Exam 16: Additional Aqueous Equilibria

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A weak acid-strong base titration is being performed using a visual indicator. By titrating a standard acid sample, it is found that the end point is occurring before the equivalence point. a. Define endpoint and equivalence point. b. Explain the probable origin of the error, and how you would modify the titration procedure to eliminate it.

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Exhibit 16-1 The following question(s) refer to the same titration: a 50.00 mL sample of 0.0950 M acetic acid (Ka = 1.8 × 10-5) is being titrated with 0.106 M NaOH. Refer to Exhibit 16-1. What is the pH at the endpoint of the titration?

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Which statement about buffer solutions is not true?

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For a solution containing a dissolved salt, if Q = Ksp

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Silver chloride has Ksp = 1.8 × 10-10. What is its molar solubility in water?

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Which of the following indicator(s) would be most suitable for the titration of acetic acid (pKa = 4.74) with NaOH? Your choices are: I. bromothymol blue (transition range pH 6 to 8) II. methyl red (transition range pH 4 to 6.3) III. phenolphthalein (transition range pH 8.3 to 11)

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In a buffer solution, if [A-] < [HA] then

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In which liquid or solution would CuI(s) have the greatest solubility?

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A buffer solution will result when ____ is added to a solution of K3PO4.

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Silver phosphate is less soluble in Na3PO4 than in water because

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Which acid, in combination with its conjugate base, would be the best choice to make a buffer of pH = 4.20?

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If a buffer is made up using 1.00 mole of a weak acid (pKa = 5.00) and 0.90 mole of its conjugate base, which of the following must be true?

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In which liquid or solution would calcium phosphate have the greatest solubility?

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Which acid-base titration would yield a titration curve of the general form shown? Which acid-base titration would yield a titration curve of the general form shown?

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When conducting a titration of an acid by adding base to the equivalence point, it is appropriate to use an indicator which has

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Which statement about the titration of 0.10 M HNO3 with 0.10 M KOH is not correct?

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The greater the Ksp of a salt

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A buffer solution is 0.080 M in lactic acid (Ka = 1.8 × 10-4) and 0.070 M in sodium lactate. The pH of the solution is

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Consider a buffer solution made up of H2PO4- and HPO42- For H2PO4-, Ka = 6.2 × 10-8. What mole ratio of HPO42- to H2PO4- will give a pH of 7.35?

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In a buffer solution, if [A-] = [HA] then

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