Exam 14: Chemical Equilibrium

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The Ostwald process converts ammonia (NH3)to nitric oxide (NO)by reaction with oxygen in the presence of a catalyst at high temperatures.In a test of the process a reaction vessel is initially charged with 4.80 mol NH3(g)and 5.80 mol O2(g),sealed,and heated at a fixed high temperature.When equilibrium is established the reaction mixture is analyzed and found to contain 3.80 mol NO(g).What is the quantity of NH3(g)in the equilibrium reaction mixture? 4NH3(g)+ 5O2(g) The Ostwald process converts ammonia (NH<sub>3</sub>)to nitric oxide (NO)by reaction with oxygen in the presence of a catalyst at high temperatures.In a test of the process a reaction vessel is initially charged with 4.80 mol NH<sub>3</sub>(g)and 5.80 mol O<sub>2</sub>(g),sealed,and heated at a fixed high temperature.When equilibrium is established the reaction mixture is analyzed and found to contain 3.80 mol NO(g).What is the quantity of NH<sub>3</sub>(g)in the equilibrium reaction mixture? 4NH<sub>3</sub>(g)+ 5O<sub>2</sub>(g)   4NO(g)+ 6H<sub>2</sub>O(g) 4NO(g)+ 6H2O(g)

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Nitrogen trifluoride decomposes to form nitrogen and fluorine gases according to the following equation: 2NF3(g) Nitrogen trifluoride decomposes to form nitrogen and fluorine gases according to the following equation: 2NF<sub>3</sub>(g)   N<sub>2</sub>(g)+ 3F<sub>2</sub>(g) When 2.54 mol of NF<sub>3</sub> is placed in a 6.00-L container and allowed to come to equilibrium at 800 K,the mixture is found to contain 0.0434 mol of N<sub>2</sub>.What is the value of K<sub>p</sub> at this temperature? (R = 0.0821 L · atm · mol<sup>-1</sup> · K<sup>-1</sup>) N2(g)+ 3F2(g) When 2.54 mol of NF3 is placed in a 6.00-L container and allowed to come to equilibrium at 800 K,the mixture is found to contain 0.0434 mol of N2.What is the value of Kp at this temperature? (R = 0.0821 L · atm · mol-1 · K-1)

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Consider the following equilibrium: C2H6(g)+ C5H12(g) Consider the following equilibrium: C<sub>2</sub>H<sub>6</sub>(g)+ C<sub>5</sub>H<sub>12</sub>(g)   CH<sub>4</sub>(g)+ C<sub>6</sub>H<sub>14</sub>(g); K<sub>p</sub> = 9.57 at 500 K Suppose 11.6 g each of CH<sub>4</sub>,C<sub>2</sub>H<sub>6</sub>,C<sub>5</sub>H<sub>12</sub>,and C<sub>6</sub>H<sub>14</sub> are placed in a 30.0-L reaction vessel at 500 K.Which of the following statements is correct? CH4(g)+ C6H14(g); Kp = 9.57 at 500 K Suppose 11.6 g each of CH4,C2H6,C5H12,and C6H14 are placed in a 30.0-L reaction vessel at 500 K.Which of the following statements is correct?

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Hydrogen iodide undergoes decomposition according to the equation 2HI(g) Hydrogen iodide undergoes decomposition according to the equation 2HI(g)   H<sub>2</sub>(g)+ I<sub>2</sub>(g) The equilibrium constant K<sub>c</sub> at 425°C for this system is 0.018.If 1.0 mol each of H<sub>2</sub>,I<sub>2</sub>,and HI were placed together in a 1-L container at 425°C,then H2(g)+ I2(g) The equilibrium constant Kc at 425°C for this system is 0.018.If 1.0 mol each of H2,I2,and HI were placed together in a 1-L container at 425°C,then

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What effect will spraying liquid water into the equilibrium given below have if NH3 is far more soluble in water than is N2 or H2? N2(g)+ 3H2(g) What effect will spraying liquid water into the equilibrium given below have if NH<sub>3</sub> is far more soluble in water than is N<sub>2</sub> or H<sub>2</sub>? N<sub>2</sub>(g)+ 3H<sub>2</sub>(g)   2NH<sub>3</sub>(g) 2NH3(g)

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In an experiment,0.30 mol H2 and 0.30 mol I2 are mixed in a 1.00-L container,and the reaction forms HI.If Kc = 49.for this reaction,what is the equilibrium concentration of HI? I2(g)+ H2(g) In an experiment,0.30 mol H<sub>2</sub> and 0.30 mol I<sub>2</sub> are mixed in a 1.00-L container,and the reaction forms HI.If K<sub>c</sub> = 49.for this reaction,what is the equilibrium concentration of HI? I<sub>2</sub>(g)+ H<sub>2</sub>(g)   2HI(g) 2HI(g)

