Exam 14: Chemical Equilibrium
Exam 1: Chemistry and Measurement111 Questions
Exam 2: Atoms, molecules, and Ions149 Questions
Exam 3: Calculations With Chemical Formulas and Equations139 Questions
Exam 4: Chemical Reactions159 Questions
Exam 5: The Gaseous State104 Questions
Exam 6: Thermochemistry119 Questions
Exam 7: Quantum Theory of the Atom68 Questions
Exam 8: Electron Configurations and Periodicity100 Questions
Exam 9: Ionic and Covalent Bonding125 Questions
Exam 10: Molecular Geometry and Chemical Bonding Theory101 Questions
Exam 11: States of Matter; Liquids and Solids123 Questions
Exam 12: Solutions119 Questions
Exam 13: Rates of Reaction113 Questions
Exam 14: Chemical Equilibrium97 Questions
Exam 15: Acids and Bases83 Questions
Exam 16: Acid-Base Equilibria148 Questions
Exam 17: Solubility and Complex-Ion Equilibria115 Questions
Exam 18: Thermodynamics and Equilibrium94 Questions
Exam 19: Electrochemistry122 Questions
Exam 20: Nuclear Chemistry90 Questions
Exam 21: Chemistry of the Main-Group Metals121 Questions
Exam 22: The Transition Elements and Coordination Compounds75 Questions
Exam 23: Organic Chemistry79 Questions
Exam 24: Polymer Materials: Synthetic and Biological56 Questions
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The Ostwald process converts ammonia (NH3)to nitric oxide (NO)by reaction with oxygen in the presence of a catalyst at high temperatures.In a test of the process a reaction vessel is initially charged with 4.80 mol NH3(g)and 5.80 mol O2(g),sealed,and heated at a fixed high temperature.When equilibrium is established the reaction mixture is analyzed and found to contain 3.80 mol NO(g).What is the quantity of NH3(g)in the equilibrium reaction mixture?
4NH3(g)+ 5O2(g)
4NO(g)+ 6H2O(g)
(Multiple Choice)
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Nitrogen trifluoride decomposes to form nitrogen and fluorine gases according to the following equation:
2NF3(g)
N2(g)+ 3F2(g)
When 2.54 mol of NF3 is placed in a 6.00-L container and allowed to come to equilibrium at 800 K,the mixture is found to contain 0.0434 mol of N2.What is the value of Kp at this temperature? (R = 0.0821 L · atm · mol-1 · K-1)
(Multiple Choice)
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Consider the following equilibrium:
C2H6(g)+ C5H12(g)
CH4(g)+ C6H14(g); Kp = 9.57 at 500 K
Suppose 11.6 g each of CH4,C2H6,C5H12,and C6H14 are placed in a 30.0-L reaction vessel at 500 K.Which of the following statements is correct?
(Multiple Choice)
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Hydrogen iodide undergoes decomposition according to the equation
2HI(g)
H2(g)+ I2(g)
The equilibrium constant Kc at 425°C for this system is 0.018.If 1.0 mol each of H2,I2,and HI were placed together in a 1-L container at 425°C,then
(Multiple Choice)
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What effect will spraying liquid water into the equilibrium given below have if NH3 is far more soluble in water than is N2 or H2?
N2(g)+ 3H2(g)
2NH3(g)
(Multiple Choice)
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In an experiment,0.30 mol H2 and 0.30 mol I2 are mixed in a 1.00-L container,and the reaction forms HI.If Kc = 49.for this reaction,what is the equilibrium concentration of HI?
I2(g)+ H2(g)
2HI(g)
(Multiple Choice)
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When the pressure of an equilibrium mixture of SO2,O2,and SO3 is halved at constant temperature,what is the effect on Kp?
2SO2(g)+ O2(g)
2SO3(g)
(Multiple Choice)
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Consider the following equilibrium:
NH4Cl(s)
NH3(g)+ HCl(g)
Suppose a vessel containing NH4Cl(s),NH3(g)and HCl(g)is at equilibrium.If the volume of the vessel is instantaneously doubled while keeping the temperature constant,when a new equilibrium is reached,which of the following statements is incorrect?
(Multiple Choice)
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What is the Kc expression for the following equilibrium?
CuBr(s)
Cu+(aq)+ Br-(aq)
(Multiple Choice)
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Consider the following equilibrium:
O2(g)+ 2F2(g)
2OF2(g); Kp = 2.3 × 10-15
Which of the following statements is true?
(Multiple Choice)
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A 2.50-mol sample of HI is placed in a 1.00-L vessel at 460°C,and the reaction system is allowed to come to equilibrium.The HI partially decomposes,forming 0.190 mol H2 and 0.190 mol I2 at equilibrium.What is the equilibrium constant Kc for the following reaction at 460°C?
1/2 H2(g)+ 1/2 I2(g)
HI(g)
(Multiple Choice)
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For which of the following systems at equilibrium and at constant temperature will increasing the volume have no effect on the equilibrium?
(Multiple Choice)
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The following equilibrium is exothermic.How could the yield of diiodine pentoxide be increased?
I2(g)+ 5CO2(g)
5CO(g)+ I2O5(g)
(Multiple Choice)
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At 550 K,Kp = 7.7 × 102 for the following equilibrium.
SO2(g)+ NO2(g)
SO3(g)+ NO(g)
If 0.279 mol each of SO3 and NO are placed in a 4.00-L container at 550 K,what is the concentration of SO3 at equilibrium? (R = 0.0821 L · atm/(K · mol))
(Multiple Choice)
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For which of the following reactions will the reactant experience the largest degree of decomposition upon reaching equilibrium at 500 K?
(Multiple Choice)
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If Kc = 0.133 for A2 + 2B
2AB,what is the value of Kc for the reaction
4AB
2A2 + 4B?
(Multiple Choice)
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The _____ is a relation that states that the values of the equilibrium-constant expression Kc are constant for a particular reaction at a given temperature,whatever equilibrium concentrations are substituted.
(Multiple Choice)
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