Exam 17: Solubility and Complex-Ion Equilibria

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In the sulfide scheme for qualitative analysis,the cations of Analytical Group IV are precipitated as phosphates or carbonates.Analytical Group IV consists of

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The figure below represents the results of adding NH3 to a saturated solution of an ionic compound.Which of the following could the ionic compound be? The figure below represents the results of adding NH<sub>3</sub> to a saturated solution of an ionic compound.Which of the following could the ionic compound be?

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The insoluble salts AV,B2W,C2X3,DY2,and EZ3,which were formed from the metal ions A+,B+,C3+,D2+,and E3+ and the nonmetals V1-,W2-,X2-,Y1-,and Z1-,all have the same Ksp value.Which salt has the highest molar solubility?

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Suppose 50.00 mL of a 1 × 10-7 M solution of lead(II)nitrate is mixed with 50.00 mL of a 1 × 10-8 solution of sodium phosphate.Which of the following statements is true? For lead(II)phosphate,Ksp = 1 × 10-44.

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If 275 mL of 1 × 10-7 M AgNO3 is mixed with 275 mL of 1 × 10-8 M NaI,what will occur? For AgI,Ksp = 8.3 × 10-17.

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What is the maximum hydroxide-ion concentration that a 0.025 M MgCl2 solution could have without causing the precipitation of Mg(OH)2? For Mg(OH)2,Ksp = 1.8 × 10-11.

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Sodium chloride is added slowly to a solution that is 0.010 M in Cu+,Ag+,and Au+.The Ksp values for the chloride salts are 1.9 × 10-7,1.6 × 10-10,and 2.0 × 10-13,respectively.Which compound will precipitate first?

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Which Figures I-IV represent(s)the result of mixing aqueous solutions of NaOH and CuCl2 in which the ion product Qc > Ksp for the insoluble product? (C = cation,A = anion) Which Figures I-IV represent(s)the result of mixing aqueous solutions of NaOH and CuCl<sub>2</sub> in which the ion product Q<sub>c</sub> > K<sub>sp</sub> for the insoluble product? (C = cation,A = anion)

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What is the relationship between molar solubility (s)and Ksp for calcium fluoride?

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What is the pH of a saturated solution of Zn(OH)2? For Zn(OH)2,Ksp = 2.1 × 10-16.

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What will happen if 0.1 mol of solid silver(I)nitrate is added to 1.0 L of a saturated solution of silver(I)chromate? For Ag2CrO4,Ksp = 2.4 × 10-12.

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Cyanide ion forms very stable complex ions with a variety of metal ions.What is the molar equilibrium concentration of uncomplexed Ni2+(aq)in a solution that initially contains 1.3 mol of Ni(CN)42− per liter of solution .Kf for Ni(CN)42− is Cyanide ion forms very stable complex ions with a variety of metal ions.What is the molar equilibrium concentration of uncomplexed Ni<sup>2+</sup>(aq)in a solution that initially contains 1.3 mol of Ni(CN)<sub>4</sub><sup>2</sup>− per liter of solution .K<sub>f</sub> for Ni(CN)<sub>4</sub><sup>2</sup>− is   . .

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_____ involves the determination of the identity of the substances present in a mixture.

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What is the solubility (in g/L)of calcium fluoride at 25°C? The solubility product constant for calcium fluoride is 3.4 × 10-11 at 25°C.

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For which of the following will precipitation be expected?

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Rank the following metal sulfides in order of increasing molar solubility in water. Salt Ksp CoS 4 × 10-21 CuS 6 × 10-36 FeS 6 × 10-18 HgS 1)6 × 10-52 MnS 2)5 × 10-10

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The silver-ion concentration in a saturated solution of silver(I)sulfate is 2.9 × 10-2 M.What is Ksp for silver(I)sulfate?

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What is the best way to ensure complete precipitation of SnS from a saturated H2S solution?

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Calculate the molar concentration of uncomplexed Zn2+(aq)in a solution that contains 0.21 mol of Zn(NH3)42+ per liter and 0.4986 M NH3 at equilibrium.Kf for Zn(NH3)42+ is Calculate the molar concentration of uncomplexed Zn<sup>2+</sup>(aq)in a solution that contains 0.21 mol of Zn(NH<sub>3</sub>)<sub>4</sub><sup>2+</sup> per liter and 0.4986 M NH<sub>3</sub> at equilibrium.K<sub>f</sub> for Zn(NH<sub>3</sub>)<sub>4</sub><sup>2+</sup> is   . .

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Which of the following particulate views is/are consistent with a heterogeneous equilibrium? Which of the following particulate views is/are consistent with a heterogeneous equilibrium?       I II III Which of the following particulate views is/are consistent with a heterogeneous equilibrium?       I II III Which of the following particulate views is/are consistent with a heterogeneous equilibrium?       I II III I II III

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