Exam 17: Solubility and Complex-Ion Equilibria

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Suppose 50.00 mL of 2.0 × 10-6 M Fe(NO3)3 is added to 50.00 mL of 2.0 ×10-4 M KIO3.Which of the following statements is true? For Fe(IO3)3,Ksp = 1.0 × 10-14.

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The best explanation for the dissolution of ZnS in dilute HCl is that

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The solubility of La(IO3)3 in a 0.71 M KIO3 solution is 1.0 ×10-7 mol/L.Calculate Ksp for La(IO3)3.

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You have two salts,AgX and AgY,with very similar Ksp values.You know that Ka for HX is much greater than Ka for HY.Which statement will be true?

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In which of the following solutions would silver(I)phosphate,Ag3PO4,be least soluble?

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Which of the following salts has the lowest molar solubility?

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Given the following equilibrium constants, ​ Zn(IO3)2 Ksp = Given the following equilibrium constants, ​ Zn(IO<sub>3</sub>)<sub>2</sub> K<sub>sp</sub> =   Zn(NH<sub>3</sub>)<sub>4</sub><sup>2+ </sup>K<sub>f </sub> =   ​ Determine K<sub>c</sub> for the dissolution of the sparingly soluble salt Zn(IO<sub>3</sub>)<sub>2</sub> in aqueous ammonia (shown below). Zn(IO<sub>3</sub>)<sub>2</sub>(s)+ 4NH<sub>3</sub>(aq)  Zn(NH<sub>3</sub>)<sub>4</sub><sup>2+</sup>(aq)+ 2IO<sub>3</sub><sup>-</sup>(aq) Zn(NH3)42+ Kf = Given the following equilibrium constants, ​ Zn(IO<sub>3</sub>)<sub>2</sub> K<sub>sp</sub> =   Zn(NH<sub>3</sub>)<sub>4</sub><sup>2+ </sup>K<sub>f </sub> =   ​ Determine K<sub>c</sub> for the dissolution of the sparingly soluble salt Zn(IO<sub>3</sub>)<sub>2</sub> in aqueous ammonia (shown below). Zn(IO<sub>3</sub>)<sub>2</sub>(s)+ 4NH<sub>3</sub>(aq)  Zn(NH<sub>3</sub>)<sub>4</sub><sup>2+</sup>(aq)+ 2IO<sub>3</sub><sup>-</sup>(aq) ​ Determine Kc for the dissolution of the sparingly soluble salt Zn(IO3)2 in aqueous ammonia (shown below). Zn(IO3)2(s)+ 4NH3(aq) Given the following equilibrium constants, ​ Zn(IO<sub>3</sub>)<sub>2</sub> K<sub>sp</sub> =   Zn(NH<sub>3</sub>)<sub>4</sub><sup>2+ </sup>K<sub>f </sub> =   ​ Determine K<sub>c</sub> for the dissolution of the sparingly soluble salt Zn(IO<sub>3</sub>)<sub>2</sub> in aqueous ammonia (shown below). Zn(IO<sub>3</sub>)<sub>2</sub>(s)+ 4NH<sub>3</sub>(aq)  Zn(NH<sub>3</sub>)<sub>4</sub><sup>2+</sup>(aq)+ 2IO<sub>3</sub><sup>-</sup>(aq)Zn(NH3)42+(aq)+ 2IO3-(aq)

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How many moles of CaF2 will dissolve in 3.0 L of 0.041 M NaF solution? (Ksp for CaF2 = 4.0 × 10-11)

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What is the hydroxide-ion concentration of a saturated solution of Ni(OH)2? For Ni(OH)2,Ksp = 2.0 × 10-15.

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If 430 mL of 1 × 10-4 M Ca(NO3)2 is mixed with 430 mL of 1 × 10-4 M NaF,what will occur? For CaF2,Ksp = 3.4 × 10-11.

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What is the solubility product expression for Zn3(PO4)2?

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In which of the following solutions would CaC2O4 have the highest molar solubility?

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What is the solubility product expression for La2(CO3)3?

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An aqueous solution of Ag(CN)2− is made by combining 0.0100 moles AgNO3 with 1.00 mole NaCN and diluting to 1.000 L.What is the molar concentration of Ag+ in the solution? Ag+(aq)+ 2CN-(aq) An aqueous solution of Ag(CN)<sub>2</sub>− is made by combining 0.0100 moles AgNO<sub>3</sub> with 1.00 mole NaCN and diluting to 1.000 L.What is the molar concentration of Ag<sup>+</sup> in the solution? Ag<sup>+</sup>(aq)+ 2CN<sup>-</sup>(aq)  Ag(CN)<sub>2</sub><sup>-</sup>(aq); K<sub>f</sub> = 5.6 × 10<sup>18</sup>Ag(CN)2-(aq); Kf = 5.6 × 1018

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What is the maximum Sr2+ concentration possible in a solution that has a What is the maximum Sr<sup>2+</sup> concentration possible in a solution that has a   M sulfide-ion concentration without precipitating strontium sulfate? For SrSO<sub>4</sub>,K<sub>sp</sub> = 2.5 × 10<sup>-7</sup>. M sulfide-ion concentration without precipitating strontium sulfate? For SrSO4,Ksp = 2.5 × 10-7.

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