Exam 14: Chemical Kinetics

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At elevated temperatures,nitrogen dioxide decomposes to nitrogen oxide and oxygen: NO2 (g)→ NO (g)+ At elevated temperatures,nitrogen dioxide decomposes to nitrogen oxide and oxygen: NO<sub>2 </sub>(g)→ NO (g)+   O<sub>2 </sub>(g) The reaction is second order in NO<sub>2</sub> with a rate constant of 0.543 M<sup>-1</sup>s<sup>-1</sup>at   If the initial [NO<sub>2</sub>] is   it will take ________ s for the concentration to drop to  O2 (g) The reaction is second order in NO2 with a rate constant of 0.543 M-1s-1at At elevated temperatures,nitrogen dioxide decomposes to nitrogen oxide and oxygen: NO<sub>2 </sub>(g)→ NO (g)+   O<sub>2 </sub>(g) The reaction is second order in NO<sub>2</sub> with a rate constant of 0.543 M<sup>-1</sup>s<sup>-1</sup>at   If the initial [NO<sub>2</sub>] is   it will take ________ s for the concentration to drop to  If the initial [NO2] is At elevated temperatures,nitrogen dioxide decomposes to nitrogen oxide and oxygen: NO<sub>2 </sub>(g)→ NO (g)+   O<sub>2 </sub>(g) The reaction is second order in NO<sub>2</sub> with a rate constant of 0.543 M<sup>-1</sup>s<sup>-1</sup>at   If the initial [NO<sub>2</sub>] is   it will take ________ s for the concentration to drop to  it will take ________ s for the concentration to drop to At elevated temperatures,nitrogen dioxide decomposes to nitrogen oxide and oxygen: NO<sub>2 </sub>(g)→ NO (g)+   O<sub>2 </sub>(g) The reaction is second order in NO<sub>2</sub> with a rate constant of 0.543 M<sup>-1</sup>s<sup>-1</sup>at   If the initial [NO<sub>2</sub>] is   it will take ________ s for the concentration to drop to

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What is the concentration (M)of [A] after 80.0 s?

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The graph shown below depicts the relationship between concentration and time for the following chemical reaction. The graph shown below depicts the relationship between concentration and time for the following chemical reaction.   The slope of this line is equal to ________. The slope of this line is equal to ________.

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The overall reaction order is the sum of the orders of each reactant in the rate law.

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The rate of disappearance of HBr in the gas phase reaction 2HBr (g)→ H2 (g)+ Br2 (g) Is 0.140 M The rate of disappearance of HBr in the gas phase reaction 2HBr (g)→ H<sub>2</sub> (g)+ Br<sub>2</sub> (g) Is 0.140 M   at 150 °C.The rate of reaction is ________ M   . at 150 °C.The rate of reaction is ________ M The rate of disappearance of HBr in the gas phase reaction 2HBr (g)→ H<sub>2</sub> (g)+ Br<sub>2</sub> (g) Is 0.140 M   at 150 °C.The rate of reaction is ________ M   . .

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________ are used in automotive catalytic converters.

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The instantaneous rate of a reaction can be read directly from the graph of molarity versus time at any point on the graph.

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The combustion of ethylene proceeds by the reaction C2H4 (g)+ 3O2 (g)→ 2CO2 (g)+ 2H2O (g) When the rate of disappearance of O2 is 0.13 M The combustion of ethylene proceeds by the reaction C<sub>2</sub>H<sub>4</sub> (g)+ 3O<sub>2</sub> (g)→ 2CO<sub>2</sub> (g)+ 2H<sub>2</sub>O (g) When the rate of disappearance of O<sub>2</sub> is 0.13 M   ,the rate of disappearance of C<sub>2</sub>H<sub>4</sub> is ________  ,the rate of disappearance of C2H4 is ________ The combustion of ethylene proceeds by the reaction C<sub>2</sub>H<sub>4</sub> (g)+ 3O<sub>2</sub> (g)→ 2CO<sub>2</sub> (g)+ 2H<sub>2</sub>O (g) When the rate of disappearance of O<sub>2</sub> is 0.13 M   ,the rate of disappearance of C<sub>2</sub>H<sub>4</sub> is ________

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In general,as activation energy increases,reaction rate ________.

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At elevated temperatures,methylisonitrile (CH3NC)isomerizes to acetonitrile (CH3CN): CH3NC (g)→ CH3CN (g) At the start of an experiment,there are 0.200 mol of reactant and 0 mol of product in the reaction vessel.After 25 min,0.121 mol of reactant (CH3NC)remain.There are ________ mol of product (CH3CN)in the reaction vessel.

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What is the magnitude of the rate constant for the reaction?

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The reaction A → B is first order in [A].Consider the following data. The reaction A → B is first order in [A].Consider the following data.   The rate constant for this reaction is ________   . The rate constant for this reaction is ________ The reaction A → B is first order in [A].Consider the following data.   The rate constant for this reaction is ________   . .

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As the temperature of a reaction is increased,the rate of the reaction increases because the ________.

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The reaction 2NOBr (g)→ 2 NO (g)+ Br2 (g) Is a second-order reaction with a rate constant of 0.80 M-1s-1 at 11 °C.If the initial concentration of NOBr is 0.0440 M,the concentration of NOBr after 6.0 seconds is ________.

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What is the order of the reaction with respect to OH-?

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The half-life for a first order rate law depends on the starting concentration.

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At elevated temperatures,methylisonitrile (CH3NC)isomerizes to acetonitrile (CH3CN): CH3NC (g)→ CH3CN (g) The reaction is first order in methylisonitrile.The attached graph shows data for the reaction obtained at 198.9 °C. At elevated temperatures,methylisonitrile (CH<sub>3</sub>NC)isomerizes to acetonitrile (CH<sub>3</sub>CN): CH<sub>3</sub>NC (g)→ CH<sub>3</sub>CN (g) The reaction is first order in methylisonitrile.The attached graph shows data for the reaction obtained at 198.9 °C.   What is the rate constant (s<sup>-1</sup>)for the reaction? What is the rate constant (s-1)for the reaction?

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It was determined experimentally that the reaction rate doubled when the concentration of B was doubled in the following reaction: A + B → C The reaction is ________ order in B.

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Which energy difference in the energy profile below corresponds to the activation energy for the forward reaction? Which energy difference in the energy profile below corresponds to the activation energy for the forward reaction?

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The overall reaction below is ________ and the elementary reaction is considered ________. AB → A + B

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