Exam 20: Electrochemistry

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Based on the following information, Br2(l)+ 2 e- → 2 Br-(aq)E° = + 1.09 V Mg2+(aq)+ 2 e- → 2 Mg(s)E° = -2.37 V Which of the following chemical species is the strongest reducing agent?

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Use the tabulated half-cell potentials to calculate ΔG° for the following balanced redox reaction. 3 I2(s)+ 2 Fe(s)→ 2 Fe3+(aq)+ 6 I⁻(aq)

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What is the shorthand notation that represents the following galvanic cell reaction? Sn2+(aq)+ F2(g)→ Sn3+(aq)+ 2 F-(aq)

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Which of the following reactions would be the most spontaneous at 298 K?

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How long must a constant current of 50.0 A be passed through an electrolytic cell containing aqueous Cu2+ ions to produce 3.50 moles of copper metal?

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Predict the species that will be oxidized first if the following mixture of molten salts undergoes electrolysis. Cu2+,Mg2+,Cl⁻,Br⁻,F⁻

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Balance the following redox reaction if it occurs in basic solution.What are the coefficients in front of Cr(OH)4⁻ and ClO⁻ in the balanced reaction? Cr(OH)4⁻(aq)+ ClO⁻(aq)→ CrO42-(aq)+ Cl⁻(aq)

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Balance the following redox reaction if it occurs in H2SO4.What are the coefficients in front of H2O and Cr2(SO4)3 in the balanced reaction? C3H8O2(aq)+ K2Cr2O7(aq)→ C3H4O4(aq)+ Cr2(SO4)3(aq)

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Balance the following reaction under basic conditions.What are the coefficients in front of H2O and Cl- in the balanced reaction? Cl2(aq)+ Br2(l)→ BrO3-(aq)+ Cl-(aq)

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What is the oxidizing agent in the redox reaction represented by the following cell notation? Pb(s)∣ Pb2+(aq) What is the oxidizing agent in the redox reaction represented by the following cell notation? Pb(s)∣ Pb<sup>2+</sup>(aq)   Ag<sup>+</sup>(aq)∣ Ag(s) Ag+(aq)∣ Ag(s)

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Which of the following is the weakest reducing agent?

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How many electrons are transferred in the following reaction? (The reaction is unbalanced.) Co3+(aq)+ K(s)→ Co(s)+ K+(aq)

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How many grams of nickel metal are plated out when a constant current of 15.0 A is passed through aqueous NiCl2 for 40.0 minutes?

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What is undergoing oxidation in the redox reaction represented by the following cell notation? Mn(s)∣ Mn2+(aq) What is undergoing oxidation in the redox reaction represented by the following cell notation? Mn(s)∣ Mn<sup>2+</sup>(aq)   H<sup>+</sup>(aq)∣ H<sub>2</sub>(g)∣ Pt H+(aq)∣ H2(g)∣ Pt

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Balance the following redox reaction if it occurs in basic solution.What are the coefficients in front of ClO2 and H2O in the balanced reaction? H2O2(l)+ ClO2(aq)→ ClO2⁻(aq)+ O2(g)

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Balance the following redox reaction if it occurs in acidic solution.What are the coefficients in front of NO3-and Sn2+ in the balanced reaction? NO3⁻(aq)+ Sn2+(aq)→ Sn4+(aq)+ NO(g)

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What element is being oxidized in the following redox reaction? H2O2(l)+ ClO2(aq)→ ClO2⁻(aq)+ O2(g)

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Calculate the cell potential for the following reaction that takes place in an electrochemical cell at 25°C. Fe(s)∣ Fe3+(aq,0.0011 M) Calculate the cell potential for the following reaction that takes place in an electrochemical cell at 25°C. Fe(s)∣ Fe<sup>3+</sup>(aq,0.0011 M)   Fe<sup>3+</sup>(aq,2.33 M)∣ Fe(s) Fe3+(aq,2.33 M)∣ Fe(s)

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Identify the location of reduction in an electrochemical cell.

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Which of the following is the weakest oxidizing agent?

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