Exam 14: Chemical Equilibrium

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The _____ is an economical process for making nitric acid in which nitric oxide is prepared by the oxidation of ammonia.

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For the equilibrium PCl5(g) For the equilibrium PCl<sub>5</sub>(g)   PCl<sub>3</sub>(g)+ Cl<sub>2</sub>(g),K<sub>c</sub> = 2.0 × 10<sup>1</sup> at 240°C.If pure PCl<sub>5</sub> is placed in a 1.00-L container and allowed to come to equilibrium,and the equilibrium concentration of PCl<sub>3</sub>(g)is 0.27 M,what is the equilibrium concentration of PCl<sub>5</sub>(g)? PCl3(g)+ Cl2(g),Kc = 2.0 × 101 at 240°C.If pure PCl5 is placed in a 1.00-L container and allowed to come to equilibrium,and the equilibrium concentration of PCl3(g)is 0.27 M,what is the equilibrium concentration of PCl5(g)?

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When cobalt chloride is added to pure water,the Co2+ ions hydrate.The hydrated form then reacts with the Cl- ions to set up the equilibrium shown here: Co(H2O)62+ + 4Cl- When cobalt chloride is added to pure water,the Co<sup>2+</sup> ions hydrate.The hydrated form then reacts with the Cl<sup>-</sup> ions to set up the equilibrium shown here: Co(H<sub>2</sub>O)<sub>6</sub><sup>2+</sup> + 4Cl<sup>-</sup>   CoCl<sub>4</sub><sup>2-</sup> + 6H<sub>2</sub>O (pink) (blue) Which statement accurately describes the change that the system will undergo if water is added? CoCl42- + 6H2O (pink) (blue) Which statement accurately describes the change that the system will undergo if water is added?

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Carbon tetrachloride may react with oxygen to produce chlorine and carbonyl chloride. 2CCl4(g)+ O2(g) Carbon tetrachloride may react with oxygen to produce chlorine and carbonyl chloride. 2CCl<sub>4</sub>(g)+ O<sub>2</sub>(g)   2COCl<sub>2</sub>(g)+ 2Cl<sub>2</sub>(g); K<sub>c</sub> = 9.9 × 10<sup>51</sup> What is K<sub>c</sub> for the following equilibrium? COCl<sub>2</sub>(g)+ Cl<sub>2</sub>(g)   CCl<sub>4</sub>(g)+ 1/2O<sub>2</sub>(g) 2COCl2(g)+ 2Cl2(g); Kc = 9.9 × 1051 What is Kc for the following equilibrium? COCl2(g)+ Cl2(g) Carbon tetrachloride may react with oxygen to produce chlorine and carbonyl chloride. 2CCl<sub>4</sub>(g)+ O<sub>2</sub>(g)   2COCl<sub>2</sub>(g)+ 2Cl<sub>2</sub>(g); K<sub>c</sub> = 9.9 × 10<sup>51</sup> What is K<sub>c</sub> for the following equilibrium? COCl<sub>2</sub>(g)+ Cl<sub>2</sub>(g)   CCl<sub>4</sub>(g)+ 1/2O<sub>2</sub>(g) CCl4(g)+ 1/2O2(g)

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What is the reaction quotient (Q)for the equilibrium ​ TlSCN(s) What is the reaction quotient (Q)for the equilibrium ​ TlSCN(s)   Tl<sup>+</sup>(aq)+ SCN<sup>-</sup>(aq) ​ When 0.1837 L of   M Tl<sup>+</sup> is combined with 0.1335 L of   M SCN<sup>-</sup> in the presence of an excess of TlSCN(s)? Tl+(aq)+ SCN-(aq) ​ When 0.1837 L of What is the reaction quotient (Q)for the equilibrium ​ TlSCN(s)   Tl<sup>+</sup>(aq)+ SCN<sup>-</sup>(aq) ​ When 0.1837 L of   M Tl<sup>+</sup> is combined with 0.1335 L of   M SCN<sup>-</sup> in the presence of an excess of TlSCN(s)? M Tl+ is combined with 0.1335 L of What is the reaction quotient (Q)for the equilibrium ​ TlSCN(s)   Tl<sup>+</sup>(aq)+ SCN<sup>-</sup>(aq) ​ When 0.1837 L of   M Tl<sup>+</sup> is combined with 0.1335 L of   M SCN<sup>-</sup> in the presence of an excess of TlSCN(s)? M SCN- in the presence of an excess of TlSCN(s)?