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When the pressure of an equilibrium mixture of SO2,O2,and SO3 is halved at constant temperature,what is the effect on Kp? 2SO2(g)+ O2(g) When the pressure of an equilibrium mixture of SO<sub>2</sub>,O<sub>2</sub>,and SO<sub>3</sub> is halved at constant temperature,what is the effect on K<sub>p</sub>? 2SO<sub>2</sub>(g)+ O<sub>2</sub>(g)   2SO<sub>3</sub>(g) 2SO3(g)

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Consider the following equilibrium: NH4Cl(s) Consider the following equilibrium: NH<sub>4</sub>Cl(s)   NH<sub>3</sub>(g)+ HCl(g) Suppose a vessel containing NH<sub>4</sub>Cl(s),NH<sub>3</sub>(g)and HCl(g)is at equilibrium.If the volume of the vessel is instantaneously doubled while keeping the temperature constant,when a new equilibrium is reached,which of the following statements is incorrect? NH3(g)+ HCl(g) Suppose a vessel containing NH4Cl(s),NH3(g)and HCl(g)is at equilibrium.If the volume of the vessel is instantaneously doubled while keeping the temperature constant,when a new equilibrium is reached,which of the following statements is incorrect?

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What is the Kc expression for the following equilibrium? CuBr(s) What is the K<sub>c</sub> expression for the following equilibrium? CuBr(s)   Cu<sup>+</sup>(aq)+ Br<sup>-</sup>(aq) Cu+(aq)+ Br-(aq)

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Consider the following equilibrium: O2(g)+ 2F2(g) Consider the following equilibrium: O<sub>2</sub>(g)+ 2F<sub>2</sub>(g)   2OF<sub>2</sub>(g); K<sub>p</sub> = 2.3 × 10<sup>-15</sup> Which of the following statements is true? 2OF2(g); Kp = 2.3 × 10-15 Which of the following statements is true?

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A 2.50-mol sample of HI is placed in a 1.00-L vessel at 460°C,and the reaction system is allowed to come to equilibrium.The HI partially decomposes,forming 0.190 mol H2 and 0.190 mol I2 at equilibrium.What is the equilibrium constant Kc for the following reaction at 460°C? 1/2 H2(g)+ 1/2 I2(g) A 2.50-mol sample of HI is placed in a 1.00-L vessel at 460°C,and the reaction system is allowed to come to equilibrium.The HI partially decomposes,forming 0.190 mol H<sub>2</sub> and 0.190 mol I<sub>2</sub> at equilibrium.What is the equilibrium constant K<sub>c</sub> for the following reaction at 460°C? 1/2 H<sub>2</sub>(g)+ 1/2 I<sub>2</sub>(g)   HI(g) HI(g)

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For which of the following systems at equilibrium and at constant temperature will increasing the volume have no effect on the equilibrium?

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The following equilibrium is exothermic.How could the yield of diiodine pentoxide be increased? I2(g)+ 5CO2(g) The following equilibrium is exothermic.How could the yield of diiodine pentoxide be increased? I<sub>2</sub>(g)+ 5CO<sub>2</sub>(g)   5CO(g)+ I<sub>2</sub>O<sub>5</sub>(g) 5CO(g)+ I2O5(g)

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At 550 K,Kp = 7.7 × 102 for the following equilibrium. SO2(g)+ NO2(g) At 550 K,K<sub>p</sub> = 7.7 × 10<sup>2</sup> for the following equilibrium. SO<sub>2</sub>(g)+ NO<sub>2</sub>(g)   SO<sub>3</sub>(g)+ NO(g) If 0.279 mol each of SO<sub>3</sub> and NO are placed in a 4.00-L container at 550 K,what is the concentration of SO<sub>3</sub> at equilibrium? (R = 0.0821 L · atm/(K · mol)) SO3(g)+ NO(g) If 0.279 mol each of SO3 and NO are placed in a 4.00-L container at 550 K,what is the concentration of SO3 at equilibrium? (R = 0.0821 L · atm/(K · mol))

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For which of the following reactions will the reactant experience the largest degree of decomposition upon reaching equilibrium at 500 K?

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If Kc = 0.133 for A2 + 2B If K<sub>c</sub> = 0.133 for A<sub>2</sub> + 2B   2AB,what is the value of K<sub>c</sub> for the reaction 4AB   2A<sub>2</sub> + 4B? 2AB,what is the value of Kc for the reaction 4AB If K<sub>c</sub> = 0.133 for A<sub>2</sub> + 2B   2AB,what is the value of K<sub>c</sub> for the reaction 4AB   2A<sub>2</sub> + 4B? 2A2 + 4B?

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The _____ is a relation that states that the values of the equilibrium-constant expression Kc are constant for a particular reaction at a given temperature,whatever equilibrium concentrations are substituted.

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