Exam 18: The Laws of Thermodynamics

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The entropy of the universe remains constant during a reversible adiabatic change.

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An ideal monatomic gas undergoes an isothermal expansion. It is correct to affirm that its entropy

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A monatomic ideal gas at an initial temperature of 390 K is compressed adiabatically from an initial volume of 120 L to a final volume of 40.0 L. What is the final temperature of the gas?

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Entropy is a state function.

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A certain Carnot engine has Th = Tc + 35K, and an efficiency of 20.0%. What is Th?

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What is the change in entropy of the lead when 2.0 kg of molten lead solidifies? [Data: Lv = 207. kcal/kg at 1744.°C; Lf = 5.9 kcal/kg at 328.°C]

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1.50 moles of an ideal monatomic gas are initially at a temperature of 317 K. If the gas gains 2730 J of heat and performs 780 J of work, what is its final temperature?

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FIGURE 18-3 FIGURE 18-3   -An ideal gas undergoes the process a→b→c→a shown in Figure 18-3. P<sub>a</sub> = P<sub>c</sub> = 240 kPa, V<sub>b</sub> = V<sub>c</sub> = 40 L, V<sub>a</sub> = 15 L, and P<sub>b</sub> = 400 kPa. How much heat is gained by the system in this process? -An ideal gas undergoes the process a→b→c→a shown in Figure 18-3. Pa = Pc = 240 kPa, Vb = Vc = 40 L, Va = 15 L, and Pb = 400 kPa. How much heat is gained by the system in this process?

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A monatomic ideal gas is compressed isobarically to one-third of its initial volume. The resulting pressure will be

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An ideal monatomic gas undergoes a reversible expansion to 1.5 times its original volume. In which of these processes does the gas perform the most work?

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A monatomic ideal gas expands adiabatically from an initial volume of 72 L and an initial temperature of 350 K until its temperature falls to 290 K. What is the final volume of the gas?

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4.00 moles of a monatomic ideal gas at a temperature of 340 K are compressed adiabatically from an initial volume of 70.0 L to a final volume of 30.0 L. What is the final pressure in the gas?

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FIGURE 18-3 FIGURE 18-3   -An ideal gas undergoes the process a→b→c→a shown in Figure 18-3. The heat gained in process a→b is 546 J, while in process b→c the system loses 62 J. In process a→b the system performs 310 J of work, while in process c→a work is done on the system in the amount of 223 J. How much heat is gained by the system in process c→a? -An ideal gas undergoes the process a→b→c→a shown in Figure 18-3. The heat gained in process a→b is 546 J, while in process b→c the system loses 62 J. In process a→b the system performs 310 J of work, while in process c→a work is done on the system in the amount of 223 J. How much heat is gained by the system in process c→a?

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When objects at different temperatures are brought into thermal contact with one another, the resulting spontaneous flow of heat proceeds from the object with the higher

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State the Third Law of Thermodynamics

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FIGURE 18-1 FIGURE 18-1   -An ideal monatomic gas undergoes the reversible expansion shown in the Figure 18-1, where V<sub>2</sub> = 5V<sub>1</sub> and P<sub>2</sub> = 3P<sub>1</sub>. How much heat is gained by the gas in this process, in terms of the initial pressure and volume? -An ideal monatomic gas undergoes the reversible expansion shown in the Figure 18-1, where V2 = 5V1 and P2 = 3P1. How much heat is gained by the gas in this process, in terms of the initial pressure and volume?

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An ideal, reversible heat pump is taking heat from the outside air at -10.0°C and discharging it into the house at 18.0°C. What is the coefficient of performance of this heat pump?

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A gas expands from an initial volume of 0.040 m3 and an initial pressure of 210 kPa to a final volume of 0.065 m3 while its temperature is kept constant. How much work is done by the system?

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A refrigerator has a coefficient of performance equal to 4.2. How much work must be done on the refrigerator in order to remove 250 J of heat from the interior?

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A heat engine has an efficiency of 35.0% and receives 150 J of heat per cycle. (a) How much work does it perform in each cycle? (b) How much heat does it exhaust in each cycle?

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