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For the reaction Br2(g)+ Cl2(g) For the reaction Br<sub>2</sub>(g)+ Cl<sub>2</sub>(g)   2BrCl(g),at equilibrium,it is found that the concentrations of Br<sub>2</sub>,Cl<sub>2</sub>,and BrCl are 0.484 M,0.105 M,and 1.24 × 10<sup>-3</sup> M,respectively.What is the value of K<sub>c</sub>? 2BrCl(g),at equilibrium,it is found that the concentrations of Br2,Cl2,and BrCl are 0.484 M,0.105 M,and 1.24 × 10-3 M,respectively.What is the value of Kc?

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At 800 K,Kc for the following equilibrium is 4.2 × 10-3. 2HgO(s) At 800 K,K<sub>c</sub> for the following equilibrium is 4.2 × 10<sup>-3</sup>. 2HgO(s)   2Hg(l)+ O<sub>2</sub>(g) Suppose 82.3 g of mercury (II)oxide is placed in a sealed 2.50-L vessel at 800 K.What is the partial pressure of oxygen gas at equilibrium? (R = 0.0821 L ∙ atm/(K ∙ mol)) 2Hg(l)+ O2(g) Suppose 82.3 g of mercury (II)oxide is placed in a sealed 2.50-L vessel at 800 K.What is the partial pressure of oxygen gas at equilibrium? (R = 0.0821 L ∙ atm/(K ∙ mol))

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Which of the following statements is incorrect concerning the addition of a catalyst to an equilibrium reaction system?

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A sample of ammonia gas was allowed to come to equilibrium at 400 K. 2NH3(g) A sample of ammonia gas was allowed to come to equilibrium at 400 K. 2NH<sub>3</sub>(g)   N<sub>2</sub>(g)+ 3H<sub>2</sub>(g) At equilibrium,it was found that the concentration of H<sub>2</sub> was 0.0484 M,the concentration of N<sub>2</sub> was 0.0161 M,and the concentration of NH<sub>3</sub> was 0.295 M.What was the initial concentration of ammonia? N2(g)+ 3H2(g) At equilibrium,it was found that the concentration of H2 was 0.0484 M,the concentration of N2 was 0.0161 M,and the concentration of NH3 was 0.295 M.What was the initial concentration of ammonia?

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For the following reaction system at equilibrium,which one of the changes below would cause the equilibrium to shift to the right? Br2(g)+ 2NO(g) For the following reaction system at equilibrium,which one of the changes below would cause the equilibrium to shift to the right? Br<sub>2</sub>(g)+ 2NO(g)   2NOBr(g); ΔH° = -30 kJ 2NOBr(g); ΔH° = -30 kJ

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When cobalt chloride is added to pure water,the Co2+ ions hydrate.The hydrated form then reacts with the Cl- ions to set up the equilibrium shown here: Co(H2O)62+ + 4Cl- When cobalt chloride is added to pure water,the Co<sup>2+</sup> ions hydrate.The hydrated form then reacts with the Cl<sup>-</sup> ions to set up the equilibrium shown here: Co(H<sub>2</sub>O)<sub>6</sub><sup>2+</sup> + 4Cl<sup>-</sup>   CoCl<sub>4</sub><sup>2-</sup> + 6H<sub>2</sub>O (pink) (blue) Which statement describes the change that the system will undergo if potassium chloride is added? CoCl42- + 6H2O (pink) (blue) Which statement describes the change that the system will undergo if potassium chloride is added?

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A sample of ammonia gas was allowed to come to equilibrium at 400 K. 2NH3(g) A sample of ammonia gas was allowed to come to equilibrium at 400 K. 2NH<sub>3</sub>(g)   N<sub>2</sub>(g)+ 3H<sub>2</sub>(g) At equilibrium,it was found that the concentration of H<sub>2</sub> was 0.0372 M,the concentration of N<sub>2</sub> was 0.0124 M,and the concentration of NH<sub>3</sub> was 0.175 M.What is K<sub>p</sub> for this equilibrium? (R = 0.0821 L ∙ atm/(K ∙ mol)) N2(g)+ 3H2(g) At equilibrium,it was found that the concentration of H2 was 0.0372 M,the concentration of N2 was 0.0124 M,and the concentration of NH3 was 0.175 M.What is Kp for this equilibrium? (R = 0.0821 L ∙ atm/(K ∙ mol))

