =     The value of K<sub>p</sub> at this temperature is ________. The value of Kp at this temperature is ________.

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The relationship between the concentrations of reactants and products of a system at equilibrium is given by the law of energy.

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The value of Keq for the following reaction is 0.50: A (g)+ 2B (g) The value of K<sub>eq</sub> for the following reaction is 0.50: A (g)+ 2B (g)   C (g)+ 4D (g) The value of K<sub>eq</sub> at the same temperature for the reaction below is ________. 1/2A (g)+ B (g)   1/2C (g)+ 2D (g) C (g)+ 4D (g) The value of Keq at the same temperature for the reaction below is ________. 1/2A (g)+ B (g) The value of K<sub>eq</sub> for the following reaction is 0.50: A (g)+ 2B (g)   C (g)+ 4D (g) The value of K<sub>eq</sub> at the same temperature for the reaction below is ________. 1/2A (g)+ B (g)   1/2C (g)+ 2D (g) 1/2C (g)+ 2D (g)

(Multiple Choice)
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The Keq for the equilibrium below is 7.52 × 10-2 at 480.0 °C. 2Cl2 (g)+ 2H2O (g) The K<sub>eq</sub> for the equilibrium below is 7.52 × 10<sup>-2</sup> at 480.0 °C. 2Cl<sub>2</sub> (g)+ 2H<sub>2</sub>O (g)   4HCl (g)+ O<sub>2</sub> (g) What is the value of K<sub>eq</sub> at this temperature for the following reaction? 2HCl (g)+   O<sub>2</sub> (g)   Cl<sub>2</sub> (g)+ H<sub>2</sub>O (g) 4HCl (g)+ O2 (g) What is the value of Keq at this temperature for the following reaction? 2HCl (g)+ The K<sub>eq</sub> for the equilibrium below is 7.52 × 10<sup>-2</sup> at 480.0 °C. 2Cl<sub>2</sub> (g)+ 2H<sub>2</sub>O (g)   4HCl (g)+ O<sub>2</sub> (g) What is the value of K<sub>eq</sub> at this temperature for the following reaction? 2HCl (g)+   O<sub>2</sub> (g)   Cl<sub>2</sub> (g)+ H<sub>2</sub>O (g) O2 (g) The K<sub>eq</sub> for the equilibrium below is 7.52 × 10<sup>-2</sup> at 480.0 °C. 2Cl<sub>2</sub> (g)+ 2H<sub>2</sub>O (g)   4HCl (g)+ O<sub>2</sub> (g) What is the value of K<sub>eq</sub> at this temperature for the following reaction? 2HCl (g)+   O<sub>2</sub> (g)   Cl<sub>2</sub> (g)+ H<sub>2</sub>O (g) Cl2 (g)+ H2O (g)

(Multiple Choice)
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Which of the following expressions is the correct equilibrium-constant expression for the reaction below? (NH4)2Se (s) Which of the following expressions is the correct equilibrium-constant expression for the reaction below? (NH<sub>4</sub>)<sub>2</sub>Se (s)   2NH<sub>3</sub> (g)+ H<sub>2</sub>Se (g) 2NH3 (g)+ H2Se (g)

(Multiple Choice)
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The value of Keq for the following reaction is 0.26: A (g)+ B (g) The value of K<sub>eq</sub> for the following reaction is 0.26: A (g)+ B (g)   C (g)+ D (g) The value of K<sub>eq</sub> at the same temperature for the reaction below is ________. 2A (g)+ 2B (g)   2C (g)+ 2D (g) C (g)+ D (g) The value of Keq at the same temperature for the reaction below is ________. 2A (g)+ 2B (g) The value of K<sub>eq</sub> for the following reaction is 0.26: A (g)+ B (g)   C (g)+ D (g) The value of K<sub>eq</sub> at the same temperature for the reaction below is ________. 2A (g)+ 2B (g)   2C (g)+ 2D (g) 2C (g)+ 2D (g)

(Multiple Choice)
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