Exam 2: Molecules

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Estimate the CO bond length in acetone, CH3COCH3.Given: covalent radii (pm)OfC-,77; C=,67; O-,74;O=,60; H,37.

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Use the bond enthalpies given to estimate the heat released when ethene, CH2=CH2,Reacts with HBr to give CH3CH2Br. Bond enthalpies (kJ.mol-1 ): C-H,412; C-C,348; C=C,612; C-Br,276; Br-Br,193; H-Br,366.

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In NO, the unpaired electron occupies what type of molecular orbital?

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What is the shape of AlH4-?

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If the following all crystallize in the same type of structure, which has the lowest lattice energy?

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The bond order of N22+ is

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What is the bond order in the OH radical?

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All the following are paramagnetic except

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Draw the Lewis structure of xenon difluoride and give the number of lone pairs electrons around the central atom.

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Write all possible Lewis structures of sulfur dioxide. Which structure is most feasible?

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White phosphorus is composed of tetrahedral molecules of P4 in which each P atom is bonded to three others.In this molecule the formal charge on each P atom is ___.

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All of the following are polar except

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Use the expression for the Coulomb potential energy to calculate the energy for formation of 1 mole of sodium chloride ion-pairs,that is, the energy change for the following reaction: Na+(g)+Cl-(g) →\rightarrow Na+Cl-(g) Use r12 = 283 pm.

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Which of the following has bond angles of 180 ∘\circ ?

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The best Lewis structures of SO2 and O3 include expanded valence structures such as O=S=O and O=O=O.

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An element, E,Has the electronic configuration [Ne] 3s23p1.Write the formula of its compound with sulfate.

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What is the formal charge of S in the molecule H2SO4?

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Use the bond enthalpies given to estimate the heat released when 2-methyl-1-propene, (CH3)2C=CH2, Reacts with HBr to give (CH3)2CBrCH3.Bond enthalpies ( kJ.mol-1 ):C-H,412; C-C,348;C=C,612; C-Br,276; H-Br,366.

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If dinitrogen oxide has a dipole moment, what is the arrangement of atoms?

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Which of the following has bond angles slightly less than 109 ∘\circ ?

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