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When gaseous carbon monoxide and hydrogen are combined in a sealed vessel and heated they will eventually form an equilbrium mixture of reactants and products according to the balanced chemical equilibrium below. CO(g)+ 3H2(g) When gaseous carbon monoxide and hydrogen are combined in a sealed vessel and heated they will eventually form an equilbrium mixture of reactants and products according to the balanced chemical equilibrium below. CO(g)+ 3H<sub>2</sub>(g)   CH<sub>4</sub>(g)+ H<sub>2</sub>O(g) In one such reaction 3 moles of one reactant were combined with 1 mole of the other reactant in a fixed volume vessel and heated to 1200 K.Analysis of the reaction mixture at various times gave the results below.Which component of the reaction mixture is represented by curve B?  CH4(g)+ H2O(g) In one such reaction 3 moles of one reactant were combined with 1 mole of the other reactant in a fixed volume vessel and heated to 1200 K.Analysis of the reaction mixture at various times gave the results below.Which component of the reaction mixture is represented by curve B? When gaseous carbon monoxide and hydrogen are combined in a sealed vessel and heated they will eventually form an equilbrium mixture of reactants and products according to the balanced chemical equilibrium below. CO(g)+ 3H<sub>2</sub>(g)   CH<sub>4</sub>(g)+ H<sub>2</sub>O(g) In one such reaction 3 moles of one reactant were combined with 1 mole of the other reactant in a fixed volume vessel and heated to 1200 K.Analysis of the reaction mixture at various times gave the results below.Which component of the reaction mixture is represented by curve B?

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The following equilibrium is established in a sealed,rigid container.How could the partial pressure of SO2 at equilibrium be increased? SO2Cl2(g) The following equilibrium is established in a sealed,rigid container.How could the partial pressure of SO<sub>2</sub> at equilibrium be increased? SO<sub>2</sub>Cl<sub>2</sub>(g)   SO<sub>2</sub>(g)+ Cl<sub>2</sub>(g); ΔH = +67 kJ SO2(g)+ Cl2(g); ΔH = +67 kJ

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A sample of ammonia gas was allowed to come to equilibrium at 400 K. 2NH3(g) A sample of ammonia gas was allowed to come to equilibrium at 400 K. 2NH<sub>3</sub>(g)   N<sub>2</sub>(g)+ 3H<sub>2</sub>(g) At equilibrium,it was found that the concentration of H<sub>2</sub> was 0.0551 M,the concentration of N<sub>2</sub> was 0.0183 M,and the concentration of NH<sub>3</sub> was 0.383 M.What is K<sub>c</sub> for this equilibrium? N2(g)+ 3H2(g) At equilibrium,it was found that the concentration of H2 was 0.0551 M,the concentration of N2 was 0.0183 M,and the concentration of NH3 was 0.383 M.What is Kc for this equilibrium?

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Consider the following reaction: 2HF(g) Consider the following reaction: 2HF(g)   H<sub>2</sub>(g)+ F<sub>2</sub>(g)(K<sub>c</sub> = 1.00 × 10<sup>-2</sup>) Given that 1.00 mol of HF(g),0.200 mol of H<sub>2</sub>(g),and 0.750 mol of F<sub>2</sub>(g)are mixed in a 5.00-L flask,determine the reaction quotient,Q. H2(g)+ F2(g)(Kc = 1.00 × 10-2) Given that 1.00 mol of HF(g),0.200 mol of H2(g),and 0.750 mol of F2(g)are mixed in a 5.00-L flask,determine the reaction quotient,Q.

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For the reaction 2HI(g) For the reaction 2HI(g)   H<sub>2</sub>(g)+ I<sub>2</sub>(g),K<sub>c</sub> = 0.290 at 400 K.If the initial concentrations of HI,H<sub>2</sub>,and I<sub>2</sub> are all 1.50 × 10<sup>-3</sup> M at 400 K,which one of the following statements is correct? H2(g)+ I2(g),Kc = 0.290 at 400 K.If the initial concentrations of HI,H2,and I2 are all 1.50 × 10-3 M at 400 K,which one of the following statements is correct?

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A 35.00-L vessel at 700 K initially contains HI(g)at a pressure of 5.80 atm; at equilibrium,it is found that the partial pressure of H2(g)is 0.56 atm.What is the partial pressure of HI(g)at equilibrium? 2HI(g) A 35.00-L vessel at 700 K initially contains HI(g)at a pressure of 5.80 atm; at equilibrium,it is found that the partial pressure of H<sub>2</sub>(g)is 0.56 atm.What is the partial pressure of HI(g)at equilibrium? 2HI(g)   H<sub>2</sub>(g)+ I<sub>2</sub>(g) H2(g)+ I2(g)

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Consider the following equilibrium: CO2(g)+ C(graphite) Consider the following equilibrium: CO<sub>2</sub>(g)+ C(graphite)   2CO(g); ΔH = 172.5 kJ The equilibrium constant for this reaction will 2CO(g); ΔH = 172.5 kJ The equilibrium constant for this reaction will

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In which of the following reactions does an instantaneous increase in the volume of the reaction vessel favor formation of the products?

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